Physical Sciences and Mathematics Commons^™

Dendroclimatology And Woodland Dynamics On The Volcanic Badlands Of Western New Mexico, U.S.A., Mark Daniel Spond

Doctoral Dissertations

My dissertation research addressed woodland dynamics and dendroclimatology on the volcanic badlands of western New Mexico. The research was intended to complement previous studies by: (1) assessing vegetation structure and composition dynamics at El Malpais National Monument between 1948–2010 using repeat photography; (2) improving knowledge of the influence of climate and land use on vegetation dynamics at El Malpais National Monument; (3) providing a unique tree-ring data set from Rocky Mountain juniper growing on the malpais; (4) elucidating relationships between Pacific teleconnections and radial growth in Rocky Mountain juniper; and (5) improving understanding of the dynamic nature of climate in …

Polymer Nanocomposite Analysis And Optimization For Renewable Energy And Materials, Nathan Walter Henry

Doctoral Dissertations

Polymer nanocomposites are an important research interest in the area of engineering and functional materials, including the search for more environmentally materials for renewable energy and materials. The ability to analyze and optimize morphology is crucial to realizing their potential, since the distribution of materials in the composite strongly influences its properties. This dissertation presents research into three different polymer nanocomposite systems with three different applications that underscore the need to understand and control the composite morphology to succeed.

The first project details work on development of a copolymer compatibilizer to enhance the dispersion of the plant-derived biopolymer lignin in …

Adsorption Of Hydrogen Onto Bare And Metal Decorated Metal Oxides, Paige Elizabeth Landry

Doctoral Dissertations

Catalytically relevant metal clusters were deposited on metal oxide supports. Palladium and gold were deposited on mixed morphology ZnO, and palladium was deposited on MgO(100). The materials were characterized with electron microscopy, photoluminescent spectroscopy, and X-ray photoelectron spectroscopy. The behavior of hydrogen on these materials, as well as bare ZnO, was studied using volumetric isotherms. The isotherms were used to determine the monolayer gas coverage, surface

area, and heats of adsorption of hydrogen on these materials over the temperature range of approximately 8-13 K. At the temperatures and pressures studied, hydrogen physically adsorbed onto the materials. Additional investigations with inelastic …

Experimental Investigations Of Fluid–Mineral Interactions In Olivine And Dolomite, Michael Thomas Deangelis

Doctoral Dissertations

Geochemical processes involving the interaction of fluids and minerals occur in nearly every environment on the surface and in the crust of the Earth. The variety of fluid–mineral processes on the Earth is quite diverse, and these various processes can occur under a large range of geochemical conditions. Aqueous dissolution and alteration, hydration, protonation, solution–precipitation, diffusion, and fluid and isotope exchange are among the many fluid–mineral interaction processes that contribute to the overall cycling of elements on Earth. This dissertation uses analog experiments to examine fluid­–mineral interaction processes found in different geological environments and under a range of environmental conditions. …

Calculation Of Physical Processes At The Lhc, Usama Adnan Al-Binni

Doctoral Dissertations

With the start of the age of the Large Hadron Collider (LHC) two challenges face theoreticians and computational physicists. The first is about understanding theories beyond the Standard Model and producing verifiable predictions that can be tested against what the LHC and subsequent machines would produce. The second is to improve computational methods so that the new experimental precision is matched by a theoretical one. But this improvement is also crucial for the detection of potential deviations from Standard Model predictions and possibly also finding the elusive Higgs. This work tries to address problems in both areas. In the first …

Population Of Low-Lying Levels In The One-Neutron Halo Nucleus 11be Via The Neutron Transfer Reaction 10be(D,P), Kyle Thomas Schmitt

Doctoral Dissertations

Historically, measurements of differential cross-sections for the neutron transfer reaction (d, p) on stable targets have been an important tool for extracting spectroscopic information. In particular, it is possible to make orbital angular momentum assignments and extract spectroscopic factors for ground states and excited states by comparing measurements to cross sections calculated for pure single-particle states. In recent years, the advent of rare isotope beams have made it possible to apply this method to increasingly exotic nuclei. As nucleon separation energies decrease along the path to the proton and neutron drip lines, many new reaction channels are opened. Out of …

Analysis Of 26Al + P Elastic And Inelastic Scattering Reactions And Galactic Abundances Of 26Al, Stephen Todd Pittman

Doctoral Dissertations

²⁶Al(p,p)²⁶Al and ²⁶Al(p,p’)²⁶Al^* scattering reactions were performed at the Holifield Radioactive Ion Beam Facility (HRIBF) at the Oak Ridge National Laboratory (ORNL). The purpose of the elastic scattering study was to determine properties of previously uncharacterized ²⁷Si levels above the proton threshold in the energy range E(c.m.) ~ 0.5 - 1.5 MeV and to calculate reaction rates for the ²⁶Al(p,γ[gamma])²⁷Si reaction that destroys ²⁶Al. The inelastic scattering reaction was also evaluated to investigate the reaction that produces the metastable state of ²⁶Al at E(c.m.) = 228 keV, …

Water Ice Films In Cryogenic Vacuum Chambers, Jesse Michael Labello

Doctoral Dissertations

The space simulation chambers at Arnold Engineering Development Complex (AEDC) allow for the testing and calibration of seeker sensors in cryogenic, high vacuum environments. During operation of these chambers, contaminant films can form on the components in the chamber and disrupt operation. Although these contaminant films can be composed of many molecular species, depending on the species outgassed by warm chamber components and any leaks or virtual leaks (pockets of gas trapped within a vacuum chamber) that may be present, water vapor is most common, and it will be the focus of this dissertation. In this dissertation, some properties of …

Radii And Neutron Correlations Of (6,8)He Within The Gamow Shell Model, Georgios Papadimitriou

Doctoral Dissertations

We study the spatial correlations between halo neutrons in ^6,8He within the complex-energy Gamow Shell Model (GSM). To this end, we calculate the neutron and proton radii, and two-neutron correlations in a large shell model space consisting of the 0p_3/2 resonance and non-resonant p-sd scattering continuum. We use schematic forces and the finite-range Modified Minnesota interaction.
The calculated charge radii, corrected for the core polarization and spin-orbit effects, are compared to the values extracted from measured atomic isotope shifts.
We find that the charge radius of ⁶He primarily depends on the two-neutron separation energy and the shell-model …

A Scalable Architecture For Simplifying Full-Range Scientific Data Analysis, Wesley James Kendall

Doctoral Dissertations

According to a recent exascale roadmap report, analysis will be the limiting factor in gaining insight from exascale data. Analysis problems that must operate on the full range of a dataset are among the most difficult. Some of the primary challenges in this regard come from disk access, data managment, and programmability of analysis tasks on exascale architectures. In this dissertation, I have provided an architectural approach that simplifies and scales data analysis on supercomputing architectures while masking parallel intricacies to the user. My architecture has three primary general contributions: 1) a novel design pattern and implmentation for reading multi-file …

If And How Many 'Races'? The Application Of Mixture Modeling To World-Wide Human Craniometric Variation, Bridget Frances Beatrice Algee-Hewitt

Doctoral Dissertations

Studies in human cranial variation are extensive and widely discussed. While skeletal biologists continue to focus on questions of biological distance and population history, group-specific knowledge is being increasingly used for human identification in medico-legal contexts. The importance of this research has been often overshadowed by both philosophic and methodological concerns. Many analyses have been constrained in their scope by the limited availability of representative samples and readily criticized for adopting statistical techniques that require user-guidance and a priori information. A multi-part project is presented here that implements model-based clustering as an alternative approach for population studies using craniometric traits. …

Geographic Disparities Associated With Stroke And Myocardial Infarction In East Tennessee, Ashley Pedigo Golden

Doctoral Dissertations

Stroke and myocardial infarction (MI) are serious conditions whose burdens vary by socio-demographic and geographic factors. Although several studies have investigated and identified disparities in burdens of these conditions at the county and state levels, little is known regarding their geographic epidemiology at the neighborhood level. Both conditions require emergency treatments and therefore timely geographic accessibility to appropriate care is critical. Investigation of disparities in geographic accessibility to stroke and MI care and the role of Emergency Medical Services (EMS) in reducing treatment delays are vital in improving health outcomes. Therefore, the objectives of this work were to: (i) classify …

Energy Functional For Nuclear Masses, Michael Giovanni Bertolli

Doctoral Dissertations

An energy functional is formulated for mass calculations of nuclei across the nuclear chart with major-shell occupations as the relevant degrees of freedom. The functional is based on Hohenberg-Kohn theory. Motivation for its form comes from both phenomenology and relevant microscopic systems, such as the three-level Lipkin Model. A global fit of the 17-parameter functional to nuclear masses yields a root- mean-square deviation of χ[chi] = 1.31 MeV, on the order of other mass models. The construction of the energy functional includes the development of a systematic method for selecting and testing possible functional terms. Nuclear radii are computed within …

Targeted Synthesis And Characterization Of Nanostructured Silicate Building Block Supports And Heterogeneous Catalysts With Tungsten(Vi) Or Zirconium(Iv) Centers, Michael Edward Peretich

Doctoral Dissertations

Catalysts play a vital role in almost every aspect of our lives and are used in the production of fuels, polymers, chemicals, foods, and pharmaceuticals. One challenge facing the heterogeneous catalysis community is the targeted synthesis of dispersed catalyst ensembles.

The Barnes research group has developed a general methodology for the synthesis of nanostructured silicate building block supports and heterogeneous catalysts. This methodology provides researchers with the ability to control the dispersion of surface functionality, the dispersion of metal cation centers, the number of linkages from the metal cation center to the support, the surface area of the support, and …

An Evaluation Of Disturbance-Induced Nutrient Changes And Climate Responses Of Loblolly Pine Xylem, Rebecca Lynne Stratton

Doctoral Dissertations

Dendrochronological techniques are currently limited to the identification of visible fire scars. However, through the development of new dendrochemical techniques, the potential exists to provide insight into a broader array of pyric ecosystems. In addition, the ability to identify historic climate-growth responses provides a better understanding of the conditions under which historic fire regimes occurred.

This study provides the groundwork for the identification of a dendrochemical nutrient fire signature in xylem and identifies the climate-radial growth responses of loblolly pine (Pinus taeda L.) on five sites in the Piedmont of South Carolina. Changes in N, P, K, Ca, Mg, …

The Beta Decay Of 79,80,81zn And Nuclear Structure Around The N=50 Shell Closure, Stephen William Padgett

Doctoral Dissertations

This dissertation reports on new information in the [beta minus] decay of the neutron-rich nucleus 81Zn, which populates states in its daughter nucleus 81Ga. This includes new [gamma]-ray transitions in the daughter nucleus, 81Ga, as well as a [beta]-delayed neutron branching ratio. This isotope was produced at the Holifield Radioactive Ion Beam Facility of Oak Ridge National Laboratory through the Isotope Separation Online technique. They are fission fragments from proton-induced fission on a uranium carbide target. These fission fragments are ionized and both mass and isotopically separated before arriving at the Low Energy Radioactive Ion Beam Spectroscopy Station (LeRIBSS). The …

Baryon Spectrum Analysis Using Dirac's Covariant Constraint Dynamics, Joshua Franklin Whitney

Doctoral Dissertations

We determine the energy spectrum of the baryons by treating each of them as a three-body system with the interacting forces coming from a set of two-body potentials that depend on both the distance between the quarks and the spin and orbital angular momentum coupling terms. We first review constraint dynamics for a relativistic two-body system in order to assemble the necessary two body framework for the three-body problem. We review the different types of covariant two-body interactions involved in constraint dynamics, including vector and scalar, and solve the problem of energy eigenstates using constraint dynamics. We use the Two …

Development And Application Of Liquid Chromatography-Tandem Mass Spectrometry Methods To The Understanding Of Metabolism And Cell-Cell Signaling In Several Biological Systems, Jessica Renee Gooding

Doctoral Dissertations

Liquid chromatography tandem mass spectrometry has become a powerful tool for investigating biological systems. Herein we describe the development of both isotope dilution mass spectrometry methods and targeted metabolomics methods for the study of metabolic and cell-cell signaling applications.

A putative yeast enzyme was characterized by discovery metabolite profiling, kinetic flux profiling, transcriptomics and structural biology. These experiments demonstrated that the enzyme shb17 was a sedoheptulose bisphosphatase that provides a thermodynamically dedicated step towards riboneogenesis, leading to the redefinition of the canonical pentose phosphate pathway.

An extension of metabolic profiling and kinetic flux profiling methods was developed for a set …

An Investigation Of Pinning Landscapes With Engineered Defects: Contact-Free Critical Current Density Measurements, John William Sinclair

Doctoral Dissertations

Pinning landscapes in modern second generation coated conductors are excellent candidates for studies of vortex pinning. The ability to produce engineered defects in thin films of high temperature superconductors allows one to investigate representative distinct pinning sites, with the objective of understanding how different pinning centers contribute, compete and evolve under varying conditions of magnetic field strength and orientation, and temperature.New contact-free methods were developed specifically to investigate this system in new ways, especially the dependence of the critical current density Jc on orientation of the magnetic field. A superconducting quantum interference device (SQUID)-based magnetometer was used to determine angular …

Development Of A Glycoconjugate Tool Set For The Assembly And Presentation Of Carbohydrate Ligands On Surfaces, Irene Esah Abia

Doctoral Dissertations

Carbohydrate and protein interactions are often essential in viral and bacterial infection, the immune response, cell differentiation and development, and the progression of tumor cell metastasis. Therefore, an understanding of carbohydrate–protein interactions at the molecular level would lead to a better insight into the biological process of living systems and assist in the development of therapeutic and diagnostic strategies. Our goal was to synthesize different mannose derivatives, immobilize them on nano-patterned surfaces and carry out binding studies with mannose-binding lectins in order to characterize carbohydrate–protein interactions.

Different derivatives of D-mannose (monosaccharide, (1→2)-linked disaccharide, (1→3)-linked disaccharide, and (1→2, 1→3)-linked trisaccharide) with …

Late Pleistocene And Holocene Hydroclimate Change In The Southeastern United States: Sedimentary, Pedogenic, And Stable Carbon Isotope Evidence In Tennessee River Floodplain Paleosols, James Joseph Kocis

Masters Theses

In order to understand hydroclimate variability of future climate change, it is important to know the timing and range of natural climate change in the past. The Southeastern United States (SE) is situated along the poleward extent of projected subtropical drying, where the expression of past hydrological balances remains unclear. The lack of high-resolution paleohydroclimate records in the SE forces climate modelers to base interpretations on better-understood regions of North America. The SE likely experienced significant changes in precipitation regimes resulting from its position at the convergence of several oceanic and continental air masses. To reconstruct precipitation variability, this study …

Nuclear Modification Factor For Production Of Open Heavy Flavor At Forward Rapidity In Cu+Cu Collisions, Archil Garishvili

Masters Theses

The PHENIX experiment at the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Laboratory with its muon spectrometer has the ability to detect muons over the range of pseudorapidity 1.1 < |eta| < 2.25. Single muon production is an important tool for studying heavy flavor production via semi-leptonic decays of open heavy flavor mesons. Because of their large mass, heavy quarks are produced in earlier stages of heavy ion collisions. Therefore, heavy flavor production can serve as an important probe of the Quark Gluon Plasma, a novel state of matter predicted to be created at RHIC. The measurement of the nuclear modification factor of open heavy flavor at forward rapidity in Cu+Cu collisions at sqrt{s_{NN}}=200 GeV is presented. Measurements of heavy flavor production in p+p collisions at sqrt{s_{NN}}=200 GeV will be also presented.

Structural And Stratigraphic Relationships Near The Southern Terminus Of The Pulaski Fault, Northeast Tennessee, Phillip Michael Derryberry

Masters Theses

The Pulaski fault is one of the master thrust faults in the Appalachian Alleghanian fold-thrust belt. Detailed geologic mapping of Cambrian and Ordovician strata in northeastern Tennessee revealed key structural and stratigraphic characteristics for distinguishing the Pulaski thrust sheet from its footwall, the Saltville thrust sheet. Unlike most thrust systems in the Valley and Ridge, the Pulaski records at least two deformation phases. Geometric and crosscutting relationships along parts of the Pulaski thrust sheet in this study area and in southwestern Virginia suggest hanging wall and possibly some footwall deformation prior to the emplacement of the thrust sheet. The initial …

Capture-Recapture Of White-Tailed Deer Using Dna Sampling From Fecal Pellet-Groups, Matthew James Goode

Masters Theses

Reliable density estimates of game and keystone species such as white-tailed deer (Odocoileus virginianus) are desirable to set proper management strategies and for evaluating those strategies over time. However, traditional methods for estimating white-tailed deer density have been inhibited by behavior, densely forested areas that can hamper observation (detection), and invalid techniques of estimating effective trapping area. We wanted to evaluate a noninvasive method of mark-recapture estimation using DNA extracted from fecal pellets as the individual marker and for gender determination, coupled with a spatial detection function to estimate density (Spatially Explicit Capture-Recapture, SECR). We collected pellet groups …

Processes Controlling The Composition Of First-Cycle Sediments Deposited In An Arid-Climate, With Implications For Provenance Reconstruction Studies, Aubrey Lynn Modi

Masters Theses

Petrologic analysis of first-cycle clastic sediments derived from a single source in an arid environment provides a means to determine how well they resemble the petrology and geochemistry of their source. The Stepladder Mountains, located in the Mojave Desert of southeastern California, represents a well-controlled location (i.e., arid environment; single, known source; short transport distance) to examine how naturally formed sediments acquire their compositions. Compositional modifications associated with sediment production were resolved through direct examination of the weathered components (regolith, grus, and sediments). Sediment compositions strongly vary by grain size, indicating that, after the source itself, hydrodynamic sorting played the …

Aeolian Simulations: A Comparison Of Numerical And Experimental Results, With Projections For Titan., Oscar Lee Mathews

Masters Theses

Aeolian processes are major determinants of geomorphology on bodies in the Solar System possessing an atmosphere-surface interface and transportable sediment, including Earth, Mars, Venus, and Titan. Substantial efforts have been made over the last few decades to understand these processes using specialized wind tunnels, field studies, and, more recently, numerical simulations. This thesis describes a model of aeolian sediment transport using computational fluid dynamics (CFD), and compares the results with those obtained in the Martian Surface Wind Tunnel (MARSWIT) testing conducted in the Planetary Aeolian Laboratory at NASA Ames Research Center. The ultimate goal of the thesis was to develop …

Effect Of Landscape Position And Dairy Manure Addition On Bioavailable Forms Of Soil Phosphorus Using Enzyme Hydrolysis, Themis Mahalia Stone

Masters Theses

Bioavailable phosphorus (P) has traditionally been measured as inorganic orthophosphate (PO₄) while organic P (P_o) has been considered of limited relevance to short-term biological consumption. However, enzymes secreted by bacteria and fungi which serve to mineralize P_o are ubiquitous in the environment and may contribute significant bioavailable P over time. In order to assess environmentally-relevant, potentially bioavailable P in soils with added dairy wastes, microcosms of identical soil series but differing management histories and landscape positions were incubated at 24 C° for three weeks. Subsamples were taken weekly from microcosms and analyzed by: 1) Mehlich-3 …

Transverse Waves In Simulated Liquid Rocket Engines With Arbitrary Headwall Injection, Charles Toufic Haddad

Masters Theses

This work introduces a closed-form analytical solution for the transverse vorticoacoustic wave in a circular cylinder with arbitrary headwall injection. This particular configuration mimics the conditions leading to the onset of traveling radial and tangential waves in a simple liquid rocket engine (LRE). Assuming a short cylindrical chamber with an injecting headwall, regular perturbations are used to linearize the problem’s mass, momentum, energy, ideal gas and isentropic relations. A Helmholtz decomposition is subsequently applied to the first-order disturbance equations, thus giving rise to a compressible, inviscid and acoustic set that is responsible for driving the unsteady motion and to an …

Cytongrasp: Cyton Alpha Controller Via Graspit! Simulation, Nicholas Wayne Overfield

Masters Theses

This thesis addresses an expansion of the control programs for the Cyton Alpha 7D 1G arm. The original control system made use of configurable software which exploited the arm’s seven degrees of freedom and kinematic redundancy to control the arm based on desired behaviors that were configured off-line. The inclusions of the GraspIt! grasp planning simulator and toolkit enables the Cyton Alpha to be used in more proactive on-line grasping problems, as well as, presenting many additional tools for on-line learning applications. In short, GraspIt! expands what is possible with the Cyton Alpha to include many machine learning tools and …

Improvements In Multi-Tool Surveying Efficiency For Archaeological Geophysics, Caitlyn Marie Williams

Masters Theses

Conventional archaeological excavation methods are, by nature, extremely invasive and result in study areas being irrevocably altered for the sake of research. For this reason, near-surface geophysical techniques have been incorporated into archaeological investigations to aid in determining the locations of buried features with minimal damage to the site. The objective of this research was to perform a geophysical survey at an archaeological site on the Akrotiri Peninsula in Cyprus to locate evidence of a Roman naval base and to develop an improved data management workflow that will improve the usefulness of geophysical data to archaeologists.

An on-site archaeologist determined …