Physical Sciences and Mathematics Commons^™

An Organic Mixed Ion-Electron Conductor For Power Electronics, Abdellah Malti, Jesper Edberg, Hjalmar Granberg, Zia Ullah Khan, Jens W. Andreasen, Xianjie Liu, Dan Zhao, Hao Zhang, Yulong Yao, Joseph W. Brill, Isak Engquist, Mats Fahlman, Lars Wågberg, Xavier Crispin, Magnus Berggren

Physics and Astronomy Faculty Publications

A mixed ionic–electronic conductor based on nanofibrillated cellulose composited with poly(3,4-ethylene-dioxythio­phene):­poly(styrene-sulfonate) along with high boiling point solvents is demonstrated in bulky electrochemical devices. The high electronic and ionic conductivities of the resulting nanopaper are exploited in devices which exhibit record values for the charge storage capacitance (1F) in supercapacitors and transconductance (1S) in electrochemical transistors.

Heterogeneous Oxidation Of Catechol, Elizabeth A. Pillar, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

Natural and anthropogenic emissions of aromatic hydrocarbons from biomass burning, agro-industrial settings, and fossil fuel combustion contribute precursors to secondary aerosol formation (SOA). How these compounds are processed under humid tropospheric conditions is the focus of current attention to understand their environmental fate. This work shows how catechol thin films, a model for oxygenated aromatic hydrocarbons present in biomass burning and combustion aerosols, undergo heterogeneous oxidation at the air–solid interface under variable relative humidity (RH = 0–90%). The maximum reactive uptake coefficient of O₃(g) by catechol γ_O3 = (7.49 ± 0.35) × 10^–6 occurs for …

Secondary Organic Aerosol Formation From The Β-Pinene+No3 System: Effect Of Humidity And Peroxy Radical Fate, C. M. Boyd, J. Sanchez, L. Xu, Alexis J. Eugene, T. Nah, W. Y. Tuet, Marcelo I. Guzman, N. L. Ng

Chemistry Faculty Publications

The formation of secondary organic aerosol (SOA) from the oxidation of β-pinene via nitrate radicals is investigated in the Georgia Tech Environmental Chamber (GTEC) facility. Aerosol yields are determined for experiments performed under both dry (relative humidity (RH) < 2 %) and humid (RH = 50 % and RH = 70 %) conditions. To probe the effects of peroxy radical (RO₂) fate on aerosol formation, "RO₂ + NO₃ dominant" and "RO₂ + HO₂ dominant" experiments are performed. Gas-phase organic nitrate species (with molecular weights of 215, 229, 231, and 245 amu, which likely correspond to molecular formulas of C₁₀H₁₇NO₄, C₁₀H₁₅NO₅, C₁₀H₁₇NO …

Detection Of Small-Scale Rockfall Incidents Using Their Seismic Signature, Achilleas Tripolitsiotis, Antonis Daskalakis, Stelios Mertikas, Dionysios Hristopulos, Zacharias Agioutantis, Panagiotis Partsinevelos

Mining Engineering Faculty Publications

Several algorithms have been effectively used to identify the seismic signature of rockfall incidents, which constitute a significant threat for human lives and infrastructure especially when occurring along transportation networks. These algorithms have been mostly evaluated using data from large scale rockfall events that release a large amount of energy. However, low-energy rockfall events (< 100 Joules) triggered by small-sized individual rocks falling from small heights can be severely destructive. In this study, a three-parameter algorithm has been developed to identify low-energy rockfall events. An experimental setup was implemented to 1) validate the results obtained by this algorithm against visual inspection of seismic signals records, 2) define the optimal algorithm parameterization to minimize false alarms, and 3) investigate whether tri-axial vibration monitoring can be replaced by a uniaxial device in order to reduce the installation cost of a real-time rockfall monitoring system. It was found that the success rate of the proposed algorithm exceeds 80% independently of the parameters used, while event identification at a maximum distance with minimal false alarms was achieved when using mean ± 3σ as the threshold criterion and 6 ms and 4 ms as the trigger and event window parameters respectively. Finally, it was found that for the specific experimental setup, a uniaxial device could be used for rockfall event identification.

Teaching Cybersecurity Using The Cloud, Khaled Salah, Mohammad Hammoud, Sherali Zeadally

Information Science Faculty Publications

Cloud computing platforms can be highly attractive to conduct course assignments and empower students with valuable and indispensable hands-on experience. In particular, the cloud can offer teaching staff and students (whether local or remote) on-demand, elastic, dedicated, isolated, (virtually) unlimited, and easily configurable virtual machines. As such, employing cloud-based laboratories can have clear advantages over using classical ones, which impose major hindrances against fulfilling pedagogical objectives and do not scale well when the number of students and distant university campuses grows up. We show how the cloud paradigm can be leveraged to teach a cybersecurity course. Specifically, we share our …

Poster Session, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

1. Quantification of Common Agricultural Herbicide Dispersal and Land Use in Selected Areas of the Kentucky River Watershed, Andrew Nagel and others, Northern Kentucky University, Highland Heights, KY
2. Exploring the Effects of Herbicides on Willow Seedlings, Sarah Stryffeler and others, Dept. of Biological Sciences, Northern Kentucky University, Highland Heights, KY
3. LiDAR Mapping Sinkholes in Cane Run Watershed, Fidele Tibouo and others, Dept. Earth and Environmental Sciences, University of Kentucky, Lexington, KY
4. Surface Enhanced Raman Spectroscopy to Study Photocatalytic Degradation of Organic Pollutants, Frankie Wallace and Matthew Nee, Dept. of Chemistry, Western Kentucky University, Bowling Green, KY
5. Test …

Session 2c, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Investigating the Recent Invasion of Silver Carp (Hypopthalmicthys molitrix) into Kentucky Lake, Utilizing Diet and Long Term Data Analysis, Ben Tumolo and Michael B. Flinn, Hancock Biological Station, Murray State University, Murray, KY
• Assessment of Chytrid Fungus (Bactrachochytrium dendrobatidis) Occurrence and Prevalence in Plethodontid Salamanders Across a Forest Disturbance Gradient in Southeastern Kentucky, Sarah M. Hamilton and others, Forestry Department, University of Kentucky, Lexington, KY
• Strain Diversity in the Fecal Indicator Escherichia coli: Implications for its Use as a Produce Pathogen Surrogate, Ethan Givan and others, USDA-ARS, Bowling Green, KY

Session 2b, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• The Kentucky Nutrient Watershed Model, Ben Albritton and others, Kentucky Water Resources Research Institute, University of Kentucky, Lexington, KY
• Model Parameter Uncertainty Analysis for an Annual Field-Scale P Loss Model, Carl Bolster, Food Animal Environmental Systems Research Unit, USDA-ARS, Bowling Green, KY
• Flood Modeling Using a Virtual 3D Environment to Help Student Learning, C. V. Chandramouli and others, Mechanical Engineering Department, Purdue University Calumet, Hammond, IN
• Updating the Fresh-Saline Water Interface Map in Eastern Kentucky, Jerrad Grider and T. M. Parris, Kentucky Geological Survey, University of Kentucky, Lexington, KY

Session 2a, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Space-Time Behavior of Soil Water Status Measured Across Two Land Use Systems, Yang Yang and Ole Wendroth, Dept. of Plant and Soil Sciences, University of Kentucky, Lexington, KY
• "Wetness" in Landsat Scenes versus "Wetness" on the Ground: Uses of the Tasselled Cap Transformation on Archival Imagery, Demetrio Zourarakis, Kentucky Division of Geographic Information, Frankfort, KY
• Dynamics of Soil Quality Indicators in Western Kentucky, Hannah Robbins and Iin Handayani, Hutson School of Agriculture, Murray State University, Murray, KY
• Sediment Organic Carbon Fate and Transport Mechanisms in a Fluvial Karst System in the Bluegrass Region, Admin Husic and …

Session 1c, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Stakeholder Engagement as a Tool for Better Environmental Decisions, Anna Hoover and Lindell Ormsbee, College of Public Health and Kentucky Water Resources Research Institute, University of Kentucky, Lexington, KY
• Diverse Participation in Watershed Planning and Governance: Building Social-Ecological Resilience in Kentucky Watersheds, Alexandra Chase and others, Center for Land Use and Environmental Responsibility, University of Louisville, Louisville, KY
• Lexington is Giving Back - Lexington's Stormwater Grant Program is Giving Money Back to Fee Payers for Stormwater Projects, Christopher Dent, Lexington-Fayette Urban County Government, Division of Water, Lexington, KY

Session 1b, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Hatchery Creek Stream Restoration Project - A Unique Opportunity to Maximize Trout Habitat, Create Recreational Opportunities and Provide Mitigation Credits, Oakes Routt and others, Stantec Consulting Services Inc., Louisville, KY
• Hatchery Creek Stream Restoration Project - Construction of A Trout Stream in Kentucky, Eric Dawalt and others, Ridgewater, LLC, Lexington, KY
• Implementing Site-Specific Flow Competence Monitoring to Inform Stream Restoration Design, Kurt Cooper and Bob Hawley, Sustainable Streams, LLC, Louisville, KY
• Streambank Stability and Riparian Habitat Relationships and Mapping Tools in the Triplett Creek Watershed, Nicole Meade and Toney Phillips, Center for Environmental Education, Morehead State …

Session 1a, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Water Quality Monitoring of McConnell Springs' Surface Waters, 2011 through 2014, David J. Price, Lexington-Fayette Urban County Government, Division of Water, Lexington, KY
• Initial Findings from the Karst Water Instrumentation System Station, Royal Spring Groundwater Basin, Kentucky Horse Park, James Currens and others, Kentucky Geological Survey, Univ. of Kentucky, Lexington, KY
• Calibration Method to Estimate Suspended-Sediment Concentration from Acoustic Backscatter in a Cross Section, Justin Boldt, USGS Kentucky Water Science Center, Louisville, KY
• Vapor Flux Sampling Techniques for Characterizing Vapor Intrusion, Evan Willett and others, Dept. of Civil Engineering, University of Kentucky, Lexington, KY

Plenary Session, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Nanocomposite Membranes for Water Purification, Sebastián Hernández and others, Dept. of Chemical and Materials Engineering, University of Kentucky, Lexington, KY
• Nanofiltration Membranes for Water Reuse and Toxic Inorganics Removal from Coal-Fired Power Plant Water, Andrew Colburn and others, Dept. of Chemical and Materials Engineering, University of Kentucky, Lexington, KY
• Thermal Analysis and Raman Studies of the Photocatalytic Degradation of Organic Pollutants, Matthew Nee and others, Dept. of Chemistry, Western Kentucky University, Bowling Green, KY

Proceedings Of 2015 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

This symposium was planned and conducted as a part of the state water resources research institute annual program that is supported by Grant/Cooperative Agreement Number G11AP20081 from the United States Geological Survey. The contents of this proceedings document and the views and conclusions presented at the symposium are solely the responsibility of the individual authors and presenters and do not necessarily represent the official views of the USGS or of the symposium organizers and sponsors. This publication is produced with the understanding that the United States Government is authorized to reproduce and distribute reprints for government purposes.

Magnetic Response Of Aperiodic Wire Networks Based On Fibonacci Distortions Of Square Antidot Lattices, Barry Farmer, Vinayak Bhat, J. Sklenar, Eric Teipel, Justin Woods, J. B. Ketterson, J. Todd Hastings, Lance Delong

Physics and Astronomy Faculty Publications

The static and dynamic magnetic responses of patterned ferromagnetic thin films are uniquely altered in the case of aperiodic patterns that retain long-range order (e.g., quasicrystals). We have fabricated permalloy wire networks based on periodic square antidot lattices (ADLs) distorted according to an aperiodic Fibonacci sequence applied to two lattice translations, d₁  = 1618 nm and d₂  = 1000 nm. The wire segment thickness is fixed at t = 25 nm, and the width W varies from 80 to 510 nm. We measured the DC magnetization between room temperature and 5 K. Room-temperature, narrow-band (9.7 GHz) ferromagnetic resonance …

Temperature Dependence Of Anisotropic Magnetoresistance In Antiferromagnetic Sr2Iro4, C. Wang, H. Seinige, Gang Cao, J.-S. Zhou, J. B. Goodenough, M. Tsoi

Center for Advanced Materials Faculty Publications

Temperature-dependent magnetotransport properties of the antiferromagnetic semiconductor Sr₂IrO₄ are investigated with point-contact devices. The point-contact technique allows to probe very small volumes and, therefore, to look for electronic transport on a microscopic scale. Point-contact measurements with single crystals of Sr₂IrO₄ were intended to see whether the additional local resistance associated with a small contact area between a sharpened Cu tip and the antiferromagnet shows magnetoresistance (MR) such as that seen in bulk crystals. Point-contact measurements at liquid nitrogen temperature revealed large MRs (up to 28%) for modest magnetic fields (250 mT) applied within an …

An Optical Sprayer Nozzle Flow Rate Sensor, Joseph S. Dvorak, Luke E. Bryant

Biosystems and Agricultural Engineering Faculty Publications

Ensuring proper flow rates from each nozzle on an agricultural sprayer has become even more important as advances continue to be made in precision application technology. In this article, we describe the structure and testing of a sensor technology based on optical cross-correlation to determine the flow rate of individual sprayer nozzles. An advantage of this technology is that it does not require that impellers or other components be placed in the flow, which could cause plugging. The only moving part in the entire system is a solenoid used to inject a tracer dye. The objective of this study was …

Numerical Investigation On Charring Ablator Geometric Effects: Study Of Stardust Sample Return Capsule Heat Shield, Haoyue Weng, Alexandre Martin

Mechanical Engineering Faculty Publications

Sample geometry is very influential in small charring ablative articles where 1D assumption might not be accurate. In heat shield design, 1D is often assumed since the nose radius is much larger than the thickness of charring. Whether the 1D assumption is valid for the heat shield is unknown. Therefore, the geometric effects of Stardust sample return capsule heat shield are numerically studied using a material response program. The developed computer program models material charring, conductive heat transfer, surface energy balance, pyrolysis gas transport and orthotropic material properties in 3D Cartesian coordinates. Simulation results show that the centerline temperatures predicted …

Commercialization Of A Small, Lightweight, Low-Cost Seismic Borehole Receiver, Rachel Adams

Theses and Dissertations--Civil Engineering

Herein, conceptualization of a recently patented seismic borehole receiver and its components is developed for commercialization. The device is significantly cheaper, lighter, and smaller than existing technologies on the market. Additionally, it has the potential to achieve better seismic readings than its competitors via patented sensor-to-borehole coupling mechanism. It is the hope that the commercialization of this device will not only provide a more affordable alternative to engineers and geophysicists in the existing market, but the significant cost difference may open new seismic measurement opportunities in the developing world. Its compact size and light weight will increase mobility, allowing investigators …

Mathematical Modeling For Platform-Based Product Configuration Considering Total Life-Cycle Sustainability, Tian Lan

Theses and Dissertations--Mechanical Engineering

Many companies are using platform-based product designs to fulfill the requirements of customers while maintaining low cost. However, research that integrates sustainability into platform-based product design is still limited. Considering sustainability during platform-based design process is a challenge because the total life-cycle from pre-manufacturing, manufacturing and use to post-use stages as well as economic, environmental and societal performance in these stages must be considered. In this research, an approach for quantifying sustainability is introduced and a mathematical model is developed for identifying a more sustainable platform. Data from life-cycle assessment is used to quantify environmental factors; criteria from the Product …

Diffuse Optical Measurements Of Head And Neck Tumor Hemodynamics For Early Prediction Of Chemo-Radiation Therapy Outcomes, Lixin Dong

Theses and Dissertations--Biomedical Engineering

Chemo-radiation therapy is a principal modality for the treatment of head and neck cancers, and its efficacy depends on the interaction of tumor oxygen with free radicals. In this study, we adopted a novel hybrid diffuse optical instrument combining a commercial frequency-domain tissue oximeter (Imagent) and a custom-made diffuse correlation spectroscopy (DCS) flowmeter, which allowed for simultaneous measurements of tumor blood flow and blood oxygenation. Using this hybrid instrument we continually measured tumor hemodynamic responses to chemo-radiation therapy over the treatment period of 7 weeks. We also explored monitoring dynamic tumor hemodynamic changes during radiation delivery. Blood flow data analysis …

A Framework For Sustainable Material Selection For Multi-Generational Components, Ryan T. Bradley

Theses and Dissertations--Mechanical Engineering

The early stages of a product’s design are a critical time for decisions that impact the entire life-cycle cost. Product designers have mastered the first generation; however, they currently do not have the ability to know the impact of their decisions on the multi-generational view. This thesis aims at closing the gap between total life-cycle information and the traditional design process in order to harbor sustainable value creation among all stakeholders involved. A framework is presented that uses a combination of a life-cycle costing methodology and an evolutionary algorithm in order to achieve a sustainability assessment for a true multi-generational …

Inhalable Nanocomposites And Anticancer Agents For Cancer Therapy, Nathanael A. Stocke

Theses and Dissertations--Chemical and Materials Engineering

Cancer is designated as the leading cause of mortality worldwide and lung cancer is responsible for nearly 30% of all cancer related deaths. Over the last few decades mortality rates have only marginally increased and rates of recurrence remain high. These factors, among others, suggest the need for more innovative treatment modalities in lung cancer therapy. Targeted pulmonary delivery is well established for treating pulmonary diseases such as asthma and provides a promising platform for lung cancer therapy. Increasing local deposition of anticancer agents (ACAs) and reducing systemic exposure of these toxic moieties could lead to better therapeutic outcomes and …

Modeling Of Spallation Phenomenon In An Arc-Jet Environment, Raghava Sai Chaitanya Davuluri

Theses and Dissertations--Mechanical Engineering

Space vehicles, while entering the planetary atmosphere, experience high loads of heat. Ablative materials are commonly used for a thermal protection system, which undergo mass removal mechanisms to counter the heat rates. Spallation is one of the ablative processes, which is characterized by the ejection of solid particles from the material into the flow. Numerical codes that are used in designing the heat shields ignore this phenomenon. Hence, to evaluate the effectiveness of spallation phenomenon, a numerical model is developed to compute the dynamics and chemistry of the particles. The code is one-way coupled to a CFD code that models …

Development Of Techniques For Assessing And Restoring Streams On Surface Mined Lands, Whitney Cole Blackburn-Lynch

Theses and Dissertations--Biosystems and Agricultural Engineering

Surface mining is a commonly used method for extracting coal in the Appalachian Coalfields of the U.S. This mining practice produces excess spoil or overburden, which is often placed in adjacent valleys resulting in the creation of valley fills. These valley fills bury headwater streams, which in turn can negatively impact downstream ecosystems. In 2008, the University of Kentucky designed and constructed 1,020 m of ephemeral, intermittent and headwater streams on an existing valley fill (Guy Cove) as a proof-of-concept. The goal of the project was to evaluate whether or not a stream recreation could occur on mined lands, particularly …

Kentucky Water Resources Research Institute Annual Technical Report Fy 2014, Kentucky Water Resources Research Institute, University Of Kentucky

KWRRI Annual Technical Reports (USGS’s 104b Grant Program)

The 2014 Annual Technical Report for Kentucky consolidates reporting requirements for the Section 104(b) base grant award into a single document that includes: 1) a synopsis of each research project that was conducted during the period, 2) citations for related publications, reports, and presentations, 3) a description of information transfer activities, 4) a summary a student support during the reporting period, and 5) notable awards and achievements during the year.