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Controlled Hydrogenation Into Defective Interlayer Bismuth Oxychloride Via Vacancy Engineering, Dandan Cui, Kang Xu, Xingan Dong, Dongdong Lv, Fan Dong, Weichang Hao, Yi Du, Jun Chen

Australian Institute for Innovative Materials - Papers

Hydrogenation is an effective approach to improve the performance of photocatalysts within defect engineering methods. The mechanism of hydrogenation and synergetic effects between hydrogen atoms and local electronic structures, however, remain unclear due to the limits of available photocatalytic systems and technical barriers to observation and measurement. Here, we utilize oxygen vacancies as residential sites to host hydrogen atoms in a layered bismuth oxychloride material containing defects. It is confirmed theoretically and experimentally that the hydrogen atoms interact with the vacancies and surrounding atoms, which promotes the separati30on and transfer processes of photo-generated carriers via the resulting band structure. The …