Physical Sciences and Mathematics Commons^™

Geochemical And Petrological Characterization Of The Back Forty Volcanogenic Massive Sulfide Deposit, Anthony Robert Boxleiter

Masters Theses

The Back Forty Zn-Au deposit is the eastern-most Volcanogenic Massive Sulfide (VMS) deposit in the Penokean Volcanic Belt (PVB). It is the only VMS deposit found in Michigan, and is located along the east side of the Menominee River in Menominee County (45°26'57.5"N, 87°49'43.2"W). The Back Forty is the most zinc-enriched, copper depleted deposit among the major VMS deposits within the PVB that include Flambeau, Crandon, Bend, and Lynne. This work constitutes the first sulfur isotope study on the Back Forty VMS deposit.

The Back Forty is characterized by massive, semi-massive, disseminated and stringer sulfide mineralization hosted within felsic-dominated volcanic …

Petrological And Geochemical Evaluation Of The Sturgeon Falls Intrusive Body, Jonathan Michael Haynes

Masters Theses

The Sturgeon Falls Intrusive Body (SFIB) is a gabbroic intrusion located along the Michigan-Wisconsin border just south of the town of Norway, MI. The SFIB is bounded to the north by the Niagara Shear Zone and the Michigamme Formation (Schulz and Cannon, 2006) and to the south by an unnamed thrust fault zone and the Quinnesec Formation (Sims and Schulz, 1993). Field mapping has shown that the SFIB is composed almost entirely of metagabbro metamorphosed to greenschist facies, with isolated outcrops of clinopyroxenite, which are thought to be xenoliths.

The origin of the SFIB is controversial. Schulz and LeBerge (2003) …

Depositional Facies And Sequence Stratigraphy Of Niagaran-Lower Salina Reef Complex Reservoirs Of The Guelph Formation, Michigan Basin, Matthew J. Rine

Masters Theses

Hydrocarbon reservoirs in the Niagara-Lower Salina Reef Complex in the Michigan Basin have been extensively studied since the early 1960’s. These reservoirs host an immense hydrocarbon resource, existing as closely-spaced, highly-compartmentalized reservoirs that have produced >500 million barrels of oil and 2.9 trillion cubic feet of natural gas. Previous studies depict these “pinnacle reefs” as tall, symmetrical towers with a random distribution of facies. This study utilizes abundant core data (32 cores, 20-acre spacing), thin-section petrography, and petrophysical wire-line logs to reconstruct the geometry, facies distributions, depositional history, and sequence stratigraphy of the Columbus III Reef Complex within the Southern …

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm³/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …

Late Tertiary Tectonic Uplift In The Southern And Central Appalachians, Mary Sheela Biswal

Masters Theses

The exposed Appalachian Mountains extend about 2500 km from Newfoundland to Alabama with the highest peaks >2000 m above sea level. The last orogeny that affected Appalachian crust was the 325-260 Ma Alleghanian. Even with minimal erosion rates, it is highly unlikely that the Appalachians could have sustained such elevations for over 200 m.y., suggesting that recent tectonic uplift has produced today’s mountainous topography. The multiple phases of Tertiary uplift are related to poorly understood processes, but a large amount of data from today’s mountain chain and the adjacent Coastal Plain indicate the present high topography is anomalous and clearly …

Geological Controls On Stratigraphy And Sedimentation Of The Mississippian Marshall Formation, Michigan Basin, U.S.A., Joseph G. Adducci

Masters Theses

An understanding of regional orogenic, climatic, and eustatic processes is critical to the interbasinal correlation of Paleozoic strata in eastern North America. Tectonic activity associated with the culmination of Appalachian Orogenic events has been shown to have regional influence on paleostructure and sediment dispersal in the Appalachian foreland basin and adjacent intracratonic Illinois and Michigan basins. The culmination of the Acadian Orogeny at the end of the Devonian represents the beginning of a period of general tectonic quiescence extending throughout the early and middle Mississippian in eastern North America. Early Mississippian strata in the Michigan basin is distinctive and marks …

Europan Double Ridge Morphology As A Test For Hypothesized Models Of Formation, Ashley Caroline Dameron

Masters Theses

Double ridges on the Jovian satellite Europa consist of two ridges with a central trough. Several hypotheses exist describing their formation. Explosive cryovolcanism would result in granular ice depositing as two self-symmetric ridges flanking a central fracture, lying at or below the angle of repose (AOR). Cryo-sediments deposited by tidal squeezing and low-viscosity cryolavas emplaced by effusive cryovolcanism would likely have shallow slopes, although ridge symmetry is not expected. A second group of hypotheses involves brittle deformation of the crust, namely by diapirism, shear heating, and buckling of the lithosphere due to compression. Because these models involve uplifting vertical fractures, …

Geostatistical Analysis Of Point Soil Water Retention Parameters For Flint Sand, William Blake Roberts

Masters Theses

Geostatistics were employed to characterize sub-core scale heterogeneity and identify spatial structure in previously published water retention data (Kang et al., 2014) obtained using neutron radiography for Flint sand. The water retention data were parameterized using the Brooks and Corey (BC) model. The BC parameters investigated were: saturated water content (Ѳ_s), residual water content (Ѳ_r), air entry value (ψ_a), and pore size distribution index (λ). Spatial dependency in the BC parameters was identified using semivariograms. Of the four BC parameters analyzed, two were found to be spatially correlated, Ѳ …

Survival And Growth Rate Of Translocated Freshwater Mussels Lampsilis Fasciola And Medionidus Conradicus, Laura L. Pullum

Masters Theses

Freshwater mussels (Family Unionidae and Margaritiferidae) are a widely threatened group of bivalve molluscs, particularly in the Southeastern United States. Translocation of freshwater mussels is an increasingly common conservation method. However, there are relatively few studies that quantitatively investigate the factors influencing translocation success or failure. In October 2013, hundreds of Medionidus conradicus and Lampsilis fasciola were translocated to the Pigeon and Nolichucky Rivers in Tennessee, with an interim partial survey (June 2014) and a full survey (October 2014). In this study, I analyze this field-collected data to determine the mechanism(s) that currently influence the outcomes of Tennessee mussel translocation. …

Measurement Of Hysteretic Shale Capillary Pressure – Saturation Relationships Using A Water Activity Meter, Brendan Michael Donnelly

Masters Theses

Capillary pressure is the pressure difference across the interface of two immiscible fluids within a porous medium due to the interfacial tension between fluids and is related to both the properties of the fluids and the porous medium. Capillary pressure within a porous medium will change depending upon its degree of saturation. Understanding the relationship between capillary pressure and saturation for a rock allows for the modeling of multi-phase flow. Many traditional methods of measuring capillary pressure are unsuitable for the characterization of shale due to their inability to measure the high capillary pressures found within the small pores. Furthermore, …

Establishing A Chronology Of Late Quaternary Glacial Advances In The Cordillera De Talamanca, Costa Rica, Rebecca Susan Potter

Masters Theses

Little research has focused on glacial events in the tropics. Providing an absolute glacial chronology in Costa Rica will build a foundation for future glacial chronologies and paleoclimate reconstructions in the highlands of Central America. Evidence of past glaciation, including moraines and glacial lakes, is preserved within formerly glaciated valleys in the Cordillera de Talamanca. Orvis and Horn (2000) constrained deglaciation ages of the most recent glacial event in the Cordillera de Talamanca based on radiocarbon dates of glacial lake sediments. Radiocarbon ages indicated complete deglaciation after 12.4 ka cal BP but before 9.7 ka cal BP (Orvis and Horn, …

Dissolution, Ocean Acidification And Biotic Extinctions Prior To The Cretaceous/Paleogene (K/Pg) Boundary In The Tropical Pacific, Serena Dameron

Masters Theses

The several million years preceding the Cretaceous/Paleogene (K/Pg) boundary has been the focus of many studies. Changes in ocean circulation and sea level, extinctions, and major volcanic events have all been documented for this interval. Important research questions these changes raise include the climate dynamics during the warm, but not hot, time after the decay of the Late Cretaceous greenhouse interval and the stability of ecosystems prior to the mass extinctions at the end-Cretaceous.

I document several biotic perturbations as well as changes in ocean circulation during the Maastrichtian stage of the latest Cretaceous that question whether the biosphere was …

Thermal History Of The Michigan Basin: Results From Thermal Maturation Data And Geodynamic Modelling, Kirk A. Wagenvelt

Masters Theses

Thermal cooling, crustal convection, high temperature fluid advection, and 1.0 Km of eroded overburden are required to explain thermal maturation observations in the Michigan Basin. Observed tectonic subsidence in central Michigan follows an exponential decay indicative of thermal cooling following an anomalous heating event. Crustal convection is responsible for episodes of rapid subsidence coincident with the late Paleozoic Appalachian orogeny. Fluid advection through dilated faults reactivated by the Alleghanian orogeny brought hot fluids (as much as 255⁰ C) to the surface and impacted thermal maturation of organic matter in sediments. Models require 1.0 Km of eroded overburden to model thermal …

Lithologic Properties Of The Upper Ordovician Utica Formation, Michigan Basin, Usa: A Geological Characterization And Assessment Of Carbon Dioxide Confinement Potential, Frank Richard Sattler

Masters Theses

The Utica/Maquoketa Shale is considered to be the primary confining layer for Cambro-Ordovician CO₂ sequestration targets in the Midwest in the Michigan and Illinois basins, respectively. Prospective regional geologic seals in mudrock formations possess a combination of lithologic properties including nanometer scale pore space, elevated breakthrough pressures for non-wetting fluid phases and ductile mechanical deformation. Mineralogical composition is related to and typically controls these properties.

The objective of this study is to investigate the geological controls on stratigraphic and lithologic variability in the Utica/Collingwood in the Michigan basin. Twelve conventional cores and hundreds of modern well logs from the …

Anomalous Thermal Indicators From Authigenic Minerals In Upper Paleozoic Strata Of The Michigan Basin, Kyle Cox

Masters Theses

Indications of anomalous paleo-temperatures exist in strata of the Michigan basin, USA. The thermal history of the basin was investigated through identification and analysis of authigenic components in two Upper Paleozoic strata, the Devonian Dundee Formation and Mississippian Marshall Sandstone. Formation conditions for diagenetic phases in both units were estimated through a variety of means and compared to conditions expected for a simple burial model. Authigenic clays identified in the Marshall via X-ray diffraction are expected to have formed at temperatures above what would have been produced by burial alone. Stable isotope and fluid inclusion analysis indicate the same for …

Naturally-Occurring Metals Concentrations In Michigan Soils: A 2015 Survey, Zachary Lowell Spotts

Masters Theses

Closure of hazardous waste sites can be aided through the use of a soil background survey for metals. Data for these studies come from either field sampling or publicly available environmental files. Previous studies were conducted in Michigan, known as the Michigan Background Soil Survey (MBSS). The current update is a refinement and improvement of the 2005 update. New data was collected from publicly available environmental files and other sources. Both the current update and the 2005 update differentiated data by soil type and glacial lobe. GIS analysis was used to observe spatial distribution of the data and to determine …

Determining Discharge From The Fallasburg Dam And The Hydrology Of The Flat River Bypass Channel, Lowell, Michigan, Seth Kuiper

Masters Theses

The Fallasburg Dam on the Flat River is required to release 110 cfs to the Bypass Channel. Residents have often reported low flows in the river, especially during the summer. The hydrology of the Bypass Channel downstream from the dam was investigated to determine whether the required flow was being released. Discharge measured at multiple transects reveal a shifts from gaining to losing conditions during the year. Gaining conditions occur during the spring and after significant rain events; losing conditions occur in the summer during dry periods. Five discharge measurements in 2013 and three in 2014 reveal flows less than …

Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux

Masters Theses

Hydraulic fracturing of shale deposits has greatly increased the productivity of the natural gas industry by allowing it to exploit previously inaccessible reservoirs. However, previous research has demonstrated that this practice can contaminate shallow aquifers with CH₄ [methane] from deeper formations. This study compares concentrations and isotope compositions of CH₄ sampled from domestic groundwater wells in Letcher County, Kentucky in order to characterize its occurrence and origins in relation to neighboring hydraulically fractured natural gas wells. Additionally, this study tests the reliability of ²²²Rn [radon] as an alternative tracer to CH₄ in identifying processes of gas …

Hydrogeological Control On Spatial Patterns Of Groundwater Seepage In Peatlands, Danielle K. Hare

Masters Theses

Groundwater seepage to surface water is an important process to peatland ecosystems; however, the processes controlling seepage zone distribution and magnitude are not well understood. This lack of process-based understanding makes degraded peatland ecosystems difficult to restore and problematic for resource managers developing a sustainable design. Degraded peatlands, particularly abandoned cranberry farms, often have drainage ditches, applied surface sand, and decreased stream sinuosity to artificially lower the water table and support agriculture. These modifications disconnect the surface and groundwater continuum, which decreases thermal buffering of surface water significantly. The combination of a decreased influx of thermally buffered groundwater, a naturally …

Paleogeographic And Paleoenvironmental Evolution Of Lacustrine And Fluvial Upper Triassic Zhangjiatan Shale Sequence, Ordos Basin, China, Qiuwan Yu

Masters Theses

"Detailed sequence stratigraphic and depositional systems analyses can effectively delineate factors and processes controlling deposition of fine-grained lacustrine sediments. Upper Triassic Zhangjiatan (ZJT) Shale Bed and adjacent strata in Ordos foreland basin was used as an example. A new depositional sequence model shows that the maximum regressive shoreline was more landward than that at the lowest lake-level. The study area is on the ramp margin, covering 100x90 km². Thin sections, cores and well-logs of 80 wells are used to calibrate log signatures, document lithofacies, and interpret depositional facies in a sequence stratigraphic context. The entire sequence thickens from …

Palynological Interpretations Of Deep Sea Drilling Projects Cores In The Gulf Of Mexico And Bahamian Platform, Adam Patrick Barron

Masters Theses

"One hundred drill core samples were from Deep Sea Drilling Project (DSDP) Sites 94, 98, and 540 were investigated for their palynological contents (pollen, spores, acritarchs, dinoflagellate cysts, and dispersed organic matter) to infer the paleoenvironmental and paleoceanographic history of the Gulf of Mexico and the Bahamian Platform during the middle Eocene to middle Miocene interval. At Sites 94 and 540, abundant dinoflagellate cysts (chiefly Operculodinium centrocarpum, Lingulodinium machaerophorum, Impagidinium sp., Nematosphaeropsis sp., and Spiniferites spp.) were used as paleoenvironmental indicators. Two alternating palynofacies assemblages were identified from dispersed organic matter analysis: terrestrially influenced assemblage A and marine dominated assemblage …

A Geochemical Investigation Of Co₂ Sequestration And Site Characterization At Two Missouri Locations, Robert Allen Swain

Masters Theses

"The feasibility of sequestering CO₂ in saline aquifers of Lamotte Formation sandstone was investigated at wells located near Thomas Hill power plant, Moberly, MO and Sioux City Power Plant in Florissant, MO. Governing factors of using aquifers for CO₂ disposal include water salinity, potential for carbonic acid buffering, rate of precipitation of carbonate minerals following CO₂ introduction into the host aquifer, and the integrity of the Davis and Derby-DoeRun shale as a trap rock to prevent migration of the CO₂ phase and carbonic acid into the overlying potable Ozark Aquifer.

Both in situ and laboratory methods …