Physical Sciences and Mathematics Commons^™

Spin Exchange Interaction In Substituted Copper Phthalocyanine Crystalline Thin Films, Naveen Rawat, Zhenwen Pan, Cody J. Lamarche, Anthony Wetherby, Rory Waterman, Takahisa Tokumoto, Judy G. Cherian

College of Arts and Sciences Faculty Publications

All rights reserved. The origins of spin exchange in crystalline thin films of Copper Octabutoxy Phthalocyanine (Cu-OBPc) are investigated using Magnetic Circular Dichroism (MCD) spectroscopy. These studies are made possible by a solution deposition technique which produces highly ordered films with macroscopic grain sizes suitable for optical studies. For temperatures lower than 2K, the contribution of a specific state in the valence band manifold originating from the hybridized lone pair in nitrogen orbitals of the Phthalocyanine ring, bears the Brillouin-like signature of an exchange interaction with the localized d-shell Cu spins. A comprehensive MCD spectral analysis coupled with a molecular …

Rapid Biotic Homogenization Of Marine Fish Assemblages, Anne E. Magurran, Maria Dornelas, Faye Moyes, Nicholas J. Gotelli, Brian Mcgill

College of Arts and Sciences Faculty Publications

The role human activities play in reshaping biodiversity is increasingly apparent in terrestrial ecosystems. However, the responses of entire marine assemblages are not well-understood, in part, because few monitoring programs incorporate both spatial and temporal replication. Here, we analyse an exceptionally comprehensive 29-year time series of North Atlantic groundfish assemblages monitored over 5° latitude to the west of Scotland. These fish assemblages show no systematic change in species richness through time, but steady change in species composition, leading to an increase in spatial homogenization: the species identity of colder northern localities increasingly resembles that of warmer southern localities. This biotic …

If You've Seen One Worm, Have You Seen Them All? Spatial, Community, And Genetic Variability Of Tubificid Communities In Montana, Nilanjan Lodh, Donna M. Rizzo, Billie L. Kerans, Stephanie Mcginnis, Nikolaos Fytilis, Lori Stevens

College of Engineering and Mathematical Sciences Faculty Publications

Genetic studies are recognized increasingly as important for understanding naturally occurring disease dynamics and are used to predict host genetic diversity and coevolutionary processes and to identify species composition in ecological communities. Tubifex tubifex, the definitive host of the whirling disease parasite Myxobolus cerebralis, comprises 6 known lineages that vary widely in parasite susceptibility. We used 16S ribosomal DNA (16S rDNA) to identify relationships among genetic variability of 3 oligochaete genera (T. tubifex, Rhyacodrilus spp., and Ilyodrilus spp.; Oligochaeta:Tubificidae), oligochaete assemblage composition, and the presence of whirling disease in 9 locations across 4 watersheds in Montana, USA. We assessed genetic …

Climate Change Sentiment On Twitter: An Unsolicited Public Opinion Poll, Emily M. Cody, Andrew J. Reagan, Lewis Mitchell, Peter Sheridan Dodds, Christopher M. Danforth

College of Engineering and Mathematical Sciences Faculty Publications

The consequences of anthropogenic climate change are extensively debated through scientific papers, newspaper articles, and blogs. Newspaper articles may lack accuracy, while the severity of findings in scientific papers may be too opaque for the public to understand. Social media, however, is a forum where individuals of diverse backgrounds can share their thoughts and opinions. As consumption shifts from old media to new, Twitter has become a valuable resource for analyzing current events and headline news. In this research, we analyze tweets containing the word "climate" collected between September 2008 and July 2014. Through use of a previously developed sentiment …

Ecological And Biogeographic Null Hypotheses For Comparing Rarefaction Curves, Luis Cayuela, Nicholas J. Gotelli, Robert K. Colwell

College of Arts and Sciences Faculty Publications

The statistical framework of rarefaction curves and asymptotic estimators allows for an effective standardization of biodiversity measures. However, most statistical analyses still consist of point comparisons of diversity estimators for a particular sampling level. We introduce new randomization methods that incorporate sampling variability encompassing the entire length of the rarefaction curve and allow for statistical comparison of i ≥ 2 individual-based, sample-based, or coverage-based rarefaction curves. These methods distinguish between two distinct null hypotheses: the ecological null hypothesis (H0eco) and the biogeographical null hypothesis (H0biog). H0eco states that the i samples were drawn from a single assemblage, and any differences …

Impacts Of Community-Based Natural Resource Management On Wealth, Food Security And Child Health In Tanzania, Sharon Pailler, Robin Naidoo, Neil D. Burgess, Olivia E. Freeman, Brendan Fisher

Rubenstein School of Environment and Natural Resources Faculty Publications

Community-based natural resource management (CBNRM) is a major global strategy for enhancing conservation outcomes while also seeking to improve rural livelihoods; however, little evidence of socioeconomic outcomes exists. We present a national-level analysis that empirically estimates socioeconomic impacts of CBNRM across Tanzania, while systematically controlling for potential sources of bias. Specifically, we apply a difference-indifferences model to national-scale, cross-sectional data to estimate the impact of three different CBNRM governance regimes on wealth, food security and child health, considering differential impacts of CBNRM on wealthy and poor populations. We also explore whether or not longer-standing CBNRM efforts provide more benefits than …

Temporal Overlap And Co-Occurrence In A Guild Of Sub-Tropical Tephritid Fruit Flies, Gleidyane N. Lopes, Miguel F. Souza-Filho, Nicholas J. Gotelli, Leandro J.U. Lemos, Wesley A.C. Godoy, Roberto A. Zucchi

College of Arts and Sciences Faculty Publications

Studies of community assembly have emphasized snapshot comparisons of spatially replicated samples from "natural" assemblages. Agro-ecosystems are characterized by relatively little habitat heterogeneity and no dispersal barriers for actively flying insects. Therefore, dynamic patterns of species segregation and aggregation are more likely to reflect the direct or indirect effects of species interactions. We studied the temporal organization of a guild of 21 congeneric species of Anastrepha that colonized fruit orchards in Monte Alegre do Sul, São Paulo, Brazil. This assemblage also included the introduced Mediterranean fruit fly Ceratitis capitata. One hundred six consecutive weekly censuses (11 Jan 2002-16 Jan 2004) …

Forecasting The Response Of Earth's Surface To Future Climatic And Land Use Changes: A Review Of Methods And Research Needs, Jon D. Pelletier, A. Brad Murray, Jennifer L. Pierce, Paul R. Bierman, David D. Breshears, Benjamin T. Crosby, Michael Ellis, Efi Foufoula-Georgiou, Arjun M. Heimsath, Chris Houser, Nick Lancaster, Marco Marani, Dorothy J. Merritts, Laura J. Moore, Joel L. Pederson, Michael J. Poulos, Tammy M. Rittenour, Joel C. Rowland, Peter Ruggiero, Dylan J. Ward, Andrew D. Wickert, Elowyn M. Yager

College of Arts and Sciences Faculty Publications

Earth's Future published by Wiley on behalf of the American Geophysical Union. In the future, Earth will be warmer, precipitation events will be more extreme, global mean sea level will rise, and many arid and semiarid regions will be drier. Human modifications of landscapes will also occur at an accelerated rate as developed areas increase in size and population density. We now have gridded global forecasts, being continually improved, of the climatic and land use changes (C&LUC) that are likely to occur in the coming decades. However, besides a few exceptions, consensus forecasts do not exist for how these C&LUC …

Climate Controls On Air Quality In The Northeastern U.S.: An Examination Of Summertime Ozone Statistics During 1993-2012, Evan M. Oswald, Lesley Ann Dupigny-Giroux, Eric M. Leibensperger, Rich Poirot, Jeff Merrell

College of Arts and Sciences Faculty Publications

The goal of this study is to better understand the linkages between the climate system and surface-level ozone concentrations in the Northeastern U.S. We focus on the regularity of observed high ozone concentrations between May 15 and August 30 during the 1993-2012 period. The first portion of this study establishes relationships between ozone and meteorological predictors. The second examines the linkages between ozone and large-scale teleconnections within the climate system. Statistical models for each station are constructed using a combination of Correlation Analysis, Principal Components Analysis and Multiple Linear Regression. In general, the strongest meteorological predictors of ozone are the …

Notes From The Field: Lessons Learned From Using Ecosystem Service Approaches To Inform Real-World Decisions, Mary Ruckelshaus, Emily Mckenzie, Heather Tallis, Anne Guerry, Gretchen Daily, Peter Kareiva, Stephen Polasky, Taylor Ricketts, Nirmal Bhagabati, Spencer A. Wood, Joanna Bernhardt

Rubenstein School of Environment and Natural Resources Faculty Publications

While there have been rapid advances in assessments of biodiversity and ecosystem services (BES), a critical remaining challenge is how to move from scientific knowledge to real-world decision making. We offer 6 lessons from our experiences applying new approaches and tools for quantifying BES in 20 pilot demonstrations: (1) Applying a BES approach is most effective in leading to policy change as part of an iterative science-policy process; (2) simple ecological production function models have been useful in a diverse set of decision contexts, across a broad range of biophysical, social, and governance systems. Key limitations of simple models arise …

Will Passive Protection Save Congo Forests?, Gillian L. Galford, Britaldo S. Soares-Filho, Laura J. Sonter, Nadine Laporte

Rubenstein School of Environment and Natural Resources Faculty Publications

Central Africa's tropical forests are among the world's largest carbon reserves. Historically, they have experienced low rates of deforestation. Pressures to clear land are increasing due to development of infrastructure and livelihoods, foreign investment in agriculture, and shifting land use management, particularly in the Democratic Republic of Congo (DRC). The DRC contains the greatest area of intact African forests. These store approximately 22 billion tons of carbon in aboveground live biomass, yet only 10% are protected. Can the status quo of passive protection - forest management that is low or nonexistent - ensure the preservation of this forest and its …

Barriers And Opportunities To Promote Rights To Sustainable Production Of Smallholders In The Context Of Climate Stresses In Central America, Raffaele Vignola

Food Systems Summit 2015

Under a systemic approach, right to food implies also considering two aspects such as the implementation of and correspondent support to sustainable agricultural production by smallholders. Given the observed and projected trends, this requires also considering how such practices can help these vulnerable producers cope with and recover from the increasing climate stresses affecting them. We here focus on these two complementary aspects for the case of coffee and basic grains smallholders: the identification of adaptive benefits of sustainable practices and the barriers and strengths of cross-scale governance to support their implementation in Central America (a highly climate-vulnerable region).

Unveiling The Species-Rank Abundance Distribution By Generalizing The Good-Turing Sample Coverage Theory, Anne Chao, T. C. Hsieh, Robin L. Chazdon, Robert K. Colwell, Nicholas J. Gotelli, B. D. Inouye

College of Arts and Sciences Faculty Publications

Based on a sample of individuals, we focus on inferring the vector of species relative abundance of an entire assemblage and propose a novel estimator of the complete species-rank abundance distribution (RAD). Nearly all previous estimators of the RAD use the conventional "plug-in" estimator pi(sample relative abundance) of the true relative abundance piof species i. Because most biodiversity samples are incomplete, the plug-in estimators are applied only to the subset of species that are detected in the sample. Using the concept of sample coverage and its generalization, we propose a new statistical framework to estimate the complete RAD by separately …

Robustness Of Spatial Micronetworks, Thomas C. Mcandrew, Christopher M. Danforth, James P. Bagrow

College of Engineering and Mathematical Sciences Faculty Publications

Power lines, roadways, pipelines, and other physical infrastructure are critical to modern society. These structures may be viewed as spatial networks where geographic distances play a role in the functionality and construction cost of links. Traditionally, studies of network robustness have primarily considered the connectedness of large, random networks. Yet for spatial infrastructure, physical distances must also play a role in network robustness. Understanding the robustness of small spatial networks is particularly important with the increasing interest in microgrids, i.e., small-area distributed power grids that are well suited to using renewable energy resources. We study the random failures of links …

Noaa Local Climate Analysis Tool (Lcat) Data, Methods, And Usability, Marina Timofeyeva-Livezey, Fiona Horsfall, Annette Hollingshead, Jenna Meyers, Lesley Ann Dupigny-Giroux

College of Arts and Sciences Faculty Publications

The National Oceanic and Atmospheric Administration (NOAA) has responded to the increased demand for local climate information by developing the Local Climate Analysis Tool (LCAT). The tool provides rapid responses to climate questions that historically required an extensive data search, research on appropriate analysis techniques, and complex graphics packages. LCAT offers easy and efficient access to scientifically sound analytical capabilities and trusted climate data. Results obtained from LCAT provide relevant climate information to local technical users, decision makers, and educators that will help build a healthy nation and create resilient communities. To ensure that LCAT responds to the articulated needs …

The Use Of Cmip5 Data To Simulate Climate Change Impacts On Flow Regime Within The Lake Champlain Basin, Ibrahim Nourein Mohammed, Arne Bomblies, Beverley C. Wemple

College of Arts and Sciences Faculty Publications

Study region: Lake Champlain Basin, northwestern New England, USA. Study focus: Our study uses regional hydrologic analyses and modeling to examine alternative possibilities that might emerge in the Lake Champlain Basin streamflow regime for various climate scenarios. Climate data as well as spatial data were processed to calibrate the Regional Hydro-Ecological Simulation System (RHESSys) model runoff simulations. The 21st century runoff simulations were obtained by driving the RHESSys model with climate data from the Coupled Model Intercomparison Project phase 5 (CMIP5) for representative concentration pathways RCP 4.5 and 8.5. New hydrological insights for the region: Our analyses suggest that most …

Survey Of Northeastern Hop Arthropod Pests And Their Natural Enemies, Lilian B. Calderwood, Scott A. Lewins, Heather M. Darby

College of Agriculture and Life Sciences Faculty Publications

The commercial production of hops (Humulus lupulus L.) in the northeastern United States is on the rise due to demand from local breweries. Several arthropod pests are economically damaging to hop yield and quality. Due to climate and landscape differences between traditional and resurging hop-growing regions, there is a need for region-specific integrated pest management (IPM). We first review hop pest and natural enemy biology and management strategies. Then the phenology, abundance, and peak date of arthropod pests scouted in seven Vermont hop yards is reported. Documentation of natural enemy abundance is also reported. Our 3-yr survey indicated that hop …

Mainstreaming Early Warning Systems In Development And Planning Processes: Multilevel Implementation Of Sendai Framework In Indus And Sahel, Asim Zia, Courtney Hammond Wagner

College of Agriculture and Life Sciences Faculty Publications

The third UN World Congress on Disaster Risk Reduction, held in Sendai, Japan in March 2015, agreed on a new framework to guide disaster risk reduction policy and practice for the next 15 years. The Sendai Framework for Disaster Risk Reduction 2015–2030 (SFDRR) leaves important implementation issues unspecified and potentially creates both problems and opportunities for complex, multilevel governance systems in coping with hazards and disastrous events. Early warning systems (EWS), if built into the mainstream of planning for development and disaster relief and recovery, could present a significant opportunity to realize many SFDRR goals. We explore the complexities of …

Micro-Topological Effects On Redox-Sensitive Nutrient Availability Of Manganese, Iron, Sulfur, And Phosphorus, Lindsey C. Ruhl

Graduate College Dissertations and Theses

The working hypothesis for this study was that small elevation differences in field depressions affect the availability of redox active nutrients because the bottom of the depression remains waterlogged and in reducing conditions longer than the edge of the depression. Mn, Fe, S and P availabilities were investigated in a field depression with a 20 meter radius and 0.5 meter depth on a flood-prone, organic vegetable farm. One depression (Depression 1) was sampled seven times during three field seasons (May 2012-June 2014). The last two dates included sampling in an additional three depressions to allow a comparison among depressions on …

Are Conservation Organizations Configured For Effective Adaptation To Global Change?, Paul R. Armsworth, Eric R. Larson, Stephen T. Jackson, Dov F. Sax, Paul Simonin, Bernd Blossey, Nancy Green, Mary L. Klein, Liza Lester, Taylor H. Ricketts, Michael C. Runge, M. Rebecca Shaw

Rubenstein School of Environment and Natural Resources Faculty Publications

© The Ecological Society of America. Conservation organizations must adapt to respond to the ecological impacts of global change. Numerous changes to conservation actions (eg facilitated ecological transitions, managed relocations, or increased corridor development) have been recommended, but some institutional restructuring within organizations may also be needed. Here we discuss the capacity of conservation organizations to adapt to changing environmental conditions, focusing primarily on public agencies and nonprofits active in land protection and management in the US. After first reviewing how these organizations anticipate and detect impacts affecting target species and ecosystems, we then discuss whether they are sufficiently flexible …

A Framework To Assess The Health Of Rocky Reefs Linking Geomorphology, Community Assemblage, And Fish Biomass, Octavio Aburto-Oropeza, Exequiel Ezcurra, Jerry Moxley, Alexandra Sánchez-Rodríguez, Ismael Mascareñas-Osorio, Carlos Sánchez-Ortiz, Brad Erisman, Taylor Ricketts

Rubenstein School of Environment and Natural Resources Faculty Publications

The recovery of historic community assemblages on reefs is a primary objective for the management of marine ecosystems. Working under the overall hypothesis that, as fishing pressure increases, the abundance in upper trophic levels decreases followed by intermediate levels, we develop an index that characterizes the comparative health of rocky reefs. Using underwater visual transects to sample rocky reefs in the Gulf of California, Mexico, we sampled 147 reefs across 1200 km to test this reef health index (IRH). Five-indicators described 88% of the variation among the reefs along this fishing-intensity gradient: the biomass of piscivores and carnivores were positively …

Social Entrepreneurship And Social Business: Retrospective And Prospective Research, Edgard Barki, Graziella Comini, Ann Cunliffe, Stuart Hart, Sudhanshu Rai

Grossman School of Business Faculty Publications

Social Entrepreneurship and Social Business (SE/SB), inclusive business, businesses with social impact and a higher purpose are becoming increasingly important both in academia and the business world (Sassmannshausen & Volkmann, 2013). Since the influential article by Dees (1998), many different perspectives about social entrepreneurship and social business have been discussed in academia. On the management side, these types of businesses have also proliferated in the last decades. Yunus with his work leading Grameen Bank has inspired many other entrepreneurs and organizations to create a new kind of business more embedded with a social purpose. The main purpose of the Social …

Lake Trout Spawning Site Use In Lake Champlain & The Development Of The Binomial Rolling Residence Test, Victoria M. Pinheiro

Graduate College Dissertations and Theses

Lake trout populations were extirpated from the lower four Great Lakes by 1960 and from Lake Champlain by 1900. The decline of lake trout populations fueled a wave of restoration-based research that spanned the Great Lakes and filled in many of the gaps in our knowledge of lake trout behavior and ecology. However, remarkably little is known about lake trout spawning behavior, even less about sex-specific differences in spawning site use. Lake trout use specific spawning sites, and may return to the same site year after year. More males are caught on spawning sites than females and are present at …

Exchange Mechanisms In Macroscopic Ordered Organic Magnetic Semiconductors, Naveen Rawat

Graduate College Dissertations and Theses

Small molecule organic semiconductors such as phthalocyanines and their derivatives represent a very interesting alternative to inorganic semiconductor materials for the development of flexible electronic devices such as organic thin field effect transistors, organic Light Emitting Diodes and photo-voltaic cells. Phthalocyanine molecules can easily accommodate a variety of metal atoms as well in the central core of the molecule, resulting in wide range of magnetic properties. Exploration of optical properties of organic crystalline semiconductors thin films is challenging due to sub-micron grain sizes and the presence of numerous structural defects, disorder and grain boundaries. However, this can be overcome by …

The Role Of Motivation And Curriculum In Shaping Pro-Sustainable Attitudes And Behaviors In Students, Kathleen Bamford

Graduate College Dissertations and Theses

Sustainability is an area of growing pertinence as our future and the future of our planet depends on its acceptance and application. Determining patterns in pro-sustainable attitudes and behaviors, and revealing motivations behind these behaviors have important implications for the future of sustainability education. The primary objective of this study is to discover the relationships between educational experience and sustainability attitudes and behaviors in elementary school students. A secondary objective is to determine the motivation behind pro-sustainability behaviors and to establish the role this plays in educational programs. The study utilizes mixed methodology through two modes of data collection: 1. …

New Insights For The Future Of Lake Champlain: Practical Approaches And Useful Tools For Grappling With Uncertainty And Weighing Trade-Offs In Watershed Management., Philip Halteman

Graduate College Dissertations and Theses

The effective management of non-point source nutrient pollution continues to prove elusive. Though the scientific literature is unequivocal that all anthropogenic land uses contribute to non-point source (NPS) pollution, variable levels of contribution over time and across location and complex relationships between cost and effect make finding technologically effective management solutions difficult. In addition, these solutions are implemented in a world of scarce resources, diverse and often competing concerns and values, and intense public scrutiny. Clearly, making the best possible decision about how to manage NPS pollution under these conditions is not simple. My overarching goal was to develop and …

Monitor: Automation Tools For Landscape-Scale Acoustic Monitoring, Jonathan Edward Katz

Graduate College Dissertations and Theses

Climate change coupled with land-use change will likely alter habitats and affect state parameters of the animal populations that dwell in them. Affected parameters are anticipated to include site occupancy and abundance, population range, and phenophase cycles (e.g., arrival dates on breeding grounds for migrant bird species). Detecting these changes will require monitoring many sites for many years, a process that is well suited for an automated system. We developed and tested monitoR, an R package that is designed for long-term, multi-taxa automated passive acoustic monitoring programs. monitoR correctly identified presence for black-throated green warbler and ovenbird in 64% and …

Reverse Engineering The Human Brain: An Evolutionary Computation Approach To The Analysis Of Fmri, Nicholas Allgaier

Graduate College Dissertations and Theses

The field of neuroimaging has truly become data rich, and as such, novel analytical methods capable of gleaning meaningful information from large stores of imaging data are in high demand. Those methods that might also be applicable on the level of individual subjects, and thus potentially useful clinically, are of special interest. In this dissertation we introduce just such a method, called nonlinear functional mapping (NFM), and demonstrate its application in the analysis of resting state fMRI (functional Magnetic Resonance Imaging) from a 242-subject subset of the IMAGEN project, a European study of risk-taking behavior in adolescents that includes longitudinal …

Discourse As Social Process In Outdoor Recreation And Natural Resource Management: Arguing, Constructing, And Performing, Monika Marie Derrien

Graduate College Dissertations and Theses

This dissertation examines the language-based, discursive processes through which meanings and experiences are socially constituted in outdoor recreation and natural resource environments. Language use and discourse are seen as interactive, constructive processes, approached through the theoretical perspectives of argumentation, social constructionism, and performance.

Three qualitative studies, based in data collected at Acadia National Park and forest-related sites throughout Vermont, comprise this dissertation. The first study uses rhetorical analysis to examine the ways National Park Service managers and community leaders argue for the meanings and management of dark night skies in and around Acadia. The second study examines how national park …

How Wildlife Information, Recreation Involvement And Demographic Characteristics Influence Public Acceptability Of Development, Jessica Espenshade

Graduate College Dissertations and Theses

Increasing development like roads and houses will alter the future landscape of Vermont. Development provides important resources for people and society, but also results in consequences for wildlife and opportunities for recreation. Managing development requires information on the public's acceptability of development and how acceptability is shaped by information on various consequences. In this study, I examined three questions: 1) What is the public's acceptability of development? 2) Does wildlife information influence public acceptability of development and 3) Is the maximum amount of acceptable development influenced by views about wildlife, involvement in recreation, and demographic factors? I surveyed 9,000 households …