Physical Sciences and Mathematics Commons^™

Heterogeneous Oxidation Of Catechol, Elizabeth A. Pillar, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

Natural and anthropogenic emissions of aromatic hydrocarbons from biomass burning, agro-industrial settings, and fossil fuel combustion contribute precursors to secondary aerosol formation (SOA). How these compounds are processed under humid tropospheric conditions is the focus of current attention to understand their environmental fate. This work shows how catechol thin films, a model for oxygenated aromatic hydrocarbons present in biomass burning and combustion aerosols, undergo heterogeneous oxidation at the air–solid interface under variable relative humidity (RH = 0–90%). The maximum reactive uptake coefficient of O₃(g) by catechol γ_O3 = (7.49 ± 0.35) × 10^–6 occurs for …

The Geologic Context Of Landslide And Rockfall Maintenance Costs In Kentucky, Bethany L. Overfield, Daniel I. Carey, Gerald A. Weisenfluh, Rebecca Wang, Matthew M. Crawford

Report of Investigations--KGS

Kentucky Transportation Cabinet maintenance cost data for landslides and rockfalls were associated with geology along Kentucky roadways in a three-phase study. Work-order costs collected over 7 yr were divided into 1-mi segments, and the segment midpoints were assigned to geologic formation. Formations that were expensive to maintain were not necessarily those that were the most frequently repaired and vice versa. Costs and frequency of repair were greater in eastern and northern Kentucky, where slope and relief are greater than in other parts of the state and shale-bearing geologic units prevail.

The Environmental Effects Of Coal Fires, Trent Garrison

Theses and Dissertations--Earth and Environmental Sciences

There are thousands of subterranean coal fires in the world that, because of incomplete combustion, emit a wide variety of volatile and semivolatile organic compounds to the atmosphere, water, and soil at concentrations that could pose health risks to humans and wildlife. The main goals of this study were to (1) review methods that are used to characterize physical and chemical characteristics of coal-fire sites, (2) determine relationships between gas emissions and physical and chemical characteristics of coal-fire sites, using a combination of regression and multivariate statistical methods, and (3) determine the concentrations of volatile and semivolatile organic compounds in …

Geologic, Geotechnical, And Geophysical Investigation Of A Shallow Landslide, Eastern Kentucky, Matthew M. Crawford, Junfeng Zhu, Steven E. Webb

Report of Investigations--KGS

In eastern Kentucky, landslides occur in colluvial soils or at the colluvium-bedrock contact, and are commonly triggered by heavy rainfall. These slides occur particularly where steep slopes and weak rocks combine with various methods of slope modification. Landslides can damage roadways, infrastructure, and residences, and mitigation costs can exceed $10 million per year.

The Meadowview landslide in Boyd County was investigated to assess the geologic conditions, extent, and behavior of a rainfall-triggered landslide in eastern Kentucky and evaluate the use of electrical resistivity as a tool to characterize a shallow colluvial landslide. Although this type of landslide is common in …

Summary Of The Kentucky River Watershed Watch 2015 Water Sampling Results, Kentucky Water Resources Research Institute

Kentucky River Watershed Watch

No abstract provided.

Comparison Of The Ground-Motion Attenuation Relationship Between The Wenchuan, China, Area And The Central And Eastern United States, Jiwei Feng, Zhenming Wang, Edward W. Woolery, Shanyou Li

Report of Investigations--KGS

An M_w-7.9 earthquake occurred in Wenchuan, China, in 2008, along the Longmenshan Fault, which is located on the western border of the South China stable continental region. A detailed comparison of the Wenchuan ground-motion attenuation relationships with the relationships for the central and eastern United States (also a stable continental region) showed that the ground-motion prediction equation for the Wenchuan area is similar to those for the central and eastern United States. Thus, the strong-motion records from the Wenchuan earthquake can be used for constraining the ground-motion prediction equation and engineering analysis for the central and eastern United …

Dynamic Surface Water-Groundwater Exchange In Tidal Freshwater Zones: Insights From The Christina River Basin (Delaware, Usa), Cole T. Musial

Theses and Dissertations--Earth and Environmental Sciences

In coastal rivers, tides can propagate for tens to hundreds of kilometers inland beyond the saltwater line. Yet the influence of tides on river-aquifer connectivity and solute transport in tidal freshwater zones (TFZs) is largely unknown. We estimate that along the TFZ of White Clay Creek (Delaware, USA), more than 17% of river water exchanges through hyporheic and riparian storage zones due to tidal pumping alone. Additional hyporheic processes such as flow through bedforms likely contribute even more exchange. The turnover length associated with the tidal pumping process is 39 km, similar to turnover lengths for all hyporheic exchange processes …

Use Of Lidar-Derived Terrain And Vegetation Information In A Deciduous Forest In Kentucky, Wesley A. Staats

Theses and Dissertations--Forestry and Natural Resources

The use of Light Detection and Ranging (LiDAR) information is gaining popularity, however its use has been limited in deciduous forests. This thesis describes two studies using LiDAR data in an Eastern Kentucky deciduous forest. The first study quantifies vertical error of LiDAR derived digital elevation models (DEMs) which describe the forests terrain. The study uses a new method which eliminates Global Positioning System (GPS) error. The study found that slope and slope variability both significantly affect DEM error and should be taken in to account when using LiDAR derived DEMs. The second study uses LiDAR derived forest vegetation and …