Physical Sciences and Mathematics Commons^™

Characterizing Reactive Iron Mineral Coatings And Their Roles In Natural Attenuation At A Site With Historical Contamination, Han Hua

Dissertations

Reactive iron mineral coatings in redox transition zones play an important role in contaminant attenuation. These mineral coatings include poorly crystalline to crystalline iron sulfides, carbonates, and oxyhydroxides, and are a signature of the biogeochemical processes occurring. To better understand these processes, reactive iron mineral coatings are characterized in an 18-m Anaerobic Core collected from a contaminated industrial site. This study targets redox transition zones uncovered in the core. A suite of complementary analyses is applied to distinguish the surface coating mineralogy using X-ray Diffraction, X-ray fluorescence, and field-emission scanning electron microscopy (FESEM) with energy dispersive X-ray analyzer (EDX). In …

Monitoring Salt Diapir Related Land Deformation And Distribution: A Geophysical And Remote Sensing Approach Jazan Province, Saudi Arabia, Hannah G. Pankratz

Dissertations

Salt diapirs are rarely preserved on the surface and seldom considered as environmental hazards. The Jazan city diapir (JZD) is located in southwest Saudi Arabia along the Red Sea coastal plain and outcrops in the middle of a rapidly growing port city. The intrusion of the diapir (~ 2 km²) into the overburden sediments continues to cause uneven surfaces, compromises building foundations and infrastructure, caused dissolution sinkholes, and limits the expansion of the city along the coastline. This research aims to better understand the distribution and deformation associated with salt diapirs in arid environments.

Using integrated Interferometric Synthetic …

Statistical Downscaling Techniques To Enhance The Spatial Resolution Of The Grace Satellite Data And To Fill Temporal Gaps, Hossein Sahour

Dissertations

The Gravity Recovery and Climate Experiment (GRACE) has been successfully used to monitor variations in terrestrial water storage (GRACE_TWS ) and groundwater storage (GRACE_GWS) across the globe, yet such applications are hindered on local scales by the limited spatial resolution of GRACE data. Using the Lower Peninsula of Michigan as a test site, I developed optimum procedures to downscale GRACE Release-06 monthly mascon solutions. A four-fold exercise is conducted. Cluster analysis is performed to identify the optimum number and distribution of clusters (areas) of contiguous pixels of similar geophysical signals (GRACE_TWS time series); three clusters are …

Integrating Detailed Petrography, Geochemistry, And Mineralogy To Elucidate Extensive Early Diagenesis In The Eocene Carbonates Of Qatar, Brooks H. Ryan

Dissertations

Eocene carbonates comprising the Umm er Radhuma (UER), Rus, and Dammam Formations, cover 80% of the surface and extend >300 m into the subsurface of Qatar. These rocks record marine sedimentation in shallow sub-tidal to restricted settings. Despite undergoing only shallow burial (<1000 m), extensive diagenetic alteration has occurred. Given that little work on this topic has been published previously, the objectives of this work are to document diagenesis in the Eocene, and to integrate petrography, mineralogy, and geochemistry to delineate the timing and environments of diagenesis of these Eocene carbonates. Detailed petrographic data show that dolomitization occurred early in the UER, before the formation of diagenetic chert, palygorskite, pyrite, calcite, and gypsum cements. Bulk dolomite δ¹⁸O values, coupled with clumped isotope-derived (Δ47) temperatures and dolomitizing fluid δ¹⁸O values, suggest dolomitization took place in near-normal marine fluids, perhaps during shallow burial. These data challenge the current paradigm of large-scale, top-down hypersaline reflux dolomitization in the UER. Associated depth trends of increasing crystal size and with increasing stoichiometry and cation ordering …