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Physical Sciences and Mathematics Commons

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2015

Chemistry

Electronic Thesis and Dissertation Repository

Cathodic reaction.

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The Influence Of Alloying Elements On The Crevice Corrosion Behaviour Of Ni-Cr-Mo Alloys, Nafiseh Ebrahimi Oct 2015

The Influence Of Alloying Elements On The Crevice Corrosion Behaviour Of Ni-Cr-Mo Alloys, Nafiseh Ebrahimi

Electronic Thesis and Dissertation Repository

To enhance its corrosion resistance in aggressive media, Ni is alloyed with various amounts of Cr and Mo along with small amounts of other alloying elements such as W, Cu, and Fe. While the resulting alloys (known as Ni superalloys) show excellent passive behaviour, the function of individual alloying elements in resisting localized corrosion processes, in particular crevice corrosion is not fully understood. This study focuses on the electrochemistry and corrosion of a series of Ni-Cr-Mo (W) alloys with various Cr and Mo contents. Several electrochemical and surface characterization techniques were used to investigate the role of major alloying elements …