Physical Sciences and Mathematics Commons^™

Iron-Doped Zinc Selenide: Spectroscopy And Laser Development, Jonathan W. Evans

Theses and Dissertations

We examine the quantum mechanics of optically active ions in crystals. Insight is developed which qualitatively explains the shape of the optical absorption and emission spectra of Fe²⁺ ions in II-VI materials. In addition to a discussion of the relevant theory, this work explores experimental techniques for absorption spectroscopy, laser-induced fluorescence spectroscopy, and upper-state lifetime measurements in detail. The data collected from these experiments are interpreted in the context of the theories developed herein. The theory and data are used to develop a simple model of the temperature dependence of the upper-state lifetime of Fe²⁺ ions in ZnSe. …