Physical Sciences and Mathematics Commons^™

Effect Of Mno2 Content On Electrochemical Capacitance Behavior Of Active Carbon Electrode, Kun Shen, Xian-Liang Zhou, Qi-Shun Duan

Journal of Electrochemistry

In this work, the manganese dioxide (MnO₂) materials were prepared by solution approach at low temperature, thermal decomposition and electrochemical deposition. The actived carbon (AC) and MnO₂ composite electrodes were used for aqueous supercapacitors. The morphologies and structures of the prepared materials were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), and the electrochemical behaviors were tested by cyclic voltammetry (CV) and galanostatic charge-discharge tests. Electrochemical test data show that the maximum specific capacitances of 151, 172 and 141 F•g^-1 were obtained with the contents of MnO₂ being 70, 60 and 70% in …

Special Issue: Electrochemistry Of Carbon Materials, Chen Wei

Journal of Electrochemistry

Carbon materials are traditional electrode materials due to their excellent electrical conductivities, high electrochemical stabilities and wide potential windows. Glassy carbon, graphite, various activated charcoals, carbon fibers etc. have been widely used in electrochemistry serving as electrode substrates or supports. In addition to their applications in basic electrochemistry, carbon materials have also played important roles in electrochemical energy storage and conversion. In recent years, various types of carbon structures, from zero-dimensional carbon nanodots, one-dimensional nanotubes, two-dimensional graphene to three-dimensional porous carbons, have attracted increasing attention in electrochemical field. It has been found that carbon materials have outstanding properties as advanced …

Colloidal Ionic Supercapacitors, Kun-Feng Chen, Dong-Feng Xue

Journal of Electrochemistry

Supercapacitors have high power density and long cycle life compared with battery systems, but they still suffer from low energy density at the same time. In order to increase the energy density of supercapacitors, we have developed a new type of pseudocapacitor, called colloidal ion supercapacitor, which can directly use commercial metal salts as electrode materials and form electroactive matter by in-situ electrochemical reactions without the need of additional materials synthesis processes. Colloidal ion supercapacitor can fully utilize the redox reaction of metal cations with multiple oxidation states, which can completely release the stored electrical energy of multiple-valence cations, leading …

Applications Of Carbon Materials In Electrochemical Energy Storage, Ji Liang, Lei Wen, Hui-Ming Cheng, Feng Li

Journal of Electrochemistry

An electrode material for electrochemical energy storage is one of the key components for high performance devices. In a variety of electrochemical energy storage systems, carbon materials, especially the lately emerged carbon nanomaterials including the carbon nanotube and graphene, have been playing a very important role and brought new vitality to the development and demonstration of the broad application prospects. In this review, we summarize the applications of various carbon materials in the typical electrochemical energy storage devices, namely lithium/sodium ion batteries, supercapacitors, and lithium-sulfur batteries, as well as flexible electrochemical energy storage and electrochemical catalysis. A perspective of novel …

Progress Of Self-Supported Supercapacitor Electrode Materials Based On Carbon Substrates, Shui-Jian He, Wei Chen

Journal of Electrochemistry

Self-supported electrode materials have been widely used in supercapacitors. Carbon materials are promising substrates in building self-supported electrode materials attributed to their diverse structures, rich resource, relatively low cost and high stability. Combined with our own research in this field, we summarize here the recent progress on the synthesis of self-supported electrode materials and their supercapacitance properties. The overall synthetic strategy could be divided into two categories: “top-down” and “bottom-up”. We hope this review is helpful for the development and application of renewable sources in self-supported electrode materials.

Synthesis Of Porous Carbon Nanosheets And Its Application In Sodium-Ion Battery, Jing-Fei Zhang, Jing Lu, Xiao-Yu Yang, Yun-Di Huang, Lin Xu, Dong-Mei Sun, Ya-Wen Tang

Journal of Electrochemistry

Owning to sodium’s high abundance, relatively low cost, similar chemical properties to Li and very suitable redox potential of E0(Na+/Na) = -2.71 V versus SHE which is only 0.3 V above that of lithium, rechargeable sodium ion battery hold much promise as potential alternatives to current lithium ion batteries for energy storage applications. Carbon material is regarded as the most promising anode candidate for sodium ion battery. Particularly, carbon nanosheet with porous structure and high conductivity is expected to have improved sodium ion storage properties. In this paper, we present a two-step pyrolysis-based method for facile synthesis of porous carbon …

Carbon Aerogel/Nickel Foam As Electrode For High-Performance Supercapacitor, Zhong Wu, Xin-Bo Zhang

Journal of Electrochemistry

Herein, a facile synthesis has been explored to prepare carbon aerogel/Ni foam. Graphene oxide, resorcinol and formaldehyde serve as precursors and polymerize in-situ on the Ni foam after hydrothermal synthesis at 85 oC. After lyophilization treatment, the carbon aerogel/Ni foam with porous structure can be obtained. Electrochemical investigations reveal that the carbon aerogel/Ni foam exhibits superior performances in both aqueous and organic electrolytes involving high specific capacitance and long-term cycling stability. The excellent properties can be ascribed to the unique formation and porous structure, which allows more effective transportations of electron and electrolyte ion.

Developing And Testing An Anguilliform Robot Swimming With Theoretically High Hydrodynamic Efficiency, John B. Potts Iii

University of New Orleans Theses and Dissertations

An anguilliform swimming robot replicating an idealized motion is a complex marine vehicle necessitating both a theoretical and experimental analysis to completely understand its propulsion characteristics. The ideal anguilliform motion within is theorized to produce ``wakeless'' swimming (Vorus, 2011), a reactive swimming technique that produces thrust by accelerations of the added mass in the vicinity of the body. The net circulation for the unsteady motion is theorized to be eliminated.

The robot was designed to replicate the desired, theoretical motion by applying control theory methods. Independent joint control was used due to hardware limitations. The fluid velocity vectors in the …

From Boolean Equalities To Constraints, Sergio Antoy, Michael Hanus

Computer Science Faculty Publications and Presentations

Although functional as well as logic languages use equality to discriminate between logically different cases, the operational meaning of equality is different in such languages. Functional languages reduce equational expressions to their Boolean values, True or False, logic languages use unification to check the validity only and fail otherwise. Consequently, the language Curry, which amalgamates functional and logic programming features, offers two kinds of equational expressions so that the programmer has to distinguish between these uses. We show that this distinction can be avoided by providing an analysis and transformation method that automatically selects the appropriate operation. Without this distinction …

Vanadium Oxide Thin-Film Variable Resistor-Based Rf Switches, Kuanchang Pan, Weisong Wang, Eunsung Shin, Kelvin Freeman, Guru Subramanyam

Guru Subramanyam

Vanadium dioxide (VO2) is a unique phase change material (PCM) that possesses a metal-to-insulator transition property. Pristine VO2 has a negative temperature coefficient of resistance, and it undergoes an insulator-to-metal phase change at a transition temperature of 68°C. Such a property makes the VO2 thin-film-based variable resistor (varistor) a good candidate in reconfigurable electronics to be integrated with different RF devices such as inductors, varactors, and antennas. Series single-pole single-throw (SPST) switches with integrated VO2 thin films were designed, fabricated, and tested. The overall size of the device is 380 μm × 600 μm. The SPST switches were fabricated on …

A High Performance Ceramic-Polymer Separator For Lithium Batteries, Jitendra Kumar, Padmakar Kichambare, Amarendra K. Rai, Rabi Bhattacharya, Stanley J. Rodrigues, Guru Subramanyam

Guru Subramanyam

A three-layered (ceramic-polymer-ceramic) hybrid separator was prepared by coating ceramic electrolyte [lithium aluminum germanium phosphate (LAGP)] over both sides of polyethylene (PE) polymer membrane using electron beam physical vapor deposition (EB-PVD) technique. Ionic conductivities of membranes were evaluated after soaking PE and LAGP/PE/LAGP membranes in a 1 Molar (1M) lithium hexafluroarsenate (LiAsF6) electrolyte in ethylene carbonate (EC), dimethyl carbonate (DMC) and ethylmethyl carbonate (EMC) in volume ratio (1:1:1). Scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques were employed to evaluate morphology and structure of the separators before and after cycling performance tests to better understand structure-property correlation. As compared …

Industry-University Collaboration: A University Of Dayton Model, Guru Subramanyam

Guru Subramanyam

This paper introduces industry-university collaboration activities currently in place at the University of Dayton's School of Engineering. These collaborations are important to prepare industry-ready graduates who excel in technical, entrepreneurial, and leadership skills. One of the key curricular components is the industry-sponsored multidisciplinary projects. Industry involvement in advisory committee, strategic research partnerships, and other forms are discussed.

College Of Engineering Senior Design Competition Fall 2015, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

An Organic Mixed Ion-Electron Conductor For Power Electronics, Abdellah Malti, Jesper Edberg, Hjalmar Granberg, Zia Ullah Khan, Jens W. Andreasen, Xianjie Liu, Dan Zhao, Hao Zhang, Yulong Yao, Joseph W. Brill, Isak Engquist, Mats Fahlman, Lars Wågberg, Xavier Crispin, Magnus Berggren

Physics and Astronomy Faculty Publications

A mixed ionic–electronic conductor based on nanofibrillated cellulose composited with poly(3,4-ethylene-dioxythio­phene):­poly(styrene-sulfonate) along with high boiling point solvents is demonstrated in bulky electrochemical devices. The high electronic and ionic conductivities of the resulting nanopaper are exploited in devices which exhibit record values for the charge storage capacitance (1F) in supercapacitors and transconductance (1S) in electrochemical transistors.

Interface And Morphology Engineering In Solution-Processed Electronic And Optoelectronic Devices, Sanjib Das

Doctoral Dissertations

The first part of this dissertation focuses on interface and morphology engineering in polymer- and small molecule-based organic solar cells. High-performance devices were fabricated, and the device performance was correlated with nanoscale structures using various electrical, spectroscopic and microscopic characterization techniques, providing guidelines for high-efficiency cell design.

The second part focuses on perovskite solar cells (PSCs), an emerging photovoltaic technology with skyrocketing rise in power conversion efficiency (PCE) and currently showing comparable PCEs with those of existing thin film photovoltaic technologies such as CIGS and CdTe. Fabrication of large-area PSCs without compromising reproducibility and device PCE requires formation of dense, …

Neuron Clustering For Mitigating Catastrophic Forgetting In Supervised And Reinforcement Learning, Benjamin Frederick Goodrich

Doctoral Dissertations

Neural networks have had many great successes in recent years, particularly with the advent of deep learning and many novel training techniques. One issue that has affected neural networks and prevented them from performing well in more realistic online environments is that of catastrophic forgetting. Catastrophic forgetting affects supervised learning systems when input samples are temporally correlated or are non-stationary. However, most real-world problems are non-stationary in nature, resulting in prolonged periods of time separating inputs drawn from different regions of the input space.

Reinforcement learning represents a worst-case scenario when it comes to precipitating catastrophic forgetting in neural networks. …

Energy Forecasting For Event Venues: Big Data And Prediction Accuracy, Katarina Grolinger, Alexandra L'Heureux, Miriam Am Capretz, Luke Seewald

Electrical and Computer Engineering Publications

Advances in sensor technologies and the proliferation of smart meters have resulted in an explosion of energy-related data sets. These Big Data have created opportunities for development of new energy services and a promise of better energy management and conservation. Sensor-based energy forecasting has been researched in the context of office buildings, schools, and residential buildings. This paper investigates sensor-based forecasting in the context of event-organizing venues, which present an especially difficult scenario due to large variations in consumption caused by the hosted events. Moreover, the significance of the data set size, specifically the impact of temporal granularity, on energy …

Water Withdrawal And Consumption Reduction Analysis For Electrical Energy Generation System, Narjes Nouri

Theses and Dissertations

There is an increasing concern over shrinking water resources. Water use in the energy sector primarily occurs in electricity generation. Anticipating scarcer supplies, the value of water is undoubtedly on the rise and design, implementation, and utilization of water saving mechanisms in energy generation systems are becoming inevitable. Most power plants generate power by boiling water to produce steam to spin electricity-generating turbines. Large quantities of water are often used to cool the steam in these plants. As a consequence, most fossil-based power plants in addition to consuming water, impact the water resources by raising the temperature of water withdrawn …

Swat Model Simulation Of Bioenergy Crop Impacts On Water Quality In Cache River Watershed, Eeshan Kumar

Graduate Theses and Dissertations

Energy security through increased biofuel production is one of the components of the Energy Independence and Security Act (EISA) 2007. As per EISA 2007 mandate, appropriate independent research institutes are required to assess concerns to natural biodiversity due to biofuel production and report it to the Congress through the Environment Protection Agency (EPA). Planners, researchers, and agencies concerned with environmental regulations, ideally, would like to have location-specific information about the impacts for developing appropriate management interventions. This study examines long-term impacts on water quality in response to targeted (i.e. marginal lands) production of biofuel crops by setting up two SWAT …

Automated Multi-Modal Search And Rescue Using Boosted Histogram Of Oriented Gradients, Matthew A. Lienemann

Master's Theses

Unmanned Aerial Vehicles (UAVs) provides a platform for many automated tasks and with an ever increasing advances in computing, these tasks can be more complex. The use of UAVs is expanded in this thesis with the goal of Search and Rescue (SAR), where a UAV can assist fast responders to search for a lost person and relay possible search areas back to SAR teams. To identify a person from an aerial perspective, low-level Histogram of Oriented Gradients (HOG) feature descriptors are used over a segmented region, provided from thermal data, to increase classification speed. This thesis also introduces a dataset …

Object Detection And Tracking In Wide Area Surveillance Using Thermal Imagery, Santosh Bhusal

UNLV Theses, Dissertations, Professional Papers, and Capstones

The main objective behind this thesis is to examine how existing vision-based detection and tracking algorithms perform in thermal imagery-based video surveillance. While color-based surveillance has been extensively studied, these techniques can not be used during low illumination, at night, or with lighting changes and shadows which limits their applicability. The main contributions in this thesis are (1) the creation of a new color-thermal dataset, (2) a detailed performance comparison of different color-based detection and tracking algorithms on thermal data and (3) the proposal of an adaptive neural network for false detection rejection.

Since there are not many publicly available …

Designing, Building And Testing A Solar Thermoelectric Generation, Steg, For Energy Delivery To Remote Residential Areas In Developing Regions, Yacouba Moumouni

UNLV Theses, Dissertations, Professional Papers, and Capstones

New alternatives and inventive renewable energy techniques which encompass both generation and power management solutions are fundamental for meeting remote residential energy supply and demand today, especially if the grid is quasi-inexistent. Solar thermoelectric generators can be a cost-effective alternative to photovoltaics for a remote residential household power supply. A complete solar thermoelectric energy harvesting system is presented for energy delivery to remote residential areas in developing regions. To this end, the entire system was built, modeled, and then validated with LTspice simulator software via thermal-to-electrical analogy schemes. Valuable data in conjunction with two novel LTspice circuits were obtained, showing …

Optical Communication Using Hybrid Micro Electro Mechanical Structures (Mems) And Commercial Corner Cube Retroreflector (Ccr), Sunny Kedia

USF Tampa Graduate Theses and Dissertations

This dissertation presents a free-space, long-range, passive optical communication system that uses electrostatically modulated microelectromechanical systems (MEMS) structures coupled with a glass total internal reflection (TIR)-type corner cube retroreflector (CCR) as a non-emitting data transmitter. A CCR consists of three mirrors orthogonal to each other, so that the incident beam is reflected back to the incident beam, source. The operational concept is to have a MEMS modulator fusion with TIR CCR, such that the modulators are working periodically to disrupt the evanescent waves at the air interface of one of the three back glass faces of a TIR CCR. The …

Investigation Of Real-Time Optical Scanning Holography, Bradley D. Duncan

Bradley D. Duncan

Real-time holographic recording using an optical heterodyne scanning technique was proposed by Poon in 1985. The first part of this dissertation provides a detailed theoretical treatment of the technique, based on a Gaussian beam analysis. Topics to be addressed include the derivations of the optical transfer function (OTF) and impulse response of the scanning holographic recording system, reconstructed image resolution and magnification, methods of carrier frequency hologram generation and experimental verification of the recording technique based on careful measurements of a hologram corresponding to a simple transmissive slit. Furthermore, computer simulations are presented pertaining to the incoherent nature of the …

Review: 'Optical Fiber Communications' (2nd Edition), By Gerd Keiser, Bradley D. Duncan

Bradley D. Duncan

If first impressions are worth anything (and they usually are), I would have to admit that my first impression of the second edition of Gerd Keiser's now popular text Optical Fiber Communications was quite good. My compliments are hereby extended to the publisher for choosing a rather handsome cover and dust jacket. It stands in strong contrast to the text's first edition, which still ranks as probably the ugliest book I own, with color choices ranging from dull cream and "baby" blue to pale pink! I am now happy to say that this older version has been discretely·retired to the …

Review: 'Theory Of Dielectric Optical Waveguides,' 2nd Edition, By Dietrich Marcuse, Bradley D. Duncan

Bradley D. Duncan

I suppose I ought to say up front that while preparing this review I often found myself feeling very much like a student evaluating his teacher. After all, it was, in part, the first edition of Dietrich Marcuse's Theory of Dielectric Optical Waveguides (among a handful of other similar texts) from which I first studied the principles of optical waveguide theory under the demanding, yet patient and graceful guidance of Dr. Ahmad Safaai-Jazi. Thus with the utmost respect for a teacher whom I have never met, I shall try to faithfully share my thoughts and feelings regarding the second edition …

Modal Interference Techniques For Strain Detection In Few-Mode Optical Fibers, Bradley D. Duncan

Bradley D. Duncan

Interference between the modes of an optical fiber results in specific intensity patterns which can be modulated as a function of disturbances in the optical fiber system. These modulation effects are a direct result of the difference in propagation constants of the constituent modes. In this presentation it is shown how the modulated intensity patterns created by the interference of specific mode groups in few-mode optical fibers (V < 5.0) can be used to detect strain. A detailed discussion of the modal phenomena responsible for the observed strain induced pattern modulation is given and it is shown that strain detection sensitivities …

Review: 'Integrated Optics: Design And Modeling,' By Reinhard Marz, Bradley D. Duncan

Bradley D. Duncan

My overall impression is that Integrated Optics: Design and Modeling will make a fine addition to almost anyone's collection of books on integrated optics. It will, however, serve its readers better as a reference book than as a text from which to first learn the basic concepts of integrated optics. I say this because the book is written at a fairly sophisticated technical level, though the author often moves rather quickly to the "bottom line" without providing material much beyond what is first necessary to introduce a problem or concept, and then a statement of the results and/or implications. It …

Index-Matched Boundary Techniques For The Elimination Of Acoustical Resonances, Jack H. Parker, Bradley D. Duncan

Bradley D. Duncan

We extend the principle of optical index of refraction to apply the concept of acoustical index for transverse acoustical wave propagation in strings. The relationship between acoustical index and mass density of the acoustic material is developed. With this theoretical link established, classic index-matching techniques are explored at acoustical boundaries. Proper selection of boundary interface segments leads to the elimination of resonant vibrationalmodes that occur in rigidly supported strings, while maintaining the nonresonant vibration response.

Heterodyne Ladar System Efficiency Enhancement Using Single-Mode Optical Fiber Mixers, Donald K. Jacob, Martin B. Mark, Bradley D. Duncan

Bradley D. Duncan

A theoretical performance analysis of a heterodyne ladar system incorporating a single-mode fiber receiver has been performed. For our purposes, the performance parameters of interest are the coupling and mixing efficiency of the ladar receiver, as they relate to the overall system carrier-to-noise ratio. For a receiver incorporating a single-mode fiber mixer, the received and local-oscillator fields are matched both spatially and temporally at the detector, yielding 100% mixing efficiency. We have therefore focused our efforts on determining an expression for the efficiency with which a diffuse return from a purely speckle target can be coupled into the receiving leg …