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Full-Text Articles in Physical Sciences and Mathematics
Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman
Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman
Chemistry Faculty Publications
Anthropogenic emissions of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of humic-like substances (HULIS). Because further processing of polyphenols in secondary organic aerosols (SOA) can continue mediated by a mechanism of ozonolysis at interfaces, a better understanding about how these reactions proceed at the air–water interface is needed. This work shows how catechol, a molecular probe of the oxygenated aromatic hydrocarbons present in SOA, can contribute interfacial reactive species that enhance the production of HULIS under atmospheric conditions. Reactive semiquinone radicals are quickly produced upon …
Climate Change And Forest Fires Synergistically Drive Widespread Melt Events Of The Greenland Ice Sheet, Kaitlin M. Keegan, Mary R. Albert, Joseph R. Mcconnell, Ian Baker
Climate Change And Forest Fires Synergistically Drive Widespread Melt Events Of The Greenland Ice Sheet, Kaitlin M. Keegan, Mary R. Albert, Joseph R. Mcconnell, Ian Baker
Dartmouth Scholarship
In July 2012, over 97% of the Greenland Ice Sheet experienced surface melt, the first widespread melt during the era of satellite remote sensing. Analysis of six Greenland shallow firn cores from the dry snow region confirms that the most recent prior widespread melt occurred in 1889. A firn core from the center of the ice sheet demonstrated that exceptionally warm temperatures combined with black carbon sediments from Northern Hemisphere forest fires reduced albedo below a critical threshold in the dry snow region, and caused the melting events in both 1889 and 2012. We use these data to project the …
Using Green Building To Mitigate Climate Change In The Twenty-First Century, Lisa Battiste
Using Green Building To Mitigate Climate Change In The Twenty-First Century, Lisa Battiste
Honors Theses
The need for green buildings are rapidly becoming more important as the nation faces impending energy crises and the world heats up from the overabundance of greenhouse gases. Buildings in America are one of the largest consumers of energy and one of the greatest contributors to CO2 emissions; more than the total emissions from all the transportation vehicles used every day. By making the construction and use of buildings more resource efficient, this can help alleviate the environmental strain of climate change. Neutralizing or eliminating carbon emissions from building use will significantly reduce the amount of greenhouse gases in the …
Impacts Of Climate Change On Soil Microorganisms In Northern Hardwood Forests, Carley Jane Kratz
Impacts Of Climate Change On Soil Microorganisms In Northern Hardwood Forests, Carley Jane Kratz
Dissertations, Master's Theses and Master's Reports - Open
As global climate continues to change, it becomes more important to understand possible feedbacks from soils to the climate system. This dissertation focuses on soil microbial community responses to climate change factors in northern hardwood forests. Two soil warming experiments at Harvard Forest in Massachusetts, and a climate change manipulation experiment with both elevated temperature and increased moisture inputs in Michigan were sampled. The hyphal in-growth bag method was to understand how soil fungal biomass and respiration respond to climate change factors. Our results from phospholipid fatty acid (PLFA) analyses suggest that the hyphal in-growth bag method allows relatively pure …
Modeling The Effects Of The Hemlock Woolly Adelgid On Carbon Storage In Northern New England Forests, Jeffrey John Krebs
Modeling The Effects Of The Hemlock Woolly Adelgid On Carbon Storage In Northern New England Forests, Jeffrey John Krebs
Graduate College Dissertations and Theses
The hemlock woolly adelgid (HWA, Adelges tsugae Annand) is an invasive insect that threatens to eradicate native eastern hemlock (Tsuga canadensis (L.) Carr.) across the eastern United States. In southern New England and southern Appalachian forests, HWA-induced hemlock mortality has impacted carbon (C) flux by altering stand age, litter composition, species composition, and coarse woody debris levels. However, no one has examined how total C storage and sequestration may be impacted by these changes. Further, while projections are that HWA will ultimately infest hemlock across its entire geographic range, the majority of studies have been limited to southern New …