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Articles 1 - 30 of 90
Full-Text Articles in Physical Sciences and Mathematics
Sustainability And Health Impacts Of Pulse Crops In The United States Using Life Cycle Assessment, Prathamesh A. Bandekar
Sustainability And Health Impacts Of Pulse Crops In The United States Using Life Cycle Assessment, Prathamesh A. Bandekar
Graduate Theses and Dissertations
Environmental sustainability and human health impact of pulses produced and consumed in the United States was assessed using life cycle assessment (LCA). The study included three objectives 1) to estimate environmental impact of current production and consumption practices in the United States using attributional LCA; 2) to estimate environmental and human health impact of iso-caloric diets containing varying amounts of pulses using Hybrid-LCA and Combined Nutritional and Environmental-LCA (CONE-LCA); and 3) to estimate environmental impact of increased demand for pulses using consequential LCA. Scope of the study varied for each objective with system boundary encompassing cradle-to-grave activities for objective 1 …
First-Principles Study Of Doping Effects On Ferroelectricity And On Rashba Spin Splitting, Zegnet Yimer Muhammed
First-Principles Study Of Doping Effects On Ferroelectricity And On Rashba Spin Splitting, Zegnet Yimer Muhammed
Graduate Theses and Dissertations
In this dissertation, we have thoroughly studied the effect of chemical and charge dopingon ferroelectrics (PbTiO3 and BaTiO3) and Rashba type semiconductor (BiTeI). In the first project, We investigate the polar instability and soft modes in electron-doped PbTiO3 using linear-response density functional calculations. Because, metallicity and ferroelectric-like polar distortion are mutually non-compatible, and their coexistence in the same system is an intriguing subject of fundamental interest in the field of structure phase transition. However, it is unclear what mechanism may extend the limit of metallicity that allows polar distortion. We find that ferroelectric instability can remarkably sustain up to an …
The Human Natural Resource Endowment Of Limestone For Cement Manufacturing, Vanya Marie North
The Human Natural Resource Endowment Of Limestone For Cement Manufacturing, Vanya Marie North
Graduate Theses and Dissertations
This study investigates the total per-capita allocation of limestone globally. Termed the Human Natural Resource Endowment (HNRE), it is calculated by subtracting the cumulative annual production from the ultimately recoverable reserve (URR) of limestone and dividing the difference by global population. HNRE represents a unique way of visualizing resource depletion by asking how much of a given resource can be allocated to each person on earth, and how long that allocation can last given multiple population and usage scenarios. The average American, born in 2021, will use approximately 23,930 kgs of cement in their lifetime, with similar demands globally. Demand …
Life Cycle Assessment Of Novel Electrochemical Struvite Recovery In Municipal Wastewater Treatment At The Plant And U.S. Watershed Scales, Karla Morrissey
Life Cycle Assessment Of Novel Electrochemical Struvite Recovery In Municipal Wastewater Treatment At The Plant And U.S. Watershed Scales, Karla Morrissey
Graduate Theses and Dissertations
As the supply of phosphorus decreases, nutrient recovery in municipal wastewater treatment has become an important area of research. Recovery methods for phosphorus-containing fertilizers, such as struvite, and other products are currently being developed and assessed for their efficiency and economic feasibility. Potential environmental impacts from nutrient recovery are also being assessed as design for the environment is important, especially with regards to the eutrophying potential of phosphorus in phosphorus-limited freshwater aquatic systems. Life cycle assessment (LCA) is a tool that can be used to estimate potential environmental impacts of a product or service focusing on its entire life cycle. …
Assessment Of Novel Protein Ingredient Arthrospira Platensis (Microalgae) And Soybean Genotype Amino Acid And Oil Selection Improvements On Broiler Performance, Savannah Wells Crafton
Assessment Of Novel Protein Ingredient Arthrospira Platensis (Microalgae) And Soybean Genotype Amino Acid And Oil Selection Improvements On Broiler Performance, Savannah Wells Crafton
Graduate Theses and Dissertations
Two experiments were conducted to assess the efficiency of including novel protein ingredient Arthrospira platensis or improved soybean meal in a broiler diet. The first experiment aimed to determine the feeding value of soybean meal produced from varieties of soybeans bred for increased amino acid content (SBAA) improved oil content (SBO) compared to a conventional soybean variety in an ANOVA design fed to Cobb 500 female broilers for 28-42d of age. The SBAA and SBO soybeans contained overall higher amino acid content and lower oligosaccharide content compared to the conventional soybean variety in addition to improved oil quality. The second …
Divide-And-Conquer Distributed Learning: Privacy-Preserving Offloading Of Neural Network Computations, Lewis C.L. Brown
Divide-And-Conquer Distributed Learning: Privacy-Preserving Offloading Of Neural Network Computations, Lewis C.L. Brown
Graduate Theses and Dissertations
Machine learning has become a highly utilized technology to perform decision making on high dimensional data. As dataset sizes have become increasingly large so too have the neural networks to learn the complex patterns hidden within. This expansion has continued to the degree that it may be infeasible to train a model from a singular device due to computational or memory limitations of underlying hardware. Purpose built computing clusters for training large models are commonplace while access to networks of heterogeneous devices is still typically more accessible. In addition, with the rise of 5G networks, computation at the edge becoming …
Gate-Controlled Quantum Dots In Two-Dimensional Tungsten Diselenide And One-Dimensional Tellurium Nanowires, Shiva Davari Dolatabadi
Gate-Controlled Quantum Dots In Two-Dimensional Tungsten Diselenide And One-Dimensional Tellurium Nanowires, Shiva Davari Dolatabadi
Graduate Theses and Dissertations
This work focuses on the investigation of gate-defined quantum dots in two-dimensional transition metal dichalcogenide tungsten diselenide (WSe2) as a means to unravel mesoscopic physical phenomena such as valley-contrasting physics in WSe2 flakes and its potential application as qubit, as well as realizing gate-controlled quantum dots based on elementaltellurium nanostructures which may unlock the topological nature of the host material carriers such as Weyl states in tellurium nanowires.The fabrication and characterization of gate-defined hole quantum dots in monolayer and bilayer WSe2 are reported. The gate electrodes in the device design are located above and below the WSe2 nanoflakes to accumulate …
Design And Comparison Of Asynchronous Fft Implementations, Julie Bigot
Design And Comparison Of Asynchronous Fft Implementations, Julie Bigot
Graduate Theses and Dissertations
Fast Fourier Transform (FFT) is a widely used digital signal processing technology in a large variety of applications. For battery-powered embedded systems incorporating FFT, its physical implementation is constrained by strict power consumption, especially during idle periods. Compared to the prevailing clocked synchronous counterpart, quasi-delay insensitive asynchronous circuits offer a series of advantages including flexible timing requirement and lower leakage power, making them ideal choices for these systems. In this thesis work, various FFT configurations were implemented in the low-power Multi-Threshold NULL Convention Logic (MTNCL) paradigm. Analysis illustrates the area and power consumption trends along the changing of the number …
Cell Division Dynamics Of Escherichia Coli In Extreme Environments, Steven P. Murray
Cell Division Dynamics Of Escherichia Coli In Extreme Environments, Steven P. Murray
Graduate Theses and Dissertations
Life is remarkable in how resilient it can be. Many organism, classified as ex- tremophiles, can not only survive in extreme environments, but they can thrive in them. In the search for extraterrestrial life, the best candidates to harbor life exist with some kind of extreme condition. Europa, for example, is a favorite for the possibility of accommodating life as we know it within our solar system. Thought there is believed to be a liquid ocean under its icy surface, this habitat would be under immense pressures and high salinity. To best know where to look for extraterrestrial life, it …
A Method For Exploring The Habitability Of Earth-Like Exoplanets: Applications To Tess Objects Of Interest 203 B, 256 B, And 700 D, Paul Bonney
Graduate Theses and Dissertations
The Transiting Exoplanet Survey Satellite (TESS) has and is continuing to discover a multitude of potentially habitable planet candidates. As more planets are detected and confirmed, it becomes increasingly important to strategically search for signs of habitability with which to differentiate and prioritize them for further observation, in particular with the James Webb Space Telescope (JWST). To facilitate this, I have created a method for prioritizing TESS planet candidates based on parameters derived from their light curves and have applied the method to the TESS Candidate Target List (CTL). This data set uses preliminary fits to transit modeling which can …
Nitrogen Use Efficiency Of Pretassel Nitrogen Applications In Corn, Robyn Brittlee Mulloy
Nitrogen Use Efficiency Of Pretassel Nitrogen Applications In Corn, Robyn Brittlee Mulloy
Graduate Theses and Dissertations
Corn (Zea mays L.) production continues to be a critical component of row-crop production systems within Arkansas and is seeing a resurgence in recent years. Nitrogen (N) is critical for corn growth and is often one of the single largest input costs associated with corn production. Research objectives for this study were to determine the nitrogen use efficiency (NUE) of late season N applications as influenced by sidedress N rate and timing of pretassel application and to quantify the nutrient uptake and partitioning in modern era corn hybrids within a furrow-irrigated production system. Research was conducted at the Milo J. …
The Evolution Of X-Ray Binaries And Their Accretion States, Lacey A. West
The Evolution Of X-Ray Binaries And Their Accretion States, Lacey A. West
Graduate Theses and Dissertations
X-ray binary systems (XRBs) consist of a compact object component (e.g., black hole or neutron star) that accretes matter from a companion star. Although the extent to which XRBs contributed to the early heating of the intergalactic medium is still under investigation, it is estimated that XRBs dominated the X-ray radiation field before the reionization epoch. The study of XRB emission is therefore crucial to our understanding of the very early universe. Furthermore, studying the abundance and radial distribution of each XRB type within a galaxy can be revealing of the host galaxy’s local properties, structure, and evolution. XRB spectra …
A Study On Interactions Between Metal-Organic Frameworks And Biological Materials, Josh Phipps
A Study On Interactions Between Metal-Organic Frameworks And Biological Materials, Josh Phipps
Graduate Theses and Dissertations
Metal-organic frameworks or MOFs are an extremely useful tool in many areas of applications. Their popularity in recent years has arisen from their high efficiency in catalytic chemical reactions. This is made possible due to their porous interior and the ability of the MOFs components to be functionalized. These same traits make MOFs excellent for use in protein encapsulation or immobilization and have the potential to become excellent drug carriers. Their development in this utilization has been limited dramatically compared to MOFs chemical applications. This is due in part to the nature of biological processes taking longer to study, but …
Diagnosing Excess Nitrogen In Rice Using Post-Season Tissue Samples, Kyle Hoegenauer
Diagnosing Excess Nitrogen In Rice Using Post-Season Tissue Samples, Kyle Hoegenauer
Graduate Theses and Dissertations
Proper nitrogen (N) management in rice production can be difficult to achieve without the aid of tools such as soil and tissue tests. There are no tests currently available to rice producers that determine whether N has been managed properly throughout the season or that detect instances of over fertilization. Rice stalk samples were collected from N response trials within 3 days of harvest from the primary Arkansas rice growing region in 2016-2018. Stalk samples were analyzed for N concentration through a KCl extraction and spectrofluorometric quantification. Samples analyzed with leaf material intact contained statistically different N concentrations than samples …
Lyubeznik Numbers Of Unmixed Edge Ideals, Sara Rae Jones
Lyubeznik Numbers Of Unmixed Edge Ideals, Sara Rae Jones
Graduate Theses and Dissertations
Lyubeznik numbers, defined in terms of local cohomology, are invariants of local rings that are able to detect many algebraic and geometric properties. Notably they recognize topological behaviors of various structures associated to their rings. We will discuss computations of these numbers for unmixed edge ideals by giving a completely combinatorial construction which realizes the connectedness information captured by these numbers.
Multivariate Fairness For Paper Selection, Reem Alsaffar
Multivariate Fairness For Paper Selection, Reem Alsaffar
Graduate Theses and Dissertations
Peer review is the process by which publishers select the best publications for inclusion in a journal or a conference. Bias in the peer review process can impact which papers are selected for inclusion in conferences and journals. Although often implicit, race, gender and other demographics can prevent members of underrepresented groups from presenting at major conferences. To try to avoid bias, many conferences use a double-blind review process to increase fairness during reviewing. However, recent studies argue that the bias has not been removed completely. Our research focuses on developing fair algorithms that correct for these biases and select …
Flood Hazard And Risk Analyses In The Republic Of Panama: A Case Study From The Juan Diaz River Watershed In Panama City, Virgilio De Jesus Quintero
Flood Hazard And Risk Analyses In The Republic Of Panama: A Case Study From The Juan Diaz River Watershed In Panama City, Virgilio De Jesus Quintero
Graduate Theses and Dissertations
Flooding is the natural hazard with most occurrences in Panama. Its frequency and magnitude have increased over the years. This dissertation analyzes Panama’s flood activity in order to better understand flood hazards, the current evolution of Panamanian perceptions of flood risk, and the incorporation of indigenous knowledge used to mitigate flood hazards. The first chapter developed a baseline of past and current flood inventory in Panama, which required the use of flood historical data, thematic cartography, and Geographic Information Science (GIS). This chapter shows Panama has experienced floods in varying degrees. Through the spatial and temporal distribution of floods from …
The Binding Of The Micronutrient Transition Metals To The Alkylation Products Of Chemical Warfare Agent, Sulfur Mustard, And Thiols, Potentially Giving New Understanding To Physiological Effects Of Exposure And Increased Toxicity, Colin O'Donnell
Graduate Theses and Dissertations
Model compounds, 3,6,9-trithaiundecane-1,11-dicarboxylic acid (TTDPA), 2,5,8-trithianonane-1,9-dicarboxylic acid (TTDAA), and 1,11-diamide-3,6,9-trithiaundecane (TTDAce), closely related to the adducts formed by cysteine alkylation of the chemical weapon, sulfur mustard, were synthesized. It is shown that TTDPA forms complexes with key metal micronutrients: copper, nickel, cobalt, manganese, and zinc. Though the strength of binding to TTDPA varies, the complexes in many cases precipitate from solution. All metals produced a visible precipitate upon interaction with TTDPA under the conditions tested, however only Cu2+, Mn2+, and Zn2+ produced enough to be measured. The mass of formed precipitate seemed to peak at an equimolar ratio of TTDPA …
Data-Driven Deep Learning-Based Analysis On Thz Imaging, Haoyan Liu
Data-Driven Deep Learning-Based Analysis On Thz Imaging, Haoyan Liu
Graduate Theses and Dissertations
Breast cancer affects about 12.5% of women population in the United States. Surgical operations are often needed post diagnosis. Breast conserving surgery can help remove malignant tumors while maximizing the remaining healthy tissues. Due to lacking effective real-time tumor analysis tools and a unified operation standard, re-excision rate could be higher than 30% among breast conserving surgery patients. This results in significant physical, physiological, and financial burdens to those patients. This work designs deep learning-based segmentation algorithms that detect tissue type in excised tissues using pulsed THz technology. This work evaluates the algorithms for tissue type classification task among freshly …
Mle And Eap Methods For Estimating Ability Scores For Data Of Varying Sample Size And Item Length, Sahar Taji
Mle And Eap Methods For Estimating Ability Scores For Data Of Varying Sample Size And Item Length, Sahar Taji
Graduate Theses and Dissertations
In this research, the performance of two popular estimators, Maximum Likelihood Estimator(MLE) and Bayesian Expected a Posteriori (EAP) is studied and compared in estimating the latent ability score in an Item Response Theory (IRT) model. The 2-Parameter Logistic (2PL) IRT model which is characterized by difficulty and discrimination item parameters is used to estimate the latent ability scores. Several datasets are generated for variety of sample size and item length values. The Monte-Carlo simulation is used to analyze the performance of the estimators. Results show that MLE produces reliable results with low root mean square error (RMSE) across all datasets. …
Deciphering Surfaces Of Trans-Neptunian And Kuiper Belt Objects Using Radiative Scattering Models, Machine Learning, And Laboratory Experiments, Al Emran
Graduate Theses and Dissertations
Decoding surface-atmospheric interactions and volatile transport mechanisms on trans-Neptunian objects (TNOs) and Kuiper Belt objects (KBOs) involves an in-depth understanding of physical and thermal properties and spatial distribution of surface constituents – nitrogen (N2), methane (CH4), carbon monoxide (CO), and water (H2O) ices. This thesis implements a combination of radiative scattering models, machine learning techniques, and laboratory experiments to investigate the uncertainties in grain size estimation of ices, the spatial distribution of surface compositions on Pluto, and the thermal properties of volatiles found on TNOs and KBOs. Radiative scattering models (Mie theory and Hapke approximations) were used to compare single …
Seasonal Patterns In Activity And Occupancy Dynamics Of The Imperiled Spotted Turtle (Clemmys Guttata), Ellery Vaughn Lassiter
Seasonal Patterns In Activity And Occupancy Dynamics Of The Imperiled Spotted Turtle (Clemmys Guttata), Ellery Vaughn Lassiter
Graduate Theses and Dissertations
Wetland ecosystems are often spatially patchy across a landscape and exhibit seasonal patterns in water levels, resulting in the need for aquatic wildlife to use several different wetland patches across a season. The ecology of semi-aquatic freshwater turtles is especially complex because individuals often move among a variety of habitats to meet life history needs and these habitat requirements often differ across a season. Understanding the temporal and spatial scale in which turtles move and distribute across the landscape is vital for effective management, especially in the face of continued habitat fragmentation and climate change. Thus, we sought to understand …
Using Molecular Dynamics Simulations To Decipher Mechanistic Details Of Biomolecular Processes Of Biology And Biotechnology Oriented Applications, Adithya Polasa
Graduate Theses and Dissertations
Researchers in chemistry and biology often utilize computer simulations, in conjunction with experimental data, to model and predict the structures, energies, kinetics, processes, and functions of the systems that are their focus of study, ranging from single molecules to whole viruses. Here, we use molecular dynamics (MD) techniques to gain a deeper understanding of biomolecular processes in biology and biotechnology-oriented applications. Using a mixture of equilibrium and non-equilibrium MD simulations, this work describes the insertion process of YidC at the atomic level. In order to better comprehend the insertion process, several docking models of YidC-Pf3 in the lipid bilayer were …
Hierarchical Structure And Material Integration For Electrocatalytic Co2 Reduction, Hamed Mehrabi
Hierarchical Structure And Material Integration For Electrocatalytic Co2 Reduction, Hamed Mehrabi
Graduate Theses and Dissertations
CO2 released by the combustion of fossil fuels is driving significant changes to the earth’sclimate. The natural cycle for removing CO2 from the atmosphere, namely photosynthesis, cannot keep up with the rate at which it is being added. Developing engineering approaches to remove CO2 from the atmosphere is becoming essential to reduce these effects. Removal leads to further issues of carbon sequestration and favorable CO2 reuse strategies, including the electrochemical transformation of recovered CO2 to useful products such as fuels and materials. Copper is an important electrocatalyst for the CO2 reduction reaction (CO2RR) because of its unique capability for producing …
Nitrogen Management In Rice Under Suboptimal Soil Conditions, Payton Suzanne Rhea
Nitrogen Management In Rice Under Suboptimal Soil Conditions, Payton Suzanne Rhea
Graduate Theses and Dissertations
In Mid-South rice (Oryza sativa, L.) production, nitrogen (N) fertilizer management for pureline varieties is most often recommended as a single preflood (SPF) or two-way split (2WS) application in a direct-seeded, delayed-flood system. Most of the N fertilizer is typically applied at the four- to six-leaf stage onto dry soil, and the second application, if necessary, into the floodwater during early reproductive growth stages (referred to as midseason). Environmental factors frequently prohibit growers from applying early N fertilizer under optimal dry soil conditions. A study was conducted to determine the best N fertilization management practices to utilize in rice when …
Orbital Mapping Of Seasonal And Yearly Changes In Co2 And Water Ice On The Southern Polar Cap Of Mars, Victoria Michell Ann Karnes
Orbital Mapping Of Seasonal And Yearly Changes In Co2 And Water Ice On The Southern Polar Cap Of Mars, Victoria Michell Ann Karnes
Graduate Theses and Dissertations
This research exhibits a new foundation for the rates of change in CO2 and water ice on the southern polar cap of Mars, where the annual precipitation cycles are known to fluctuate seasonally between the north and south pole, based on observations from the Compact Reconnaissance Imaging Spectrometer (CRISM). The conventional belief is that both CO2 ice and water ice on the southern polar cap condenses and evaporates over the course of a Martian year (MY), condensing during the Martian spring and summer and evaporating during the Martian fall and winter. With this theory in mind, CO2 and water ice …
Electrical Modeling For Dynamic Performance Prediction And Optimization Of Mcpms Layout, Quang Minh Le
Electrical Modeling For Dynamic Performance Prediction And Optimization Of Mcpms Layout, Quang Minh Le
Graduate Theses and Dissertations
In recent years, the fast development of Multichip Power Modules (MCPM) packaging and Wide Bandgap (WBG) technology has enabled higher voltage and current ratings, better thermal performance, lower parasitic parameters, and higher mechanical reliability. However, the design of the MCPM layout is a multidisciplinary problem leading to many time-consuming analyses and tedious design processes. Because of these challenges, the design automation tool for MCPM layout has become an emerging research area and gained much attention from the power electronics community. The two critical objectives of a design automation tool for MCPM layout are fast and accurate models for design insights …
Delineating Field Variation Using Apparent Electrical Conductivity In An Ozark Highlands Agroforestry System, Shane Reid Ylagan
Delineating Field Variation Using Apparent Electrical Conductivity In An Ozark Highlands Agroforestry System, Shane Reid Ylagan
Graduate Theses and Dissertations
Little to no work has been conducted assessing field variability using repeated electromagnetic induction (EMI) apparent electrical conductivity (ECa) surveys in agroforestry (AF) systems within regions similar to the Ozark Highlands. The objectives of this thesis were to identify i) spatiotemporal ECa variability; ii) ECa-derived soil management zones (SMZs); iii) correlations among EMI-ECa and in-situ, sentential-site soil properties; iv) whether fewer, EMI-ECa surveys could be conducted to capture similar ECa variance as mid-monthly EMI-ECa surveys; v) correlations between ECa and forage yield, tree growth, and terrain attributes based on plant (forage and tree) species, and fertility treatments, and ECa-derived SMZs, …
Visible Light-Assisted Deconstruction/Refunctionalization Of Strained And Unstrained N-Cycloalkylanilines, Elvis Duah Boateng
Visible Light-Assisted Deconstruction/Refunctionalization Of Strained And Unstrained N-Cycloalkylanilines, Elvis Duah Boateng
Graduate Theses and Dissertations
The exploitation of ring strain as a driving force to facilitate chemical reactions is a well-appreciated principle in organic chemistry. Of the strained carbocycles frequently explored in this respect, cyclopropane ring systems have drawn considerably more interest among synthetic chemists than their homolog, the cyclobutane ring systems, even though the strain energy of cyclobutane (26.7 kcal/mol) is similar to that of cyclopropane (27.5 kcal/mol). We have previously developed a [4+2] annulation reaction for the synthesis of aniline-substituted six-membered carbocycles under photoredox catalysis via the oxidative cleavage of N-cyclobutylanilines. The key reaction involved in this method is a ring-opening process of …
Movie Reviews Sentiment Analysis Using Bert, Gibson Nkhata
Movie Reviews Sentiment Analysis Using Bert, Gibson Nkhata
Graduate Theses and Dissertations
Sentiment analysis (SA) or opinion mining is analysis of emotions and opinions from texts. It is one of the active research areas in Natural Language Processing (NLP). Various approaches have been deployed in the literature to address the problem. These techniques devise complex and sophisticated frameworks in order to attain optimal accuracy with their focus on polarity classification or binary classification. In this paper, we aim to fine-tune BERT in a simple but robust approach for movie reviews sentiment analysis to provide better accuracy than state-of-the-art (SOTA) methods. We start by conducting sentiment classification for every review, followed by computing …