Physical Sciences and Mathematics Commons^™

Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. We assayed dissolved nutrient levels in surface and subsurface waters of Eastern Kentucky University’s Meadowbrook Farm in order to assess levels of dissolved nutrients leaving its farmland and draining into the Muddy Creek watershed. The Farm raises both crops and livestock so that nutrient sources include fertilizer and manure. We sampled springs, runoff, and subsurface pipe drainage as well as Muddy Creek on six days from May to August 2016 under a variety of weather conditions. Using established, standard colorimetric methods, we measured nitrate (NO …

Geochemical Characteristics And Storm Dynamics Of Surface Waters And Groundwater At Eastern Kentucky University’S Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. Eastern Kentucky University’s Meadowbrook Farm raises crops and livestock, contributing dissolved nutrients to the neighboring Muddy Creek watershed. Consequently, the Farm is developing methods to sequester and limit nutrient contamination.

Before phosphorous sequestration methods can be tested, the geochemistry of surface water and groundwater on the Farm need to be better understood to determine hydrological pathways. We use naturally-occurring, dissolved cations as tracers to identify the contribution of different water sources and interpret storm events.

Water samples taken from springs (groundwater), surface water, and storm …

Diurnal And Seasonal Variation In Groundwater Nitrate -N Concentration In A Saturated Buffer Zone, Joseph Miller

Theses and Dissertations

Surface water pollution by nitrate (NO3-) is identified as a critical problem in agricultural land-use areas. Excess NO3- loading causes eutrophication and hypoxia in near-shore marine waters such as the Gulf of Mexico. Diversion of agricultural runoff into saturated buffer zones reduces NO3- loading. Although the mechanisms responsible for NO3- reduction in saturated buffer zones are well characterized, little is known about how NO3- concentrations vary temporally and what factors control those changes. The objective of this study is to understand NO3- concentration and environmental factor variability in a saturated buffer zone on a diurnal scale within and among the …

Nitrate Leaching From Sand And Pumice Geomedia Amended With Pyrogenic Carbon Materials, Jihoon Kang, Marissa Davila, Sergio Mireles, Jungseok Ho

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

There is increasing interest in using pyrogenic carbon as an adsorbent for aqueous contaminants in stormwater. The objective of this study was to investigate pyrogenic carbon materials as an amendment to geomedia to reduce nitrate leaching. Batch adsorption and column experiments were conducted to evaluate the performance of a commercial activated carbon and two biochars incorporated (5% by weight) into sand and pumice columns. The batch adsorption with 50 mg L−1 of nitrate solution showed that only activated carbon resulted in a substantial adsorption for nitrate up to 41%. Tested biochars were not effective in removing aqueous nitrate and even …

Groundwater Vulnerability Assessment For Nitrate Pollution In The Salinas Valley Using A Modified Drastic Model, Bernadette Boyle

Master's Projects and Capstones

Groundwater is an integral piece of California’s groundwater resources. One of the most common contaminants present in groundwater is nitrate. Nitrate contamination is often a result of agricultural land use activities on the ground surface. The study area for this analysis is the Salinas Valley Groundwater Basin, an agriculturally dominated basin in coastal California. The Salinas Valley Basin is both one of the most agriculturally productive areas of the state, as well as one of the most nitrate-contaminated basins in the state. The purpose of this research was to develop a groundwater vulnerability map for nitrate pollution in the Salinas …

Riparian Buffered Sinkholes In The Blue River Watershed, Colin Copler

Undergraduate Theses

Riparian vegetation along streams has many positive effects on water quality and macroinvertebrate communities, especially in agricultural areas. Some of these effects include erosion prevention, pollutant removal, and lower summer water temperatures. There has been much research done examining the link between these riparian areas and streams; however, riparian vegetation is understudied in karst areas. Karst is a geologic formation that is composed of limestone, which dissolves in groundwater, forming sinkholes. Thus, the question this paper seeks to investigate is does riparian vegetation around sinkholes in a karst plain influence water quality within a watershed? Water quality, land cover, and …

Nutrient Loading Reduction In A Tile Drained Agricultural Watershed Through Watershed-Scale Cover Cropping: A High Resolution Analysis, Benjamin Gerald Bruening

Theses and Dissertations

Nutrient pollution originating from agricultural regions in the Midwest is a serious issue, leading to pollution of drinking water sources as well as large hypoxic zones in the Gulf of Mexico. The source of much of this contamination has been shown to be runoff from agricultural fields in the Upper Mississippi River Basin. One method that has been shown to reduce this pollution from the Upper Mississippi River Basin is the planting of winter cover crops. Winter cover crops such as rye and tillage radish have been shown to significantly reduce nitrate exported from agricultural fields, even in tile-drained watersheds …

Dynamics Of Nitrate, Phosphorus, And Suspended Sediment Transport In Two Agricultural Streams In Central Illinois, Luke W. Lampo

Theses and Dissertations

Nutrients such as nitrate and phosphorus are necessary for life, but excessive amounts can be detrimental. Large amounts of nutrients entering bodies of water can lead to hypoxic zones such as the one in the Gulf of Mexico. Nutrients are also problematic in drinking water reservoirs, as high concentrations of nitrate in drinking water can cause health conditions such as blue baby syndrome and high phosphorus concentrations can lead to algal blooms. Suspended sediment leads to reservoir sedimentation, habitat degradation, and is able to transport particulate nutrients. High nutrient and sediment concentrations are a recurring problem in the drinking water …

Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. We assayed dissolved nutrient levels in surface and subsurface waters of Eastern Kentucky University’s Meadowbrook Farm in order to assess levels of dissolved nutrients leaving its farmland and draining into the Muddy Creek watershed. The Farm raises both crops and livestock so that nutrient sources include fertilizer and manure. We sampled springs, runoff, and subsurface pipe drainage as well as Muddy Creek on six days from May to August 2016 under a variety of weather conditions. Using established, standard colorimetric methods, we measured nitrate (NO …

Assessing The Potential To Decrease The Gulf Of Mexico Hypoxic Zone With Midwest Us Perennial Cellulosic Feedstock Production, Andy Vanloocke, Tracy E. Twine, Christopher J. Kucharik, Carl J. Bernacchi

Andy VanLoocke

The goal of this research was to determine the changes in streamflow, dissolved inorganic nitrogen (DIN) leaching and export to the Gulf of Mexico associated with a range of large-scale dedicated perennial cellulosic bioenergy production scenarios within in the Mississippi–Atchafalaya River Basin (MARB). To achieve this goal, we used Agro-IBIS, a vegetation model capable of simulating the biogeochemistry of row crops, miscanthus and switchgrass, coupled with THMB, a hydrology model capable of simulating streamflow and DIN export. Simulations were conducted at varying fertilizer application rates (0–200 kg N ha -1) and fractional replacement (5–25%) of current row crops with miscanthus …

Nitrate Loading In The Saw Kill Watershed: Small Watershed Nutrient Dynamics, Answering A Community Question, And Assessing Methodological Approaches, Marco Sebastian Spodek

Senior Projects Spring 2017

Biogeochemical cycles mitigate the movement of nutrients through ecosystems at a variety of scales. Within aquatic systems, nitrogen (N) and phosphorus (P) are especially critical due to their high influence on primary production and decomposition. However, in excess, N and P can pose hazardous ecological effects downstream. Excessive loading of both N and P to waterways can facilitate harmful algal blooms or dead zones in reservoirs and at drainage points. Extensive research over the past half century has shown that the majority of nutrient loading to aquatic systems is the result of anthropogenic land use. While the effects of these …

Isotope Investigation Of Nitrate In Soils And Agricultural Drain Waters Of The Lower Yakima Valley, Washington, Dallin Jensen

All Master's Theses

Nitrate in the groundwater of the Lower Yakima Valley, Washington has long been known to frequently exceed the EPA maximum contaminant level standard for potable water (10 mg/L), adversely impacting communities with disadvantaged socio-economic status. In this research, nitrogen and oxygen isotopic signatures were determined for nitrate soil leachates and irrigation return flow collected in the Lower Yakima Valley, Washington and compared to previous isotopic studies of nitrate in Central Washington. δ¹⁵N, δ¹⁸O and Δ¹⁷O values are used to constrain sources of to groundwater. Isotope signatures for nitrate from soil leachate largely overlapped with …