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Full-Text Articles in Physical Sciences and Mathematics

Self-Assembly And Ring-Opening Metathesis Polymerization Of A Bifunctional Carbonate–Stilbene Macrocycle, Yuewen Xu, Weiwei L. Xu, Mark D. Smith, Linda S. Shimizu Nov 2014

Self-Assembly And Ring-Opening Metathesis Polymerization Of A Bifunctional Carbonate–Stilbene Macrocycle, Yuewen Xu, Weiwei L. Xu, Mark D. Smith, Linda S. Shimizu

Faculty Publications

No abstract provided.


Sustainable Thermoplastic Elastomers Derived From Renewable Cellulose, Rosin And Fatty Acids, Y. Liu, K. Yao, Xiaoming Chen, Jifu Wang, Zhongkai Wang, Harry J. Ploehn, C. Wang, F. Chu, Chuanbing Tang Jan 2014

Sustainable Thermoplastic Elastomers Derived From Renewable Cellulose, Rosin And Fatty Acids, Y. Liu, K. Yao, Xiaoming Chen, Jifu Wang, Zhongkai Wang, Harry J. Ploehn, C. Wang, F. Chu, Chuanbing Tang

Faculty Publications

Two series of graft copolymers, cellulose-g-poly(n-butyl acrylate-co-dehydroabietic ethyl methacrylate) (Cell-g-P(BA-co-DAEMA)) and cellulose-g-poly(lauryl methacrylate-co-dehydroabietic ethyl methacrylate) (Cell-g-P(LMA-co-DAEMA)), were prepared by “grafting from” atom transfer radical polymerization (ATRP). In these novel graft copolymers, cellulose, DAEMA (derived from rosin), and LMA (derived from fatty acids) are all sourced from renewable natural resources. The “grafting from” ATRP strategy allows the preparation of high molecular weight graft copolymers consisting of a cellulose main chain with acrylate copolymer side chains. By manipulating the monomer ratios in the P(BA- …