Physical Sciences and Mathematics Commons^™

The Fold Illusion: The Origins And Implications Of Ogives On Silicic Lavas, Graham Dm Andrews, Stuart Kenderes, Alan Whittington, Shelby L. Isom, Sarah Brown, Holly Danielle Pettus, Brenna Cole, Kailee Gokey

Faculty & Staff Scholarship

Folds on the surfaces of mafic lavas are among the most readily recognized geological structures and are used as first-order criteria for identifying ancient lavas on Earth and other planetary bodies. However, the presence of surface-folds on the surface of silicic lavas is contested in this study and we challenge the widely accepted interpretation that silicic lava surfaces contain folds using examples from the western United States and Sardinia, Italy. We interpret the ridges and troughs on their upper surfaces, typically referred to as ‘ogives’ or ‘pressure ridges’, as fracture-bound structures rather than folds. We report on the absence of …

Teaching With Digital 3d Models Of Minerals And Rocks, Graham Dm Andrews, Gabrielle Labishak, Sarah Brown, Shelby L. Isom, Holly Danielle Pettus, Trevor Byers

Faculty & Staff Scholarship

The disruption to geoscience curricula due to the COVID-19 pandemic highlights the difficulty of making mineral and rock samples accessible to students online rather than through traditional lab classes. In spring 2020, our community had to adapt rapidly to remote instruction; this transition amplified existing disparities in access to geoscience education but can be a catalyst to increase accessibility and flexibility in instruction permanently. Fortunately, a rich collection of 3D mineral and rock samples is being generated by a community of digital modelers (e.g., Perkins et al., 2019).

Volcanic Record Of The Arc-To-Rift Transition Onshore Of The Guaymas Basin In The Santa Rosalía Area, Gulf Of California, Baja California, Graham Dm Andrews

Faculty & Staff Scholarship

The Gulf of California is an archetype of continental rupture through transtensional rifting, and exploitation of a thermally weakened arc to produce a rift. Volcanic rocks of central Baja California record the transition from calcalkaline arc magmatism, due to subduction of the Farallon plate (ca. 24–12 Ma), to rift magmatism, related to the opening of the Gulf of California (<12 Ma). In addition, a suite of postsubduction rocks (<12 Ma), referred to as “bajaites,” are enriched in light rare-earth and other incompatible elements (e.g., Ba and Sr). These are further subdivided into high-magnesian andesite (with 50%–58% SiO2 and MgO >4%) and adakite (>56% SiO2 and MgO <3%). The bajaites correlate spatially with a fossil slab imaged under central Baja and are inferred to record postsubduction melting of the slab and subduction-modified mantle by asthenospheric upwelling associated with rifting or slab breakoff. We report on volcanic rocks of all three suites, which surround and underlie the Santa Rosalía sedimentary rift basin. This area represents the western margin of the Guaymas basin, the most magmatically robust segment of the Gulf of California rift, where seafloor spreading occurred in isolation for 3–4 m.y. (starting at 6 Ma) before transtensional pull-apart basins to the north and south ruptured the continental crust. Outcrops of the Santa Rosalía area thus offer the opportunity to understand the magmatic evolution of the Guaymas rift, which has been the focus of numerous oceanographic expeditions.

We describe 21 distinct volcanic and hypabyssal map units in the Santa Rosalía area, using field characteristics, petrographic data, and major- and trace-element geochemical data, as well as zircon isotopic data and …

Subsurface Analytics: Contribution Of Artificial Intelligence And Machine Learning To Reservoir Engineering, Reservoir Modeling, And Reservoir Management, Shahab D. Mohaghegh

Faculty & Staff Scholarship

Subsurface Analytics is a new technology that changes the way reservoir simulation and modeling is performed. Instead of starting with the construction of mathematical equations to model the physics of the fluid flow through porous media and then modification of the geological models in order to achieve history match, Subsurface Analytics that is a completely AI-based reservoir simulation and modeling technology takes a completely different approach. In AI-based reservoir modeling, field measurements form the foundation of the reservoir model. Using data-driven, pattern recognition technologies; the physics of the fluid flow through porous media is modeled through discovering the best, most …

The Effects Of Environmental Restoration On Housing Prices In Northern Colorado, Jack Steketee

Capstones and Honors Theses

Hedonic valuation is a method of using a market, such as the housing market, to estimate the value of non-market goods. An example of a non-market good we might want to value is environmental quality. Proper valuation of the environment can help make informed policy decisions, as well as help better protect or restore it. We use the hedonic valuation model This research uses data from a housing market in Colorado to estimate the value homeowners place on an environmental restoration project. We hypothesized that overall, we would see an increase in home value after a restoration project was completed …

Paleohydrology And Machine-Assisted Estimation Of Paleogeomorphology Of Fluvial Channels Of The Lower Middle Pennsylvanian Allegheny Formation, Birch River, Wv, Oluwasegun O. Abatan, Amy Weislogel

Faculty & Staff Scholarship

Rivers transport sediments in a source to sink system while responding to allogenic controls of the depositional system. Stacked fluvial sandstones of the Middle Pennsylvanian (Desmoinesian Stage, ∼310–306 Ma) Allegheny Formation (MPAF) exposed at Birch River, West Virginia exhibit change in sedimentary structure and depositional style, reflecting changes in allogenic behavior. Paleohydrologic and numerical analysis were used to quantify geomorphological and paleohydrologic variations reflected by MPAF fluvial deposits with the goal of understanding the controls on resulting fluvial sandstone architecture in these different systems. Channel body geometry, sedimentary structures, and sandstone grain size distribution were used to reconstruct the paleoslope …

Integrated Techno-Economic And Life Cycle Analyses Of Biomass Utilization For Value-Added Bioproducts In The Northeastern United States, Yuxi Wang

Graduate Theses, Dissertations, and Problem Reports

A multi-stage spatial analysis was first conducted to select locations for lignocellulosic biomass-based bioproduct facility, using Geographical Information System (GIS) spatial analysis, multi-criteria analysis ranking algorithm, and social-economic assessment. A case study was developed to determine locations for lignocellulosic biorefineries using feedstocks including forest residue biomass and three energy crops for 13 states in the northeastern United States. In the entire study area, 11.1% of the counties are high-suitable, 48.8% are medium-suitable for biorefinery siting locations. A non-parametric analysis of cross-group surveys showed that preferences on biorefinery siting are homogeneous for experts in academia and industry groups, but people in …

The Transition From Planar To En Echelon Morphology In A Single Vein In Shale: Insights From X-Ray Computed Tomography Scanning, Graham Dm Andrews, Sarah R. Brown, Johnathan Moore, Dustin Crandall, Paige Mackey

Faculty & Staff Scholarship

En echelon fractures and veins are among the most common and distinctive geological structures, yet their three-dimensional forms and relationships to surrounding structures are commonly unclear. X-ray computed tomography (CT) offers an unrivaled ability to examine structures within rocks in three dimensions, and it is applied here to a sample of drill core from the Marcellus Shale of southwestern Pennsylvania (USA). CT images yield qualitative and quantitative data on the transition from a pyrite-rich planar vein to an en echelon veinlet array, and on the heterogeneity of veinlets within the array. Using a combination of three- and two-dimensional images, geometric …

Household Water Security: An Analysis Of Water Affect In The Context Of Hydraulic Fracturing In West Virginia, Appalachia, Bethani Turley, Martina Angela Caretta

Faculty & Staff Scholarship

Hydraulic fracturing has been booming in the last decade in the United States. While natural gas extraction and production has improved the national energy security, it has raised questions around the water security of those communities where extraction is taking place. Both scientists and residents are concerned about hydraulic fracturing’s impacts on surface- and groundwater, especially regarding how hydraulic fracturing impacts residents’ access to safe household well water. In the past decade, the Marcellus Shale has been developed in Northwestern West Virginia, yet the human geography dimensions of oil and gas extraction in West Virginia remain to be investigated. This …

Searches For Fast Radio Bursts Using Machine Learning, Devansh Agarwal

Graduate Theses, Dissertations, and Problem Reports

Fast Radio bursts (FRBs) are enigmatic astrophysical events with millisecond durations and flux densities in the range 0.1-100 Jy, with the prototype source discovered by Lorimer et al. (2007). Like pulsars, FRBs show the characteristic inverse square sweep in observing frequency due to propagation through an ionized medium. This effect is quantified by the dispersion measure (DM). Unlike pulsars, FRBs have anomalously high DMs, which are consistent with an extragalactic origin. Over 100 FRBs have been published at the time of writing, and 13 have been conclusively identified with host galaxies with spectroscopically determined redshifts in the range 0.003 ≤ …

Development And Implementation Of A Novel Voltage-Free Interface For Capillary Electrophoresis-Mass Spectrometry Separations Of Proteins, Courtney J. Kristoff

Graduate Theses, Dissertations, and Problem Reports

Capillary electrophoresis-mass spectrometry is a powerful technique for high-throughput and high efficiency separations combined with structural identification. Electrospray ionization is the primary interface used to couple capillary electrophoresis to mass analyzers; however, improved designs continue to be reported. A new interfacing method based on vibrating sharp-edge spray ionization is presented in this work to overcome the challenges of decoupling applied voltages and to enhance the compatibility with separations performed at near-neutral pH. The versatility and ease of use of this ionization source is demonstrated using β-blockers, peptides, and proteins. The cationic β-blocker pindolol was injected electrokinetically and detected at concentrations …

Genetic Algorithms Used For Search And Rescue Of Vulnerable People In An Urban Setting, Shuhad Aljandeel

Graduate Theses, Dissertations, and Problem Reports

The main goal of this research is to design and develop a genetic algorithm (GA) for path planning of an Unmanned Aerial Vehicle (UAV) outfitted with a camera to efficiently search for a lost person in an area of interest. The research focuses on scenarios where the lost person is from a vulnerable population, such as someone suffering from Alzheimer or a small child who has wondered off. To solve this problem, a GA for path planning was designed and implemented in Matlab. The area of interest is considered to be a circle that encompasses the distance the person could …

Effects Of Oxygen Modification On The Structural And Magnetic Properties Of Highly Epitaxial La0.7sr0.3mno3 (Lsmo) Thin Films, Shalini Kumari, Navid Mottaghi, Chih-Yeh Huang, Robbyn Trappen, Ghadendra Bhandari, Saeed Yousefi, Guerau Cabrera, Mohindar S. Seehra, Mikel B. Holcomb

Faculty & Staff Scholarship

La0.7Sr0.3MnO3, a strong semi-metallic ferromagnet having robust spin polarization and magnetic transition temperature (TC) well above 300 K, has attracted significant attention as a possible candidate for a wide range of memory, spintronic, and multifunctional devices. Since varying the oxygen partial pressure during growth is likely to change the structural and other physical functionalities of La0.7Sr0.3MnO3 (LSMO) films, here we report detailed investigations on structure, along with magnetic behavior of LSMO films with same thickness (~30 nm) but synthesized at various oxygen partial pressures: 10, 30, 50, 100, 150, 200 and 250 mTorr. The observation of only ( …

Fast Decision-Making Under Time And Resource Constraints, Kyle Gabriel Lassak

Graduate Theses, Dissertations, and Problem Reports

Practical decision makers are inherently limited by computational and memory resources as well as the time available in which to make decisions. To cope with these limitations, humans actively seek methods which limit their resource demands by exploiting structure within the environment and exploiting a coupling between their sensing and actuation to form heuristics for fast decision-making. To date, such behavior has not been replicated in artificial agents. This research explores how heuristics may be incorporated into the decision-making process to quickly make high-quality decisions through the analysis of a prominent case study: the outfielder problem. In the outfielder problem, …

Relating Sonic Velocities, Minimum Horizontal Stress, And Natural Fracture Distribution To Stimulation Efficiency During Completion Of The Marcellus Shale Mip-3h Unconventional Well, West Virginia, Usa, Kaitlin Gayle Evans

Graduate Theses, Dissertations, and Problem Reports

Log data from the Marcellus Shale Energy and Environment Laboratory (MSEEL) was acquired along the lateral of the MIP-3H well. This unconventional shale-gas well was completed within the Marcellus Shale just above the Cherry Valley Limestone, a thin limestone member separating organic rich units of the Marcellus. The geomechanical moduli, Poisson’s Ratio (PR) and Young’s Modulus (YME), were generated using compressional and shear sonic logs to indicate zones of increasing brittleness for each of the 28 stages along the 6124 ft. (1867m) horizontal lateral. Brittle reservoir rock is more readily fractured during hydraulic stimulation than more malleable rock. Stages with …

Circuits And Cycles In Graphs And Matroids, Yang Wu

Graduate Theses, Dissertations, and Problem Reports

This dissertation mainly focuses on characterizing cycles and circuits in graphs, line graphs and matroids. We obtain the following advances.

1. Results in graphs and line graphs. For a connected graph G not isomorphic to a path, a cycle or a K1,3, let pc(G) denote the smallest integer n such that the nth iterated line graph Ln(G) is panconnected. A path P is a divalent path of G if the internal vertices of P are of degree 2 in G. If every edge of P is a cut edge of G, then P is a bridge divalent path of G; …

Cycle Double Covers And Integer Flows, Zhang Zhang

Graduate Theses, Dissertations, and Problem Reports

My research focuses on two famous problems in graph theory, namely the cycle double cover conjecture and the integer flows conjectures. This kind of problem is undoubtedly one of the major catalysts in the tremendous development of graph theory. It was observed by Tutte that the Four color problem can be formulated in terms of integer flows, as well as cycle covers. Since then, the topics of integer flows and cycle covers have always been in the main line of graph theory research. This dissertation provides several partial results on these two classes of problems.

Physical And Chemical Properties Of Clastic Sediments From Two Caves In The Northern Karst Region Of Puerto Rico, Autum R. Downey

Graduate Theses, Dissertations, and Problem Reports

Geochemical properties and organic characteristics are essential to understanding the general depositional dynamics of a cave. Most work on clastic cave sediments focuses on physical properties of sediments. Little work has been done on bulk organic matter and geochemical properties.

This project reports physical and geochemical characterization of cave sediments from two caves in the northern karst region of Puerto Rico: El Tallonal Cave and Cueva Clara. Core and grab samples were collected and analyzed for particle size, total organic carbon, total nitrogen, organic matter characteristics using fluorescence spectroscopy, and major and minor elements using X-ray fluorescence (XRF). The sediments …

Investigating Effects Of Carbonate Minerals On Shale- Hydraulic Fracturing Fluid Interactions In The Marcellus Shale, Brennan Matthew Ferguson

Graduate Theses, Dissertations, and Problem Reports

Natural gas extracted from tight shale formations, such as the Marcellus Shale, represent an important and developing front in energy exploration. By fracturing these formations using pressurized fracturing fluid, previously unobtainable hydrocarbon reserves may be tapped. While pursuing this resource hydraulic fracturing operations leave chemically complex fluids in the shale formation for at least two weeks. This provides a substantial opportunity for the hydraulic fracturing fluid (HFF) to react with the shale formation at reservoir temperature and pressure. In this study, we investigated the effects of the carbonates on shale-HFF reactions with a focus on the Marcellus Shale. We determined …

Relating Recharge Mechanisms To Chemical Changes In An Updip Appalachian Coal Mine Discharge: A Case Study From Lambert Run, West Virginia, Matthew Lewis Bell

Graduate Theses, Dissertations, and Problem Reports

Impaired drainage from active and abandoned mines degrades the water quality of receiving streams and aquifers. Coal mine drainage (CMD) has been studied for decades in Appalachia, but unknowns and uncertainties are still present, including the influence of mine hydrogeology on the outflow chemistry of above-drainage mines. To evaluate the influence of recharge type on above-drainage mine chemistry, samples were collected every two weeks at a CMD outflow treatment system in Harrison County, West Virginia.

Samples were collected to measure geochemical changes taking place in the mine workings and along the flowpath of the passive treatment system. Samples were divided …

Advancing Quantitative Understanding Of Escherichia Coli Concentrations In A Contemporary Mixed Land-Use Watershed, In West Virginia, Usa, Fritz Petersen

Graduate Theses, Dissertations, and Problem Reports

A scarcity of field-based research investigating the relationships between E. coli (fecal matter) concentration, suspended particulate matter (SPM; including size distribution), physicochemical parameters (water temperature, pH, SPC, DO, chloride) and land use practices and the importance of these relationships, particularly for human health, policy makers, and water resource managers, provided the impetus for this research. A 22-site, nested-scale, experimental watershed study design was implemented to investigate E. coli concentrations and the aforementioned relationships in a contemporary mixed land use watershed in the Appalachian region of the eastern United States. Results from a reduced (n=4 sites) study showed SPM in the …

Image And Video-Based Autism Spectrum Disorder Detection Via Deep Learning, Mindi Ruan

Graduate Theses, Dissertations, and Problem Reports

People with Autism Spectrum Disorder (ASD) show atypical attention to social stimuli and aberrant gaze when viewing images of the physical world. However, it is unknown how they perceive the world from a first-person perspective. In this study, we used machine learning to classify photos taken in three different categories (people, indoors, and outdoors) as either having been taken by individuals with ASD or by peers without ASD. Our classifier effectively discriminated photos from all three categories but was particularly successful at classifying photos of people with >80% accuracy. Importantly, the visualization of our model revealed critical features that led …

Genetic And Biochemical Characterization Of Ergot Alkaloid Synthesizing Fungi And Their Symbionts, Matthew Duane Maust

Graduate Theses, Dissertations, and Problem Reports

Ergot alkaloids are fungal tryptophan derived toxins which affect mammalian circulation and neurotransmission. These compounds are biosynthesized by a conserved genetic pathway, known as the ergot alkaloid synthesis (EAS) pathway by fungi belonging to the ascomycete families Trichocomaceae and Clavicipitaceae. Several Ipomoea species and related plants in the morning glory family harbor vertically transmitted symbiotic fungi in the genus Periglandula, also members of Clavicipitaceae, that produce ergot alkaloids. Metabolomic analysis of seeds identified a previously uncharacterized glycoside form of the pharmaceutically important ergot alkaloid, ergonovine. Several species belonging to the fungal genus Metarhizium have recently been shown to have the …

Microbial Responses To Unconventional Oil And Gas Development May Alter Ecosystem Function In Headwater Streams, Rachel Michaels

Graduate Theses, Dissertations, and Problem Reports

The demand for natural gas, and the need for efficient extraction, has led to the development of unconventional oil and natural gas (UOG) techniques. Due to the novelty of UOG, the potential impacts to freshwater ecosystems are not fully understood. We used a dual pronged approach to study the effects of UOG development on microbial biodiversity and function via a laboratory microcosm experiment and a survey study of streams with and without UOG development within their watersheds. The laboratory microcosm study simulated stream contamination with produced water, a byproduct of UOG operation, using sediment collected from one high water-quality stream …

Cobalt-Catalyzed Aerobic Oxidative Cyclization Reactions Of Bisnucleophiles: New Methodologies And The Role Of Bisnucleophiles In O2 Activation, Jiaqi Liu

Graduate Theses, Dissertations, and Problem Reports

Over the past few decades, transition metals have found wide applications in the development of selective oxidative transformations mediated by molecular oxygen. Due to the benign nature of molecular oxygen as an oxidant and an increasing awareness of green chemistry practice, tremendous progress has been made towards the development of Cu-and Pd-catalyzed aerobic oxidation reactions. As a first-row transition metal alternative to copper, cobalt has been employed in aerobic catalytic transformations for its cost-efficiency and earth abundance; however, redox-active mediators such as benzoquinone (BQ), N-hydroxyphthalimide (NHPI) or salen-type ligands are usually required. To date, reactions mediated by Co/O₂ catalytic …

Evaluating The Accuracy Of Firearm Examiner Conclusions Using Cartridge Case Reproductions, Eric Freeman Law

Graduate Theses, Dissertations, and Problem Reports

The forensic science pattern comparison areas, including fingerprints, footwear, and firearms, have been criticized for their subjective nature. While much research has attempted to move these disciplines to more objective methods, a majority of examiners are still coming to conclusions based on their own training and experience. To compare accuracy between examiners, a method called double-casting was used in this study to create plastic cartridge case reproductions. In the first part of this study, double-cast accuracy was evaluated using two automated comparison systems to quantify the similarity. It was determined that the double-casting method used here produces accurate reproductions with …

Protein/Peptide Characterization Using Mass Spectrometry And Molecular Dynamics Simulations, Ahmad Kiani Karanji

Graduate Theses, Dissertations, and Problem Reports

Mass spectrometry (MS) based-techniques and molecular dynamics (MD) simulations have been used to characterize protein/peptide structure as well as their interactions with lipid vesicles and detergents. Chapter 1 introduces an introduction to the concepts and tools that were used in this work. In Chapter 2, the dominant gas-phase conformer of [M+3H]3+ ions of the model peptide Acetyl-PSSSSKSSSSKSSSSKSSSSK are examined with ion mobility spectrometry (IMS), gas-phase hydrogen deuterium exchange (HDX), and mass spectrometry (MS) techniques. This section furthers the development of a protein structural prediction tool by providing information about gas-phase ion conformers of two model peptides having different solution conformational …

Estimating Refactoring Efforts For Architecture Technical Debt, Samir Deeb

Graduate Theses, Dissertations, and Problem Reports

Paying-off the Architectural Technical Debt by refactoring the flawed code is important to control the debt and to keep it as low as possible. Project Managers tend to delay paying off this debt because they face difficulties in comparing the cost of the refactoring against the benefits they gain. For these managers to decide whether to refactor or to postpone, they need to estimate the cost and the efforts required to conduct these refactoring activities as well as to decide which flaws have higher priority to be refactored among others.

Our research is based on a dataset used by other …

A Machine Learning Approach To Estimate The Annihilation Photon Interactions Inside The Scintillator Of A Pet Scanner, Sai Akhil Bharthavarapu

Graduate Theses, Dissertations, and Problem Reports

Biochemical processes are chemical processes that occur in living organisms. They can be studied with nuclear medicine through the help of radioactive tracers. Based on the radioisotope used, the photons that are emitted from the body tissue are either detected by single-photon emission computed tomography (SPECT) or by positron emission tomography (PET) scanners. SPECT uses gamma rays as tracer but gives a weaker contrast and spatial resolution compared to a PET scanner which uses positrons as tracer. PET scans show the metabolic changes occurring at the cellular level in an organ or a tissue. This detection is important because diseases …

Time-Dependent Reliability Framework For Durability Design Of Frp Composites, Rajneesh Kumar Bharil

Graduate Theses, Dissertations, and Problem Reports

The life-cycle performance, durability, and aging characteristics of Fiber Reinforced Polymer (FRP or Structural Composites) have been of keen interest to the engineers engaged in the FRP design, construction, and manufacturing. Unlike conventional construction materials such as steel and concrete, the design guidelines to account for the aging of FRP are somewhat scattered or not available in an approved or consistent format. Loss of strength over time or aging of any structural material should be of concern to engineers as the in-service lifespan of many engineering structures is expected to exceed 100 years. Use of durability strength-reduction factors or factors …