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2022

Publications and Research

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Full-Text Articles in Physical Sciences and Mathematics

Perspectives On Determinism In Quantum Mechanics: Born, Bohm, And The “Quantal Newtonian” Laws, Viraht Sahni Dec 2022

Perspectives On Determinism In Quantum Mechanics: Born, Bohm, And The “Quantal Newtonian” Laws, Viraht Sahni

Publications and Research

Quantum mechanics has a deterministic Schrödinger equation for the wave function. The Göttingen–Copenhagen statistical interpretation is based on the Born Rule that interprets the wave function as a “probability amplitude.” A precept of this interpretation is the lack of determinism in quantum mechanics. The Bohm interpretation is that the wave function is a source of a field experienced by the electrons, thereby attributing determinism to quantum theory. In this paper, we present a new perspective on such determinism. The ideas are based on the equations of motion or “Quantal Newtonian” Laws obeyed by each electron. These Laws, derived from …


Coupled Spherical-Cavities, Stanislav Kreps, Vladimir Shuvayev, Mark Douvidzon, Baheej Bathish, Tom Lenkiewicz Abudi, Amirreza Ghaznavi, Jie Xu, Yang Lin, Lev Deych, Tal Carmon Dec 2022

Coupled Spherical-Cavities, Stanislav Kreps, Vladimir Shuvayev, Mark Douvidzon, Baheej Bathish, Tom Lenkiewicz Abudi, Amirreza Ghaznavi, Jie Xu, Yang Lin, Lev Deych, Tal Carmon

Publications and Research

In this work, we study theoretically and experimentally optical modes of photonic molecules—clusters of optically coupled spherical resonators. Unlike previous studies, we do not use stems to hold spheres in their positions relying, instead on optical tweezers to maintain desired structures. The modes of the coupled resonators are excited using a tapered fiber and are observed as resonances with a quality factor as high as 107. Using the fluorescent mapping technique, we observe families of coupled modes with similar spatial and spectral shapes repeating every free spectral range (a spectral separation between adjacent resonances of individual spheres). Experimental results are …


The Living Breakwaters Pdr Efforts Econcrete Resource Analysis, Guianina Ferrari, Shervon Stephens, Calvin O. Walters Jr. Dec 2022

The Living Breakwaters Pdr Efforts Econcrete Resource Analysis, Guianina Ferrari, Shervon Stephens, Calvin O. Walters Jr.

Publications and Research

On October 29, 2012, Superstorm Sandy impacted 443,000 people and caused nearly $19 billion (about $58 per person in the US) worth of damage within New York City. As part of the New York City infrastructure reparation plan, the Living Breakwaters project in Tottenville addressed coastal resilience, allocating $100M of public funds to a series of artificial breakwaters by the southwest coast of Staten Island. Each breakwater is constructed and designed to mitigate water flow in storm events. ECOncrete, a primary element of the breakwater, is a specialty cast cementitious product that is marine organism-friendly that encourages biocalcification and photosynthesis. …


From Computer Curriculum That Works For The Use Of Computer Intellignece Computer Science, Malachi B. Bacchus Dec 2022

From Computer Curriculum That Works For The Use Of Computer Intellignece Computer Science, Malachi B. Bacchus

Publications and Research

Computer interconnection can link different networks by using electrical artificial flow ways that can travel through different connections. these are called data network which travels through different sectors of the network simulation of service computer network using artificial intelligence to enhanced further understanding the computations, I've also demonstrated knowing by using the network to get better understanding of how ethical computing can be learned through universities and collegiate that can help established knowledge and healthy computer information. The main tools for the research are using data networking, ethical learning and translation towards different computer systems.


Sea Level Rising And Its Impact On Nyc, Angela Knafo, Jeff Mao, Andray Whyte, Filip Valencin, Erick Humala, Jubran Alawdi, Jonathan Carangui Dec 2022

Sea Level Rising And Its Impact On Nyc, Angela Knafo, Jeff Mao, Andray Whyte, Filip Valencin, Erick Humala, Jubran Alawdi, Jonathan Carangui

Publications and Research

Climate change is not only about the rising temperatures, which is usually the most discussed topic in news, but it also involves other Earth sciences like hydrology, oceanography and other parts of meteorology In our poster we are focusing on sea level rising and its impact on NYC, and how people could mitigate and adapt to it


Systematic Review Of A Ramsar Wetland And Unesco Biosphere Reserve In A Climate Change Hotspot (Ichkeul Lake, Tunisia), Sabrine Sahbani, Béchir Béjaoui, Sihem Benabdalla, Rachid Toujani, Afef Fathalli, Noureddine Zaaboub, Jalel Aouissi, Zeineb Kassouk, Nabil Hamdi, Nabiha Ben Mbarek, Hechmi Missaoui, Leila Basti, Reginald Blake, Hamidreza Norouzi Dec 2022

Systematic Review Of A Ramsar Wetland And Unesco Biosphere Reserve In A Climate Change Hotspot (Ichkeul Lake, Tunisia), Sabrine Sahbani, Béchir Béjaoui, Sihem Benabdalla, Rachid Toujani, Afef Fathalli, Noureddine Zaaboub, Jalel Aouissi, Zeineb Kassouk, Nabil Hamdi, Nabiha Ben Mbarek, Hechmi Missaoui, Leila Basti, Reginald Blake, Hamidreza Norouzi

Publications and Research

Tunisia's Ichkeul Lake is among the most productive ecosystems in the Mediterranean, with a great regional value thanks to its diversity of habitats. It is an important overwintering area for waterfowl species. It is a RAMSAR wetland, a National Park, a UNESCO World Heritage, and a Biosphere Reserve. This review paper provides a broad overview of the climatic, hydraulic, biogeochemical features, bio-resources, and bio-productivity of the Lake. The interconnectivity between the different environmental components of the lake is presented, highlighting the main characteristics of this vital ecosystem. Its ecosystem consists of a permanent lake bordered by temporary marshes. It is …


Computer Ethics In Curriculum, Tiya Williams Dec 2022

Computer Ethics In Curriculum, Tiya Williams

Publications and Research

Ethics specifically in Computer Curriculum is a growing problem that has yet to be widely addressed. Although, start of computer ethics being taught has been traced back to the early 1940’s it has not been standardized or implemented in all computer curriculum. The objective of this research is to diagnose the reasons why ethics is so crucial in computer curriculum at all levels. I used surveys to investigate whether students were taught ethics in their computer curriculum. I also conducted surveys for professors at universities and colleges if they were taught ethics while obtaining their degree, as well as if …


Natural Language Processing For Disaster Tweets, Akinyemi D. Apampa, Nan Li Dec 2022

Natural Language Processing For Disaster Tweets, Akinyemi D. Apampa, Nan Li

Publications and Research

Our goal is to establish an automatic model that identifies which tweets are about natural disasters based on the content of the tweets. Our method is to construct a decision tree based on keyword searching. We will construct the model using 7,645 tweets and test our model on 3,465 tweets as an assessment of the performance.


Whispering Gallery Modes Of A Triatomic Photonic Molecule, Vladimir Shuvayev, Stanislav Kreps, Tal Carmon, Lev Deych Nov 2022

Whispering Gallery Modes Of A Triatomic Photonic Molecule, Vladimir Shuvayev, Stanislav Kreps, Tal Carmon, Lev Deych

Publications and Research

In this paper, we present the results of numerical simulations of the optical spectra of a three-sphere photonic molecule. The configuration of the system was continuously modified from linear to triangular, in-plane with the fundamental mode excited in one of the spheres and perpendicular to it. We found the relative insensitivity of the spectra to the in-plane deviation from the linear arrangement up to about 110°. For larger angles, the spectra show significant modification consisting of the major spectral peaks splitting and shifting. On the contrary, the spectra are quite sensitive to out-of-plane molecule deviation, even at small angles. Thus, …


Plasmon Damping Rates In Coulomb-Coupled 2d Layers In A Heterostructure, Dipendra Dahal, Godfrey Gumbs, Andrii Iurov, Chin-Sen Ting Nov 2022

Plasmon Damping Rates In Coulomb-Coupled 2d Layers In A Heterostructure, Dipendra Dahal, Godfrey Gumbs, Andrii Iurov, Chin-Sen Ting

Publications and Research

The Coulomb excitations of charge density oscillation are calculated for a double-layer heterostructure. Specifically, we consider two-dimensional (2D) layers of silicene and graphene on a substrate. From the obtained surface response function, we calculated the plasmon dispersion relations, which demonstrate how the Coulomb interaction renormalizes the plasmon frequencies. Most importantly, we have conducted a thorough investigation of how the decay rates of the plasmons in these heterostructures are affected by the Coulomb coupling between different types of two- dimensional materials whose separations could be varied. A novel effect of nullification of the silicene band gap is noticed when graphene is …


Logic, Co-Ordination And The Envelope Of Our Beliefs, Rohit J. Parikh Nov 2022

Logic, Co-Ordination And The Envelope Of Our Beliefs, Rohit J. Parikh

Publications and Research

Each of us has a story which we can think of as a set of beliefs, hopefully consistent. We make our decisions in view of our beliefs which may be probabilistic, in the general case, but simple yes or no as in this paper. Our beliefs are our envelope just as the shell of a tortoise is its envelope.

Decision theory - or single agent game theory tells us when to make the best choice in a game of us against nature. But nature has no desire to further or frustrate our efforts. Nature is mysterious but not malign.

Things …


Algorithmic Rationality, Rohit J. Parikh Oct 2022

Algorithmic Rationality, Rohit J. Parikh

Publications and Research

The notion of rationality is much discussed by both Economists and Philosophers. Perhaps you are rational if you accept certain axioms of rationality. If you prefer A to B and B to C then you must prefer A to C. Or you can define rationality in terms of the net results of your behavior. We examine a notion of algorithmic rationality. Even animals upwards from the humble tick carry out algorithms. Are they rational? And can we use this theory to define the IQ of animals?


Ocean Currents Break Up A Tabular Iceberg, Alex Huth, Alistair Adcroft, Olga Sergienko, Nuzhat Khan Oct 2022

Ocean Currents Break Up A Tabular Iceberg, Alex Huth, Alistair Adcroft, Olga Sergienko, Nuzhat Khan

Publications and Research

In December 2020, giant tabular iceberg A68a (surface area 3900 km 2 ) broke up in open ocean much deeper than its keel, indicating that the breakage was not immediately caused by collision with the seafloor. Giant icebergs with lengths exceeding 18.5 km account for most of the calved ice mass from the Antarctic Ice Sheet. Upon calv - ing, they drift away and transport freshwater into the Southern Ocean, modifying ocean circulation, disrupting sea ice and the marine biosphere, and potentially triggering changes in climate. Here, we demonstrate that the A68a breakup event may have been triggered by ocean-current …


Preliminary Geochemical And Mineralogical Assessment Of The Beach Sand, Vieques, Puerto Rico, Nazrul I. Khandaker Oct 2022

Preliminary Geochemical And Mineralogical Assessment Of The Beach Sand, Vieques, Puerto Rico, Nazrul I. Khandaker

Publications and Research

PRELIMINARY GEOCHEMICAL AND MINERALOGICAL ASSESSMENT OF THE BEACH SAND, VIEQUES, PUERTO RICO

ROBBINS, Kathy H., KHANDAKER, Nazrul, SINGH, Andrew, and MUNRO, Toralv, Geological Society of America Abstracts with Programs, Vol 54, No. 5, https://doi.org/10.1130/abs/2022AM-379886

ROBBINS, Kathy H., Bronx Early College Academy for Teaching and Learning, 250E 164 STREET, Bronx, NY 10456, KHANDAKER, Nazrul, Geology Discipline, York College of CUNY, 9420 Guy R Brewer Blvd, AC-2F09, Jamaica, NY 11451-0001, SINGH, Andrew, Earth and Physical Sciences, York College of CUNY, 9420 Guy R Brewer Blvd, AC-2F09, Jamaica, NY 11451-0001 and MUNRO, Toralv, 10911 164th St Apt 1, Jamaica, NY 11433-2921 …


Geochemical Analysis Of Recent Volcanic Ash Blanketing Barbados And Constraints On Magma Composition (V32e-0112), Nazrul I. Khandaker, Krishna Mahabir, Surendranauth Mahabir, Lloyd Kiefer, Juan C. Campo, Andrew M. Singh Oct 2022

Geochemical Analysis Of Recent Volcanic Ash Blanketing Barbados And Constraints On Magma Composition (V32e-0112), Nazrul I. Khandaker, Krishna Mahabir, Surendranauth Mahabir, Lloyd Kiefer, Juan C. Campo, Andrew M. Singh

Publications and Research

Preliminary field and geochemical investigations were conducted on ash samples from Barbados to chemically characterize and decipher magma chemistry associated with a recent volcanic event. A thick plume of volcanic ash from the La Soufriere Volcano in St Vincent, which erupted on April 9, 2021, caused lower visibility due to ash clouds which engulfed the region for some time. Three authors from the research team visited Barbados during the summer subsequent and completed a reconnaissance investigation on recent ashfall. St Vincent is a small volcanic island in the Eastern Caribbean and lies in the southern part of the Lesser Antilles …


Changing Behavior Of Cyclone In Bangladesh And Its Risk Assessment For Adaptation, Sareea Rahman Heea, Muhammad Qumrul Hassan, Abdul Mannan, Nazrul I. Khandaker Oct 2022

Changing Behavior Of Cyclone In Bangladesh And Its Risk Assessment For Adaptation, Sareea Rahman Heea, Muhammad Qumrul Hassan, Abdul Mannan, Nazrul I. Khandaker

Publications and Research

Tropical cyclone (TC) is one of the most crucial topics not only for the natural loss but also for physical and economical loss of any country. The Bay of Bengal (BoB) generates number of tropical cyclones in each year. Bangladesh also experiences a number of cyclones. The surface temperature of the sea and air temperature is observed from NOAA high resolution satellite image. The Sea Surface Temperature (SST) of about 27°C and its higher is one of the prerequisite conditions for formation of a TC. But SST has increased by 1.2°C since last 40 years. It can be settled that …


Assessing Student Performance And Interest From The Start Of The Covid-19 Pandemic To Present Using Engagement, Attendance, And Grades As Indicators, Nazrul I. Khandaker Oct 2022

Assessing Student Performance And Interest From The Start Of The Covid-19 Pandemic To Present Using Engagement, Attendance, And Grades As Indicators, Nazrul I. Khandaker

Publications and Research

ASSESSING STUDENT PERFORMANCE AND INTEREST FROM THE START OF THE COVID-19 PANDEMIC TO PRESENT USING ENGAGEMENT, ATTENDANCE, AND GRADES AS INDICATORS

SINGH, Andrew, KHANDAKER, Nazrul, ZARINE, Ali, ROBBINS, Kathy H., JACKSON, Shirley and AHMED, Masud,

Geological Society of America Abstracts with Programs. Vol 54, No. 5, https://doi.org/10.1130/abs/2022AM-379409

SINGH, Andrew1, KHANDAKER, Nazrul2, ZARINE, Ali3, ROBBINS, Kathy H.4, JACKSON, Shirley3 and AHMED, Masud5, (1)Earth and Physical Sciences, York College of CUNY, 9420 Guy R Brewer Blvd, AC-2F09, Jamaica, NY 11451-0001, (2)Geology Discipline, York College of CUNY, 9420 Guy R Brewer …


Comparing Geosciences-Related Engagement Generated During And After The Use Of Multiple Pedagogical Approaches: Animated Videos, Youtube, Interactive Educational Games, Group Discussion And Powerpoint Presentations, Andrew M. Singh, Nazrul I. Khandaker, Ality Aghedo, Jasmin Budhan, Belal A. Sayeed, B'Jorn K. Forde, Krishna Mahabir Oct 2022

Comparing Geosciences-Related Engagement Generated During And After The Use Of Multiple Pedagogical Approaches: Animated Videos, Youtube, Interactive Educational Games, Group Discussion And Powerpoint Presentations, Andrew M. Singh, Nazrul I. Khandaker, Ality Aghedo, Jasmin Budhan, Belal A. Sayeed, B'Jorn K. Forde, Krishna Mahabir

Publications and Research

The COVID-19 pandemic has increased educators’ reliance on online learning tools such as Blackboard Collaborate Ultra and Zoom meetings to deliver geoscience-related lessons in real-time. Assessments were conducted using introduction to geology, environmental geology, and oceanography - part of the City University of New York's (CUNY) newly implemented pathways curriculum. These general education courses belong to scientific world and life and physical sciences category and are intended for seamless transfer between CUNY campuses. Students, however, have the option to disengage from participation. Students are able to disable microphones and cameras, as well as rely entirely on text-chat if they choose. …


Assessing Vegetation Pattern Using Moderate Resolution Imaging Spectroradiometer (Modis) Images Along The Western Coastal Area Of Bangladesh, Nazrul I. Khandaker Oct 2022

Assessing Vegetation Pattern Using Moderate Resolution Imaging Spectroradiometer (Modis) Images Along The Western Coastal Area Of Bangladesh, Nazrul I. Khandaker

Publications and Research

ASSESSING VEGETATION PATTERN USING MODERATE RESOLUTION IMAGING SPECTRORADIOMETER (MODIS) IMAGES ALONG THE WESTERN COASTAL AREA OF BANGLADESH

AKHI, Atika Rahman, AHMED, Asib, HASSAN, Muhammad Qumrul, and KHANDAKER, Nazrul

Geological Society of America Abstracts with Programs, Vol 54, No. 5, https://doi.org/10.1130/abs/2022AM-379769

AKHI, Atika Rahman, Department of Environmental Science, Bangladesh University of Professionals, Dhaka, 1000, Bangladesh, AHMED, Asib, Department of Geography and Environment, Dhaka University, Agargaon, Dhaka, 1000, Bangladesh, HASSAN, Muhammad Qumrul, Department of Geology, University of Dhaka, Dhaka, 1000, Bangladesh and KHANDAKER, Nazrul, Geology Discipline, York College of CUNY, 9420 Guy R Brewer Blvd, AC-2F09, Jamaica, NY 11451-0001

The …


Integrating Remote Digital Tools Into Post-Pandemic Geologic Fieldwork To Effectively Disseminate Content Delivery And Assist In Overall Understanding Of Various Geologic Phenomena: Summer 2022 Field Mapping Exercises, Nazrul I. Khandaker Oct 2022

Integrating Remote Digital Tools Into Post-Pandemic Geologic Fieldwork To Effectively Disseminate Content Delivery And Assist In Overall Understanding Of Various Geologic Phenomena: Summer 2022 Field Mapping Exercises, Nazrul I. Khandaker

Publications and Research

INTEGRATING REMOTE DIGITAL TOOLS INTO POST-PANDEMIC GEOLOGIC FIELDWORK TO EFFECTIVELY DISSEMINATE CONTENT DELIVERY AND ASSIST IN OVERALL UNDERSTANDING OF VARIOUS GEOLOGIC PHENOMENA: SUMMER 2022 FIELD MAPPING EXERCISES

SHAMI, Malek, BETHEL, Cherise, NUNEZ, Eddy, RAYHAN, Salam, KHANDAKER, Nazrul and CABAROY, Charren C.

Geological Society of America Abstracts with Programs. Vol 54, No. 5, https://doi.org/10.1130/abs/2022AM-379779

SHAMI, Malek1, BETHEL, Cherise2, NUNEZ, Eddy3, RAYHAN, Salam3, KHANDAKER, Nazrul2 and CABAROY, Charren C.1, (1)Geology Discipline, AC-2F09, York College of CUNY, 9420 Guy R. Brewer Blvd., Jamaica, NY 11451, (2)Geology Discipline, York College of CUNY, …


Artificial Intelligence And The Situational Rationality Of Diagnosis: Human Problem-Solving And The Artifacts Of Health And Medicine, Michael W. Raphael Oct 2022

Artificial Intelligence And The Situational Rationality Of Diagnosis: Human Problem-Solving And The Artifacts Of Health And Medicine, Michael W. Raphael

Publications and Research

What is the problem-solving capacity of artificial intelligence (AI) for health and medicine? This paper draws out the cognitive sociological context of diagnostic problem-solving for medical sociology regarding the limits of automation for decision-based medical tasks. Specifically, it presents a practical way of evaluating the artificiality of symptoms and signs in medical encounters, with an emphasis on the visualization of the problem-solving process in doctor-patient relationships. In doing so, the paper details the logical differences underlying diagnostic task performance between man and machine problem-solving: its principle of rationality, the priorities of its means of adaptation to abstraction, and the effects …


Conflict Dynamics In Scale-Free Networks With Degree Correlations And Hierarchical Structure, Eduardo Jacobo-Villegas, Bibiana Obregón-Quintana, Lev Guzmán-Vargas, Larry S. Liebovitch Oct 2022

Conflict Dynamics In Scale-Free Networks With Degree Correlations And Hierarchical Structure, Eduardo Jacobo-Villegas, Bibiana Obregón-Quintana, Lev Guzmán-Vargas, Larry S. Liebovitch

Publications and Research

We present a study of the dynamic interactions between actors located on complex networks with scale-free and hierarchical scale-free topologies with assortative mixing, that is, correlations between the degree distributions of the actors. The actor’s state evolves according to a model that considers its previous state, the inertia to change, and the influence of its neighborhood. We show that the time evolution of the system depends on the percentage of cooperative or competitive
interactions. For scale-free networks, we find that the dispersion between actors is higher when all interactions are either cooperative or competitive, while a balanced presence of interactions …


Microstructural Origin Of The High-Energy Storage Performance In Epitaxial Lead-Free Ba(Zr 0.2 Ti 0.8 )O 3 Thick Films, Jun Ouyang, Xianke Wang, Changtao Shao, Hongbo Cheng, Hanfei Zhu, Yuhang Ren Sep 2022

Microstructural Origin Of The High-Energy Storage Performance In Epitaxial Lead-Free Ba(Zr 0.2 Ti 0.8 )O 3 Thick Films, Jun Ouyang, Xianke Wang, Changtao Shao, Hongbo Cheng, Hanfei Zhu, Yuhang Ren

Publications and Research

In our previous work, epitaxial Ba(Zr 0.2 Ti 0.8 )O 3 thick films (~1–2 μ m) showed an excellent energy storage performance with a large recyclable energy density (~58 J/cc) and a high energy efficiency (~92%), which was attributed to a nanoscale entangled heterophase polydomain structure. Here, we propose a detailed analysis of the structure–property relationship in these film materials, using an annealing process to illustrate the effect of nanodomain entanglement on the energy storage performance. It is revealed that an annealing-induced stress relaxation led to the segregation of the nanodomains (via detailed XRD analyses), and a degraded energy storage …


Small Molecule Modulation Of Microbiota: A Systems Pharmacology Perspective, Qiao Liu, Bohyun Lee, Lei Xie Sep 2022

Small Molecule Modulation Of Microbiota: A Systems Pharmacology Perspective, Qiao Liu, Bohyun Lee, Lei Xie

Publications and Research

Background

Microbes are associated with many human diseases and influence drug efficacy. Small-molecule drugs may revolutionize biomedicine by fine-tuning the microbiota on the basis of individual patient microbiome signatures. However, emerging endeavors in small-molecule microbiome drug discovery continue to follow a conventional “one-drug-one-target-one-disease” process. A systematic pharmacology approach that would suppress multiple interacting pathogenic species in the microbiome, could offer an attractive alternative solution.

Results

We construct a disease-centric signed microbe–microbe interaction network using curated microbe metabolite information and their effects on host. We develop a Signed Random Walk with Restart algorithm for the accurate prediction of effect of microbes …


Toward Informatics-Enabled Preparedness For Natural Hazards To Minimize Health Impacts Of Climate Change, Jimmy Phuong, Naomi O. Riches, Luca Calzoni, Gora Datta, Deborah Duran, Asiyah Yu Lin, Ramesh P. Singh, Anthony E. Solomonides, Noreen Y. Whysel, Ramakanth Kavuluru Sep 2022

Toward Informatics-Enabled Preparedness For Natural Hazards To Minimize Health Impacts Of Climate Change, Jimmy Phuong, Naomi O. Riches, Luca Calzoni, Gora Datta, Deborah Duran, Asiyah Yu Lin, Ramesh P. Singh, Anthony E. Solomonides, Noreen Y. Whysel, Ramakanth Kavuluru

Publications and Research

Natural hazards (NHs) associated with climate change have been increasing in frequency and intensity. These acute events impact humans both directly and through their effects on social and environmental determinants of health. Rather than relying on a fully reactive incident response disposition, it is crucial to ramp up preparedness initiatives for worsening case scenarios. In this perspective, we review the landscape of NH effects for human health and explore the potential of health informatics to address associated challenges, specifically from a preparedness angle. We outline important components in a health informatics agenda for hazard preparedness involving hazard-disease associations, social determinants …


Markovnikov Alcohols Via Epoxide Hydroboration By Molecular Alkali Metal Catalysts, Guoqi Zhang, Haisu Zeng, Shengping Zheng, Michelle C. Neary, Los Alamos National Laboratory Sep 2022

Markovnikov Alcohols Via Epoxide Hydroboration By Molecular Alkali Metal Catalysts, Guoqi Zhang, Haisu Zeng, Shengping Zheng, Michelle C. Neary, Los Alamos National Laboratory

Publications and Research

Summary

Synthesis of branched “Markovnikov” alcohols is crucial to various chemical industries. The catalytic reduction of substituted epoxides under mild conditions is a highly attractive method for preparing such alcohols. Classical methods based on heterogeneous or homogeneous transition metal-catalyzed hydrogenation, hydroboration, or hydrosilylation usually suffer from poor selectivity, reverse regioselectivity, limited functional group compatibility, high cost, and/or low availability of the catalysts. Here we report the discovery of highly regioselective hydroboration of nonsymmetrical epoxides catalyzed by ligated archetypal reductants in organic chemistry ‒ alkali metal triethylborohydrides. The chemoselectivity and turnover efficiencies of the present catalytic approach are excellent. Thus, terminal …


How Many Mutex Bugs Can A Simple Analysis Find In Go Programs?, Fumi Takeuchi, Hidehiko Masuhara, Raffi T. Khatchadourian, Youyou Cong, Keisuke Ishibashi Sep 2022

How Many Mutex Bugs Can A Simple Analysis Find In Go Programs?, Fumi Takeuchi, Hidehiko Masuhara, Raffi T. Khatchadourian, Youyou Cong, Keisuke Ishibashi

Publications and Research

In open-source software, it is known that there are many concurrency bugs. A previous study in Go revealed that a considerable number of such bugs are simple (for example, 9% of the bugs are the ones that forget to unlock a mutex,) through a manual program investigation. This paper tries to detect such bugs by applying a simple analysis to see how far such a tool can match the manual analysis. We built a simple intraprocedural control flow analysis in Go, and evaluated its performance concerning the open source programs with concurrency bugs reported in the previous study. Consequently, as …


Generalization Of Bi-Canonical Degrees, Joseph Brennan, Laura Ghezzi, Jooyoun Hong, Wolmer Vasconcelos Sep 2022

Generalization Of Bi-Canonical Degrees, Joseph Brennan, Laura Ghezzi, Jooyoun Hong, Wolmer Vasconcelos

Publications and Research

We discuss invariants of Cohen-Macaulay local rings that admit a canonical module ω. Attached to each such ring R, when ω is an ideal, there are integers–the type of R, the reduction number of ω–that provide valuable metrics to express the deviation of R from being a Gorenstein ring. In (Ghezzi et al. in JMS 589:506–528, 2017) and (Ghezzi et al. in JMS 571:55–74, 2021) we enlarged this list with the canonical degree and the bi-canonical degree. In this work we extend the bi-canonical degree to rings where ω is not necessarily an ideal. We also discuss generalizations to rings …


Asian Hate Speech Detection On Twitter During Covid-19, Amir Toliyat, Sarah Ita Levitan, Zeng Peng, Ronak Etemadpour Aug 2022

Asian Hate Speech Detection On Twitter During Covid-19, Amir Toliyat, Sarah Ita Levitan, Zeng Peng, Ronak Etemadpour

Publications and Research

Coronavirus disease 2019 (COVID-19) started in Wuhan, China, in late 2019, and after being utterly contagious in Asian countries, it rapidly spread to other countries. This disease caused governments worldwide to declare a public health crisis with severe measures taken to reduce the speed of the spread of the disease. This pandemic affected the lives of millions of people. Many citizens that lost their loved ones and jobs experienced a wide range of emotions, such as disbelief, shock, concerns about health, fear about food supplies, anxiety, and panic. All of the aforementioned phenomena led to the spread of racism and …


A Decade Review Of Disease Surveillance Research Trends In The International Journal Of Health Geographics (2009 To 2018), Rose Jimenez, Paradorn Wongchanapai Aug 2022

A Decade Review Of Disease Surveillance Research Trends In The International Journal Of Health Geographics (2009 To 2018), Rose Jimenez, Paradorn Wongchanapai

Publications and Research

The field of health geographics is rapidly growing in its methods and epistemologies. This is a review of the open-source journal International Journal of Health Geographics, and the trends in disease surveillance over ten years (2009-2018). Drawing from research review methodologies, we wrote a Python script to quantify research trends within the field of geographic disease surveillance, finding many articles focusing on population health, techniques of GIS, qualitative techniques, and geospatial technology for health monitoring. This was foundational in conducting an in-depth qualitative lexical analysis of article content and epistemologies. Overall, we concluded that over the time period, the …