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Full-Text Articles in Physical Sciences and Mathematics
Estimating Hydroxyl Radical Photochemical Formation Rates In Natural Waters During Long-Term Laboratory Irradiation Experiments, Luni Sun, Hongmei Chen, Hussain A. Abdulla, Kenneth Mopper
Estimating Hydroxyl Radical Photochemical Formation Rates In Natural Waters During Long-Term Laboratory Irradiation Experiments, Luni Sun, Hongmei Chen, Hussain A. Abdulla, Kenneth Mopper
Chemistry & Biochemistry Faculty Publications
In this study it was observed that, during long-term irradiations (>1 day) of natural waters, the methods for measuring hydroxyl radical (˙OH) formation rates based upon sequentially determined cumulative concentrations of photoproducts from probes significantly underestimate actual ˙OH formation rates. Performing a correction using the photodegradation rates of the probe products improves the ˙OH estimation for short term irradiations (<1 day), but not long term irradiations. Only the ‘instantaneous’ formation rates, which were obtained by adding probes to aliquots at each time point and irradiating these sub-samples for a short time (≤2 h), were found appropriate for accurately estimating ˙OH photochemical formation rates during long-term laboratory irradiation experiments. Our results also showed that in iron- and dissolved organic matter (DOM)-rich water samples, ˙OH appears to be mainly produced from the Fenton reaction initially, but subsequently from other sources possibly from DOM photoreactions. Pathways of ˙OH formation in long-term irradiations in relation to H2O2 and iron concentrations are discussed.
Separated Response Function Ratios In Exclusive, Forward Π± Electroproduction, G. M. Huber, H. P. Blok, C. Butuceanu, D. Gaskell, T. Horn, D. J. Mack, D. Abbott, A. Klein, L. M. Qin, K. Vansyoc
Separated Response Function Ratios In Exclusive, Forward Π± Electroproduction, G. M. Huber, H. P. Blok, C. Butuceanu, D. Gaskell, T. Horn, D. J. Mack, D. Abbott, A. Klein, L. M. Qin, K. Vansyoc
Physics Faculty Publications
The study of exclusive π± electroproduction on the nucleon, including separation of the various structure functions, is of interest for a number of reasons. The ratio R-L=sigma(pi-)(L) / sigma(pi+)(L) is sensitive to isoscalar contamination to the dominant isovector pion exchange amplitude, which is the basis for the determination of the charged pion form factor from electroproduction data. A change in the value of R-T=sigma(pi-)(L) / sigma(pi+)(L) from unity at small -t, to 1/4 at large -t, would suggest a transition from coupling to a (virtual) pion to coupling to individual quarks. Furthermore, the mentioned ratios may show an earlier …
Photoproduction Of Π0 On Hydrogen With Clas From 1.1 Gev - 5.45 Gev Using E+E –Γ Decay, Michael C. Kunkel
Photoproduction Of Π0 On Hydrogen With Clas From 1.1 Gev - 5.45 Gev Using E+E –Γ Decay, Michael C. Kunkel
Physics Theses & Dissertations
Photoproduction of the π0 meson was studied using the CLAS detector at the Thomas Jefferson National Accelerator Facility using tagged incident photon energies spanning the range Eγ = 1.1 GeV - 5.45 GeV. The measurement is performed on a liquid hydrogen target in the reaction γp → pe +e–(γ). The final state of the reaction is the sum of two subprocesses for π0 decay, the Dalitz decay mode of π0 → e +e–γ and conversion mode where one photon from π0 → γγ decay is converted into a …