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Electron-Impact Vibrational Excitation Of Vibrationally Excited H2 Molecules Involving The Resonant 2(Sigma)G+ Rydberg-Excited Electronic State, R Celiberto, R. K. Janev, V Laporta, J Tennyson, J. M. Wadehra

Physics and Astronomy Faculty Research Publications

Electron-impact theoretical cross sections and rate coefficients for vibrational excitation of vibrationally excited H2 molecules, occurring through the H−2 resonant species in the 2Σ+g Rydberg-excited electronic state, are presented. The cross sections are calculated as functions of the incident electron energy by adopting the local-complex-potential model for resonant collisions and by using ab initio calculated molecular potentials and resonance widths. The calculations have been extended to all possible vibrational transitions linking all 15 vibrational levels of the electronic ground state of the H2 molecule. The corresponding rate coefficients are also obtained as a function of the electron temperature by assuming …