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Physical Sciences and Mathematics Commons

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Full-Text Articles in Physical Sciences and Mathematics

Synthesis And Characterization Of Support-Modified Nanoparticle-Based Catalysts And Mixed Oxide Catalysts For Low Temperature Co Oxidation, Andrew Justin Binder May 2015

Synthesis And Characterization Of Support-Modified Nanoparticle-Based Catalysts And Mixed Oxide Catalysts For Low Temperature Co Oxidation, Andrew Justin Binder

Doctoral Dissertations

Heterogeneous catalysts are responsible for billions of dollars of industrial output and have a profound, if often understated, effect on our everyday lives. New catalyst technologies and methods to enhance existing catalysts are essential to meeting consumer demands and overcoming environmental concerns. This dissertation focuses on the development of catalysts for low temperature carbon monoxide oxidation. CO [carbon monoxide] oxidation is often used as a probe reaction to test overall oxidation activity of a given catalyst and is an important reaction in the elimination of toxic pollutants from automotive exhaust streams. The work included here presents three new heterogeneous catalysts …


Functional Nanostructures From Nanoparticle Building Blocks, Jimmy Lawrence Mar 2015

Functional Nanostructures From Nanoparticle Building Blocks, Jimmy Lawrence

Doctoral Dissertations

Advances in the synthetic strategies of engineered nanomaterials, multifunctional molecules and polymers have opened pathways for the development of functional nanomaterials having unique optoelectronic, mechanical, and biological properties. By designing the chemistry of surface ligands, the organic interface of nanoparticles, one can further the versatility and utilization of engineered nanomaterials, opening pathways for breakthroughs in sensing, catalysis, and delivery using nanomaterials. This thesis describes the synthesis and characterization of small molecule and polymer ligand functionalized inorganic nanoparticles (e.g., metal, semiconducting). Embedding specific chemical functionality into the ligand periphery of nanoparticles enables the resulting functional nanoparticles to react selectively …