Physical Sciences and Mathematics Commons^™

Odu Scientists Address Antarctic Ice Melt Affecting Sea Levels, Miasia Osbey

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Selenium Distribution And Cycling In The Eastern Equatorial Pacific Ocean, Zoe Wambaugh

OES Theses and Dissertations

Oxygen minimum zones in oceanic waters have become increasingly important to the marine environment and society. Low oxygen waters affect not only the distribution and abundance of marine organisms, but also impact the solubility and transport of trace elements that are of biological importance, with the chemical speciation and solubility depending on the actual redox poise of the waters. One redox sensitive trace element of interest is selenium, which can be both toxic and essential for organisms, depending on its chemical speciation. In 2013, the US GEOTRACES program completed the GP16 transect from Peru to Tahiti, going through the oxygen …

Precipitation And Sea Level Rise Impacts On Groundwater Levels In Virginia Beach, Virginia, Brett A. Buzzanga

OES Theses and Dissertations

Global sea level rise (SLR) is one of the most immediate impacts of climate change, and poses a significant threat to low-lying coastal communities worldwide. The metropolitan region of Hampton Roads in Southeastern Virginia is one such community, and one where knowledge surrounding SLR is rapidly accumulating. However, most of the research is focused exclusively on surface water processes despite the presence of a shallow groundwater table closely connected to them. SLR will continue to cause the groundwater table to increase in tidally influenced areas of Hampton Roads, and thereby decrease storage capacity of the unsaturated zone.

This study investigates …

A Near-Global Atmospheric Distribution Of N2o Isotopologues, Peter F. Bernath, Mahdi Yousefi, Eric Buzan, Chris D. Boone

Chemistry & Biochemistry Faculty Publications

The distributions of the four most abundant isotopologues and isotopomers (N₂O, ¹⁵NNO, N¹⁵NO, and NN¹⁸O of nitrous oxide have been measured in the Earth's stratosphere by infrared remote sensing with the Atmospheric Chemistry Experiment (ACE) Fourier transform spectrometer. These satellite observations have provided a near-global picture of N₂O isotopic fractionation. The relative abundances of the heavier species increase with altitude and with latitude in the stratosphere as the air becomes older. The heavy isotopologues are enriched by 20-30% in the upper stratosphere and even more over the poles. These observations are …

Robustness Of Observation-Based Decadal Sea Level Variability In The Indo-Pacific Ocean, A. G. Nidheesh, M. Lengaigne, J. Vialard, T. Izumo, A. S. Unnikrishnan, B. Meyssignac, B. Hamlington, C. De Boyer Montegut

OES Faculty Publications

We examine the consistency of Indo-Pacific decadal sea level variability in 10 gridded, observation-based sea level products for the 1960-2010 period. Decadal sea level variations are robust in the Pacific, with more than 50% of variance explained by decadal modulation of two flavors of El Nino-Southern Oscillation (classical ENSO and Modoki). Amplitude of decadal sea level variability is weaker in the Indian Ocean than in the Pacific. All data sets indicate a transmission of decadal sea level signals from the western Pacific to the northwest Australian coast through the Indonesian throughflow. The southern tropical Indian Ocean sea level variability is …

Separating Decadal Global Water Cycle Variability From Sea Level Rise, B. D. Hamlington, J. T. Reager, M.-H. Lo, K. B. Karnauskas, R. R. Leben

CCPO Publications

Under a warming climate, amplification of the water cycle and changes in precipitation patterns over land are expected to occur, subsequently impacting the terrestrial water balance. On global scales, such changes in terrestrial water storage (TWS) will be reflected in the water contained in the ocean and can manifest as global sea level variations. Naturally occurring climate-driven TWS variability can temporarily obscure the long-term trend in sea level rise, in addition to modulating the impacts of sea level rise through natural periodic undulation in regional and global sea level. The internal variability of the global water cycle, therefore, confounds both …

Groundwater And Tidal Controls On Wetland Hydrology, Julie J. Metz Wetland Mitigation Bank, Woodbridge, Virginia, Benjamin Stuart Hiza

OES Theses and Dissertations

Julie J. Metz Wetlands Mitigation Bank, a 92-hectare freshwater wetland located in Woodbridge, Virginia, borders the tidally-influenced Neabsco Creek. Seven pods separated by earthen berms were built by Wetland Studies and Solutions Inc. (WSSI) in 1995 and 1997 by removing the toe of small sandy alluvial fans and covering the underlying coarse gravel bed with a low permeability cap. The basal Quaternary gravels were deposited in a creek valley incised into a thick sand-and-clay Cretaceous delta. The alluvial-fan apron developed at the base of steep slopes along the sides of the valley. Pressure transducer data from five monitoring wells along …

Hydrologic Response Caused By Wetland Expansion At Huntley Meadows Park In Hybla Valley, Virginia, Stephen Fraser Stone

OES Theses and Dissertations

The goal of this study was to understand the effects of wetland expansion across a watershed. The 2013 restoration and expansion of the wetlands at Huntley Meadows Park (Fairfax County, VA) performed by Wetland Studies and Solutions, Inc. provided the opportunity to study this process. The 630 ha park contains more than 364 ha of freshwater emergent and freshwater forested wetlands. The restoration and expansion project used a subsurface vinyl-piling dam that impedes groundwater flow leaving the wetland, thus expanding the existing pond and the surrounding wetland.

This study used a network of more than twenty monitoring instruments making observations …

Alicyclic And Aromatic Carboxylic Acids In Soil Organic Matter: An Investigation Of Potential Origin And Association With Plutonium Using Advanced Analytical Techniques, Nicole Didonato

Chemistry & Biochemistry Theses & Dissertations

Carboxylic acids are a defining component of soil organic matter, responsible for many of the physical and chemical properties, including metal-organic matter interactions, which govern its role as an important constituent of soils. However, there is a shortage of detailed molecular level information regarding orientation and structural arrangement of carboxylic acids within soil organic matter. This dissertation utilizes electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICRMS) as well as solid-state and multi-dimensional nuclear magnetic resonance (NMR) to investigate the molecular formula composition within several organic matter sources and the primary structures that feature carboxylic acids. Soil organic matter …

Multiple Metabolisms Constrain The Anaerobic Nitrite Budget In The Eastern Tropical South Pacific, Andrew R. Babbin, Brian D. Peters, Calvin W. Mordy, Brittany Widner, Karen L. Casciotti, Bess B. Ward

OES Faculty Publications

The Eastern Tropical South Pacific is one of the three major oxygen deficient zones (ODZs) in the global ocean and is responsible for approximately one third of marine water column nitrogen loss. It is the best studied of the ODZs and, like the others, features a broad nitrite maximum across the low oxygen layer. How the microbial processes that produce and consume nitrite in anoxic waters interact to sustain this feature is unknown. Here we used ¹⁵N-tracer experiments to disentangle five of the biologically mediated processes that control the nitrite pool, including a high-resolution profile of nitrogen loss rates. …

Dependence Of The Martian Radiation Environment On Atmospheric Depth: Modeling And Measurement, Jingnan Guo, Tony C. Slaba, Cary Zeitlin, Robert F. Wimmer-Schweingruber, Francis F. Badavi, Eckart Böhm, Stephan Böttcher, David E. Brinza, Bent Ehresmann, Donald M. Hassler

Physics Faculty Publications

The energetic particle environment on the Martian surface is influenced by solar and heliospheric modulation and changes in the local atmospheric pressure (or column depth). The Radiation Assessment Detector (RAD) on board the Mars Science Laboratory rover Curiosity on the surface of Mars has been measuring this effect for over four Earth years (about two Martian years). The anticorrelation between the recorded surface Galactic Cosmic Ray-induced dose rates and pressure changes has been investigated by Rafkin et al. (2014) and the long-term solar modulation has also been empirically analyzed and modeled by Guo et al. (2015). This paper employs the …

Widespread Infilling Of Tidal Channels And Navigable Waterways In The Human-Modified Tidal Deltaplain Of Southwest Bangladesh, C. Wilson, S. Goodbred, C. Small, J. Gilligan, S. Sams, B. Mallick, R. Hale

OES Faculty Publications

Since the 1960s, ~5000 km² of tidal deltaplain in southwest Bangladesh has been embanked and converted to densely inhabited, agricultural islands (i.e., polders). This landscape is juxtaposed to the adjacent Sundarbans, a pristine mangrove forest, both well connected by a dense network of tidal channels that effectively convey water and sediment throughout the region. The extensive embanking in poldered areas, however, has greatly reduced the tidal prism (i.e., volume of water) transported through local channels. We reveal that >600 km of these major waterways have infilled in recent decades, converting to land through enhanced sedimentation and the direct blocking …

New And Improved Infra-Red Absorption Cross Sections And Ace-Fts Retrievals Of Carbon Tetrachloride (Ccl4), Jeremy J. Harrison, Christopher D. Boone, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

Carbon tetrachloride (CCl₄) is one of the species regulated by the Montreal Protocol on account of its ability to deplete stratospheric ozone. As such, the inconsistency between observations of its abundance and estimated sources and sinks is an important problem requiring urgent attention (Carpenter et al., 2014) [5]. Satellite remote-sensing has a role to play, particularly limb sounders which can provide vertical profiles into the stratosphere and therefore validate stratospheric loss rates in atmospheric models. This work is in two parts. The first describes new and improved high-resolution infra-red absorption cross sections of carbon tetrachloride/dry synthetic air over …

Spatial Patterns Of Sea Level Variability Associated With Natural Internal Climate Modes, Weiqing Han, Gerald A. Meehl, Detlef Stammer, Aixue Hu, Benjamin Hamlington, Jessica Kenigson, Hindumathi Palanisamy, Philip Thompson

OES Faculty Publications

Sea level rise (SLR) can exert significant stress on highly populated coastal societies and low-lying island countries around the world. Because of this, there is huge societal demand for improved decadal predictions and future projections of SLR, particularly on a local scale along coastlines. Regionally, sea level variations can deviate considerably from the global mean due to various geophysical processes. These include changes of ocean circulations, which partially can be attributed to natural, internal modes of variability in the complex Earth's climate system. Anthropogenic influence may also contribute to regional sea level variations. Separating the effects of natural climate modes …

Upper Water Structure And Mixed Layer Depth In Tropical Waters: The Seats Station In The Northern South China Sea, Jen-Hua Tai, George T. F. Wong, Xiaoju Pan

OES Faculty Publications

The variability of the upper water hydrographic structure, the efficacy of the different schemes for estimating the mixed layer depth (MLD), the inter-comparability estimation of the MLDs and diurnal and intra-annual MLD climatology in the tropical waters in the northern South China Sea were accessed in 702 depth-profiles of potential temperature (θ) and salinity collected in 64 cruises between 17.5 and 18.5°N and 115.3 and 116.3°E from 1997 to 2013. The hydrographic structure may be subdivided into three principal types: the classical type, with quasi-isopycnal surface mixed layer followed by an abrupt increase in the depth-gradient in θ and potential …

Holocene Cyclic Records Of Ice-Rafted Debris And Sea Ice Variations On The East Greenland And Northwest Iceland Margins, D. A. Darby, J. T. Andrews, S. T. Belt, A. E. Jennings, P. Cabedo-Sanz

OES Faculty Publications

The dynamics of the Greenland Ice Sheet and drift of sea ice from the Arctic Ocean reaching Denmark Strait are poorly constrained. We present data on the provenance of Fe oxide detrital grains from two cores in the Denmark Strait area and compare the Fe grain source data with other environmental proxies in order to document the variations and potential periodicities in ice-rafted debris delivery during the Holocene. Based on their Fe grain geochemistry, the sediments can be traced to East Greenland sources and to more distal sites around the Arctic Basin. On the Holocene time scales of the two …

Upscaling Stem To Community-Level Transpiration For Two Sand-Fixing Plants: Salix Gordejevii And Caragana Microphylla, Limin Duan, Yang Li, Xue Yan, Tingxi Liu, Xixi Wang

Civil & Environmental Engineering Faculty Publications

The information on transpiration is vital for sustaining fragile ecosystem in arid/semiarid environment, including the Horqin Sandy Land (HSL) located in northeast China. However, such information is scarce in existing literature. The objectives of this study were to: (1) measure sap flow of selected individual stems of two sand-fixing plants, namely Salix gordejevii and Caragana microphylla, in HSL; and (2) upscale the measured stem-level sap flow for estimating the community-level transpiration. The measurements were done from 1 May to 30 September 2015 (i.e., during the growing season). The upscaling function was developed to have one dependent variable, namely sap …

Community Production Modulates Coral Reef Ph And The Sensitivity Of Ecosystem Calcification To Ocean Acidification, Thomas M. Decarlo, Anne L. Cohen, George T. F. Wong, Fuh-Kwo Shiah, Steven J. Lentz, Kristen A. Davis, Kathryn E. F. Shamberger, Pat Lohmann

OES Faculty Publications

Coral reefs are built of calcium carbonate (CaCO₃) produced biogenically by a diversity of calcifying plants, animals, and microbes. As the ocean warms and acidifies, there is mounting concern that declining calcification rates could shift coral reef CaCO3 budgets from net accretion to net dissolution. We quantified net ecosystem calcification (NEC) and production (NEP) on Dongsha Atoll, northern South China Sea, over a 2 week period that included a transient bleaching event. Peak daytime pH on the wide, shallow reef flat during the nonbleaching period was ~8.5, significantly elevated above that of the surrounding open ocean (~8.0-8.1) as …

Effects Of Nonaerated Circulation Water Velocity On Nutrient Release From Aquaculture Pond Sediments, Xiangju Cheng, Dantong Zhu, Xixi Wang, Deguang Yu, Jun Xie

Civil & Environmental Engineering Faculty Publications

Sustaining good water quality in aquaculture ponds is vital. Without an aerator, the dissolved oxygen in ponds comes primarily from mass transfer at the water-ambient atmosphere interface. As sediment can seriously affect water quality, this study used indoor experiments to examine the nutrient (nitrogen and phosphorus) release mechanisms and fluxes from sediment in aquaculture ponds with moving water but no aeration. The results showed that the ammonia nitrogen (NH₃-N) concentration in the overlying water was inversely proportional to flow velocity and that a higher flow velocity tended to result in a lower concentration in the overlying water, a …

Numerical Modeling Of The Interactions Between Nonlinear Waves And Arbitrarily Flexible Vegetation, Navid Tahvildari

Civil & Environmental Engineering Faculty Publications

Coastal wetlands are among the natural features with the capability to dissipate wave energy and reduce storm damage. Inadequate representation of wave and vegetation characteristics in numerical models may reduce their capability in predicting wave processes over wetlands. Previous numerical wave models have typically applied simplifications on vegetation behavior. For instance, vegetation stems were usually assumed to be rigid or semi-flexible and thus extreme stem deflections could not be captured. In this study, a time-domain nonlinear numerical model based on extended Boussinesq formulation is developed and coupled with a numerical model for vegetation blade dynamics that allows for arbitrary flexibility. …

Effects Of Sea Level Rise On Hydrology: Case Study In A Typical Mid-Atlantic Coastal Watershed, Xixi Wang, Rui Li, Homa Jalaeian Taghadomi, Shohreh Pedram, Xiao Zhao

Civil & Environmental Engineering Faculty Publications

Sea level rise (SLR) can negatively affect the hydrology of coastal watersheds. However, the relevant information is incomplete and insufficient in existing literature. The objective of this study is to present a modeling approach to predict long-term effects of SLR on changes of flood peak, flood stage, and groundwater table with an assumption that the historical climate would reoccur in the future. The study was conducted for a typical coastal watershed in southeast USA. The results indicate that sea level had been rising at a rate of 4.21 mm yr⁻¹ from 1948 to 1982 but at a faster rate …

Water–Soil–Vegetation Dynamic Interactions In Changing Climate, Xixi Wang, Xuefeng Chu, Tingxi Liu, Xiangju Cheng, Rich Whittecar

Civil & Environmental Engineering Faculty Publications

Previous studies of land degradation, topsoil erosion, and hydrologic alteration typically focus on these subjects individually, missing important interrelationships among these important aspects of the Earth's system. However, an understanding of water–soil–vegetation dynamic interactions is needed to develop practical and effective solutions to sustain the globe's eco-environment and grassland agriculture, which depends on grasses, legumes, and other fodder or soil-building crops. This special issue is intended to be a platform for a discussion of the relevant scientific findings based on experimental and/or modeling studies. Its 12 peer-reviewed articles present data, novel analysis/modeling approaches, and convincing results of water–soil–vegetation interactions under …

Introducing Global Peat-Specific Temperature And Ph Calibrations Based On Brgdgt Bacterial Lipids, B.D.A. Naafs, G. N. Imglis, Y. Zheng, M. J. Amesbury, H. Biester, R. Bindler, J. Blewett, M. A. Burrows, D. Del Castillo Torres, F. M. Chambers, P. G. Hatcher

Chemistry & Biochemistry Faculty Publications

Glycerol dialkyl glycerol tetraethers (GDGTs) are membrane-spanning lipids from Bacteria and Archaea that are ubiquitous in a range of natural archives and especially abundant in peat. Previous work demonstrated that the distribution of bacterial branched GDGTs (brGDGTs) in mineral soils is correlated to environmental factors such as mean annual air temperature (MAAT) and soil pH. However, the influence of these parameters on brGDGT distributions in peat is largely unknown. Here we investigate the distribution of brGDGTs in 470 samples from 96 peatlands around the world with a broad mean annual air temperature (−8 to 27 °C) and pH (3–8) range …

Exploring The Reasons For The Seasons Using Google Earth, 3d Models, And Plots, Declan G. De Paor, Mladen M. Dordevic, Paul Karabinos, Stephen Burgin, Filis Coba, Steven J. Whitmeyer

Physics Faculty Publications

Public understanding of climate and climate change is of broad societal importance. However, misconceptions regarding reasons for the seasons abound amongst students, teachers, and the public, many of whom believe that seasonality is caused by large variations in Earth's distance from the Sun. Misconceptions may be reinforced by textbook illustrations that exaggerate eccentricity or show an inclined view of Earth's near-circular orbit. Textbook explanations that omit multiple factors influencing seasons, that do not mesh with students' experiences, or that are erroneous, hinder scientifically valid reasoning. Studies show that many teachers share their students' misconceptions, and even when they understand basic …