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Full-Text Articles in Physical Sciences and Mathematics

Electrical Resistivity Of Nickel, Iron And Iron-Silicon Alloy Melts At High Pressure With Implications For The Thermal Conductivity Of The Earth’S Core, Reynold E. Silber Dec 2018

Electrical Resistivity Of Nickel, Iron And Iron-Silicon Alloy Melts At High Pressure With Implications For The Thermal Conductivity Of The Earth’S Core, Reynold E. Silber

Electronic Thesis and Dissertation Repository

The Earth’s liquid outer core (OC) is composed of Fe alloyed with up to 10% Ni and a small fraction of light elements. However, the effect of light elements such as Si on the transport properties of liquid Fe-alloy in Earth’s OC is not clear. Thermal conductivity (κ) and related electrical resistivity (ρ) are the least constrained parameters in OC. Therefore, the characterization of transport properties of Ni, Fe and Fe-Si at high pressure has important geophysical implications for the Earth’s core. The ρ of solid and liquid Ni, Fe and Fe 4%Si was measured at …


Pressure Tuning Of Energy Storage Materials Probed By In-Situ Vibrational Spectroscopy And Synchrotron Radiation, Pan Wang Oct 2018

Pressure Tuning Of Energy Storage Materials Probed By In-Situ Vibrational Spectroscopy And Synchrotron Radiation, Pan Wang

Electronic Thesis and Dissertation Repository

Clean and renewable energy has drawn much attention recently due to the increasing demand for more energy and environmental issues. New materials have been developed and the improved performance of such materials have been achieved in the past decades. It has been proved that application of external high pressure can significantly tune the structure of materials. Consequently, the properties of the materials could also be modified. Therefore, in this thesis, we focused on the high-pressure studies of two classes of energy storage materials, hydrogen storage materials and solar cell materials. Ammonia borane (AB) has been extensively investigated as an excellent …