Physical Sciences and Mathematics Commons^™

First-Principles Simulations Of Materials Under Extreme Conditions, Kien Nguyen Cong

USF Tampa Graduate Theses and Dissertations

The investigation of materials at extreme conditions of high pressure and temperature (high-PT), has been one of the greatest scientific endeavors in condensed mater physics, chemistry, astronomy, planetary, and material sciences. Being subjected to high-PT conditions, materials exhibit dramatic changes in both atomic and electronic structure resulting in an emergence of exceptionally interesting phenomena including structural and electronic phase transitions, chemical reactions, and formation of novel compounds with never-previously observed physical and chemical properties. Although new exciting experimental developments in static and dynamic compression combined with new diagnostics/characterization methods allow to uncover new processes and phenomena at high P-T conditions, …

Effects Of Reservoir Conditions And Trace Co-Contaminant Gases On Geological Carbon Sequestration, Ram Kumar

USF Tampa Graduate Theses and Dissertations

Geological carbon sequestration in a saline formation is a promising technology for large-scale carbon dioxide (CO2) mitigation. Several factors such as temperature, pressure, salinity, hydraulic conductivity, and mineralogy of a formation affect the CO2 sequestration in saline formations. These factors can vary widely depending upon the type of formation or the degree of heterogeneity within a formation. In addition to these properties of the repositories, the CO2-rich flue gas streams captured from point sources often contains small amounts of impurities such as sulfur oxides (SOx) and nitrogen oxides (NOx), which may have serious implications on the chemistry of the repositories …

Fabrication And Characterization Of Electrical Energy Storage And Harvesting Energy Devices Using Gel Electrolytes, Belqasem Aljafari

USF Tampa Graduate Theses and Dissertations

Redox-active materials in the bulk of gel electrolytes are unquestionably holding the primary roles in developing energy harvesting and storage technology. Both technologies are necessary in order to cope with the current challenges of the environmental crises of global warming and finite non-renewable sources while the demand for energy modern societies have been speedily increased. One of the most challenges of making a hybrid device of energy conversion and storage is the cost of the fabrication process. Therefore, gel electrolyte-based materials with redox-active properties can potentially be a promising solution to improve the performance of electrochemical and photoelectrochemical devices for …

Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations, Yasin Kocak

USF Tampa Graduate Theses and Dissertations

High density polyethylene (HDPE) geomembrane is most common geomembrane which is mainly used for civil engineering applications. However, HDPE geomembrane loses its properties under oxidative degradation progress. This study aims to assess geomembranes which have different percentage of phenolic antioxidant and hindered amine light stabilizer (HALS) with under the six months of the thermal-oxidative degradation. The interactions between phenolic antioxidant, HALS and carbon black can affect the mechanical, physical and chemical properties. To monitor these properties, Differential Scanning Calorimetry (DSC), Fourier-transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy coupled with Energy Dispersive X-ray spectroscopy (SEM/EDX), Melt Index tests, …

Modeling Of Buildings With Electrochromic Windows And Thermochromic Roofs, Hua-Ting Kao

USF Tampa Graduate Theses and Dissertations

Air conditioning and heating have increased substantially during the past two decades. According to a survey, buildings consume about 73% of the total electricity in the United States, accounting for 41% of all other energy in the world. At the same time, building skin technologies are constantly improving. Electrochromic and thermochromic are two exciting new technologies that can help reduce the energy consumption of a building. The purpose of this work is to increase our understanding of how much the use of electrochromic (EC) and thermochromic (TC) technologies can reduce the energy consumption of residential and commercial buildings in two …

A Gpu-Based Framework For Parallel Spatial Indexing And Query Processing, Zhila Nouri Lewis

USF Tampa Graduate Theses and Dissertations

Support for efficient spatial data storage and retrieval have become a vital component in almost all spatial database systems. Previous work has shown the importance of using spatial indexing and parallel computing to speed up such tasks. While GPUs have become a mainstream platform for high-throughput data processing in recent years, exploiting the massively parallel processing power of GPUs is non-trivial. Current approaches that parallelize one query at a time have low work efficiency and cannot make good use of GPU resources. On the other hand, many spatial database applications are busy systems in which a large number of queries …

Statistical Learning Of Biomedical Non-Stationary Signals And Quality Of Life Modeling, Mahdi Goudarzi

USF Tampa Graduate Theses and Dissertations

Statistical learning is a set of tools for modeling and understanding complex datasets. It is a recently developed area in statistics and blends with parallel developments in computer science and, in particular, machine learning.

The classification of biomedical non-stationary signals such as Electroencephalogram (EEG) is always a challenging problem due to their complexity. The low spatial resolution on the scalp, curse of dimensionality, poor signal-to-noise ratio are disadvantages of working with biomedical signals. EEG signals are unstructured data which needs preprocessing steps to extract informative features which are measurable and predictive. In the first two chapters of this dissertation, EEG …

Design Of Variable Wall Thickness Geometry And Performance Mapping Of Scroll Expanders For Distributed Power Generation, Arun Kumar Narasimhan

USF Tampa Graduate Theses and Dissertations

Low-temperature heat sources such as industrial waste heat, solar, and geothermal are more suitable for small-scale power generation rather than utility scale. In order to maximize the electricity generated from low-temperature heat sources, an efficient expansion device for small-scale power output is necessary. This research work has focused on evaluating the use of a scroll expander and improving its geometrical design for the power output range of 1-25 kW_e.

The first part of the work focusses on modeling the performance of a scroll expander using two non-dimensionless parameters, namely, specific speed and specific diameter. Performance of a scroll …

A Decision-Making Framework For Hybrid Resource Recovery Oriented Wastewater Systems, Nader Rezaei

USF Tampa Graduate Theses and Dissertations

Water shortage, water contamination, and the emerging challenges in sustainable water resources management (e.g., the likely impacts of climate change and population growth) necessitate adopting a reverse logistics approach, which is the process of moving wastewater from its typical final destination back to the water supply chain for reuse purposes. This practice not only reduces the negative impacts of wastewater on the environment, but also provides an alternative to withdrawal from natural water resources, forming a closed-loop water supply chain. However, the design of such a supply chain requires an appropriate sustainability assessment, which simultaneously accounts for economic, environmental, and …

Prioritizing Rehabilitation Of Sanitary Sewers In Pinellas County, Fl, Jesse T. Hillman

USF Tampa Graduate Theses and Dissertations

Following large rain events, extraneous freshwater contributions known as inflow and infiltration (I/I) bypass the storm sewer and enter the sanitary sewer system. In areas with a high water table, like Pinellas County and the surrounding Tampa Bay area, a majority of the wastewater infrastructure is submerged year round exacerbating the rate of groundwater infiltration. This excess flow overloads the existing wastewater infrastructure leading to sanitary sewer overflows (SSOs). These SSOs result in serious problems for municipalities and utilities across the country.

This study was performed in order to assist Pinellas County Utilities in rehabilitating their southern sewer system. To …

Authentication And Sql-Injection Prevention Techniques In Web Applications, Cagri Cetin

USF Tampa Graduate Theses and Dissertations

This dissertation addresses the top two “most critical web-application security risks” by combining two high-level contributions.

The first high-level contribution introduces and evaluates collaborative authentication, or coauthentication, a single-factor technique in which multiple registered devices work together to authenticate a user. Coauthentication provides security benefits similar to those of multi-factor techniques, such as mitigating theft of any one authentication secret, without some of the inconveniences of multi-factor techniques, such as having to enter passwords or biometrics. Coauthentication provides additional security benefits, including: preventing phishing, replay, and man-in-the-middle attacks; basing authentications on high-entropy secrets that can be generated and updated automatically; …

Phase Evolution And Dynamic Behavior In Materials With Noncollinear Spin Textures, Eleanor M. Clements

USF Tampa Graduate Theses and Dissertations

Noncentrosymmetric magnetic materials have gained special attention due to their ability to stabilize topologically nontrivial magnetic states via the competition between symmetric exchange and the antisymmetric Dzyaloshinskii-Moriya (DM) interaction. The spin struc- tures in these materials have become a center of interest for spintronics applications due to their stable, particle-like properties, and high degree of tunability via control of external parameters, such as magnetic and/or electric field and temperature. Understanding how these robust magnetic structures stabilize, evolve, dynamically respond, and adhere to existing models, all in the presence of external stimuli, are topics of fundamental interest. In this dissertation, the …

Essays On Time Series And Machine Learning Techniques For Risk Management, Michael Kotarinos

USF Tampa Graduate Theses and Dissertations

The Capital Asset Pricing Model combined with the Sharpe ratio is a standard method for choosing assets for selection in a portfolio. However, this method has many structural issues and was designed for a time when high dimensional computing was in its infancy. An alternative to these methods using a mix of Multi-Level Time Series Clustering, the MACBETH algorithm and traditional time series techniques was constructed that minimized data loss and allow for customized portfolio construction for investors with different risk profiles and specialized investment needs. It was shown that these methods are adaptable to cloud computing environments and allow …

Robotic Motion Generation By Using Spatial-Temporal Patterns From Human Demonstrations, Yongqiang Huang

USF Tampa Graduate Theses and Dissertations

Robots excel in manufacturing facilities because the tasks are repetitive and do not change. However, when the tasks change, which happens in almost all tasks that humans perform daily, such as cutting, pouring, and grasping, etc., robots perform much worse. We aim at teaching robots to perform tasks that are subject to change using demonstrations collected from humans, a problem referred to as learning from demonstration (LfD).

LfD consists of two parts: the data of human demonstrations, and the algorithm that extracts knowledge from the data to perform the same motions. Similarly, this thesis is divided into two parts. The …

Force Feedback And Intelligent Workspace Selection For Legged Locomotion Over Uneven Terrain, John Rippetoe

USF Tampa Graduate Theses and Dissertations

Legged robots present an incredible opportunity for humanity to conduct dangerous operations such as search and rescue, disaster recovery, and planetary exploration without ever placing themselves in harms way. The ability of a leg to more freely dictate its shape, orientation, and length gives it tremendous mobility and adaptability demanded of a system intended for operation outside of a controlled environment. However, one only need look at the average cat, dog, or friendly neighborhood squirrel to understand the immense gap that exists between what is possible of legged systems and their current set of capabilities.

Areas of study relevant to …

Conducting Polymer Based Gel Electrolytes For Ph Sensitivity, Aditya Jagannath Kashyap

USF Tampa Graduate Theses and Dissertations

The evaluation of concentration of ions and molecules with the help of biosensors have been regarded as an emerging technology. Bio and chemical sensors have a variety of applications in the field of medicine, military, environmental and food industries alike. With an estimated investment growth of over 4.31% in the development of pH sensors in the next five year, the objective of a developing a robust measurement system is all the more required. The scope of this research is to evaluate the ability of conducting polymer-based gel electrolytes for pH sensitivity, as a function of the transistor characteristics using an …

Modeled Affinity Constants For Phosphorus Adsorption And Desorption Due To Saltwater Intrusion, Yasemin Taşcı

USF Tampa Graduate Theses and Dissertations

It is important to understand the processes that regulate phosphorus (P) fluxes to coastal environments, because P is an important nutrient in coastal ecosystems. Phosphorus adsorbs to the surface of minerals in sediment and bedrock, and an influx of seawater can cause some of that P to desorb, raising the P concentration of ambient water. Although seawater-induced P desorption is thought to be an important source of P to coastal environments, the chemical reactions that underlie it have not been established. Previous work provides some relevant surface reactions and associated affinity constants between various aqueous P species and the surface …

Absorber And Window Study – Cdsexte1-X/Cdte Thin Film Solar Cells, Chih-An Hsu

USF Tampa Graduate Theses and Dissertations

CdTe an II-VI semiconductor has been a leading thin film photovoltaic material due to its near ideal bandgap and high absorption coefficient [1]. The typical thin film CdTe solar cells have been of the superstrate configuration with CdS (Eg-2.42eV) as the n-type heterojunction partner. Due to the relatively narrow bandgap of CdS, a wider bandgap n-type window layer has recently emerged as a promising substitute: alloys of MgyZn1-yO have been successfully used as the emitter or window layer. The benefits in the usage of MgyZn1-yO (MZO) are its tunable bandgap and wide optical spectrum on optoelectronic devices. Due to an …