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Full-Text Articles in Physical Sciences and Mathematics

Formulation Of Colloidal Suspensions Of 3-Mercaptopropionic Acid Capped Pbs Quantum Dots As Solution Processable Qd "Inks" For Optoelectronic Applications, Chase Collier Reinhart Dec 2016

Formulation Of Colloidal Suspensions Of 3-Mercaptopropionic Acid Capped Pbs Quantum Dots As Solution Processable Qd "Inks" For Optoelectronic Applications, Chase Collier Reinhart

Dissertations and Theses

The use of colloidal quantum dots (QDs) for photovoltaic energy conversion is a nascent field that has been dominated for well over a decade by the use of 3-mercaptopropionic acid (3-MPA) capped PbS QDs. These QDs are routinely deposited via an in situ solid state ligand exchange process that displaces the native oleate ligand on the PbS QD surface. This ligand exchange procedure is wasteful of material and has been demonstrated to leave numerous impurities that limit electronic performance of the as-deposited QD devices. Until the last few years there was very little understanding in chemical literature as to many …


Assessing The Protective Quality Of Wax Coatings On Bronze Sculptures Using Hydrogel Patches In Impedance Measurements, Alice H. England, Kathryn N. Hosbein, Capri A. Price, Morgan K. Wylder, Kenna S. Miller, Tami Lasseter Clare Oct 2016

Assessing The Protective Quality Of Wax Coatings On Bronze Sculptures Using Hydrogel Patches In Impedance Measurements, Alice H. England, Kathryn N. Hosbein, Capri A. Price, Morgan K. Wylder, Kenna S. Miller, Tami Lasseter Clare

Chemistry Faculty Publications and Presentations

In this work, we used chemically cross-linked acrylamide-based hydrogel patches that have been specifically developed for use as solid electrolytes in Electrochemical Impedance Spectroscopy to measure the impedance of two waxed bronze sculptures at the Seattle Art Museum’s (SAM) Olympic Sculpture Park (OSP) and compare those results to laboratory test panels. We determined that the impedance response in the frequency range in which measurements may be taken (10 kHz to 1 MHz) is mostly capacitive and that a freshly applied wax coating should ideally be less than 1 nF·cm−2for optimal protective performance.