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Full-Text Articles in Physical Sciences and Mathematics
The Importance Of The Rotor In Hydrazone-Based Molecular Switches, Xin Su, Timo Lessing, Ivan Aprahamian
The Importance Of The Rotor In Hydrazone-Based Molecular Switches, Xin Su, Timo Lessing, Ivan Aprahamian
Dartmouth Scholarship
The pH-activated E/Z isomerization of a series of hydrazone-based systems having different functional groups as part of the rotor (R = COMe, CN, Me, H), was studied. The switching efficiency of these systems was compared to that of a hydrazone-based molecular switch (R = COOEt) whose E/Z isomerization is fully reversible. It was found that the nature of the R group is critical for efficient switching to occur; the R group should be a moderate H-bond acceptor in order to (i) provide enough driving force for the rotor to move upon protonation, and (ii) stabilize the obtained Z configuration, to …
Variability Of Black Carbon Deposition To The East Antarctic Plateau, 1800-2000 Ad, M. M. Bisiaux, R. Edwards, J. R. Mcconnell, M. R. Albert
Variability Of Black Carbon Deposition To The East Antarctic Plateau, 1800-2000 Ad, M. M. Bisiaux, R. Edwards, J. R. Mcconnell, M. R. Albert
Dartmouth Scholarship
Refractory black carbon aerosols (rBC) from biomass burning and fossil fuel combustion are deposited to the Antarctic ice sheet and preserve a history of emissions and long-range transport from low- and mid-latitudes. Antarctic ice core rBC records may thus provide information with respect to past combustion aerosol emissions and atmospheric circulation. Here, we present six East Antarctic ice core records of rBC concentrations and fluxes covering the last two centuries with approximately annual resolution (cal. yr. 1800 to 2000). The ice cores were drilled in disparate regions of the high East Antarctic ice sheet, at different elevations and net snow …
3,3-Dimethyl-1,2,3,4-TetraHydroCycloPenta[B]Indole-1,2-Dione (Bruceolline E), Jason A. Jordon, Jeanese C. Badenock, Gordon W. Gribble, Jerry P. Jasinski, James A. Golen
3,3-Dimethyl-1,2,3,4-TetraHydroCycloPenta[B]Indole-1,2-Dione (Bruceolline E), Jason A. Jordon, Jeanese C. Badenock, Gordon W. Gribble, Jerry P. Jasinski, James A. Golen
Dartmouth Scholarship
The title compound, C13H11NO2, crystallizes with two molecules in the asymmetric unit. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which link the molecules into chains along [10], and weak C—H⋯O interactions.