Physical Sciences and Mathematics Commons^™

Increased Yields And Simplified Purification With A Second-Generation Cobalt Catalyst For The Oxidative Formation Of Trans-Thf Rings., Cory Palmer, Nicholas A Morra, Andrew C Stevens, Barbora Bajtos, Ben P Machin, Brian L Pagenkopf

Chemistry Publications

The synthesis of a second-generation cobalt catalyst for the formation of trans-THF products via the Mukaiyama aerobic oxidative cyclization is reported. Two procedures have been developed with the new water-soluble catalyst that give superior yields and greatly simplify purification compared to the previous catalysts.

East Canyon Reservoir Water Intake Structure Final Environmental Assessment And Finding Of No Significant Impact, United States Department Of The Interior, Bureau Of Reclamation

Environmental Assessments (UT)

The purpose of the proposed action is to authorize SWDC to build and operate facilities to deliver water to the Park City/Snyderville Basin area (Figure 1.2). The need for the proposed action is a growing demand for water in the Park City/Snyderville Basin area due to population growth and increased development of recreation facilities and vacation homes.

Residential Water Demand Under Alternative Rate Structures: Simulation Approach, David E. Rosenberg

Civil and Environmental Engineering Faculty Publications

Econometricians have long studied the effect of price on residential water demand and the impact on water use of the rate (tariff) structure in which price signals are embedded. This paper applies an existing deductive model of residential water use for the intermittent supply system in Amman, Jordan and simulates demand responses across a cross section of households over many uniform, increasing block, and linear price (quadratic charge) rate structures at historically low and significantly higher prices. Results show inelastic piped water demand responses for all rate structures at historically low prices similar to findings from a prior econometric study …

Lead Detection In Water: Using Hydroxyapatite And Atomic Absorption, Nicolas Cantarero

Department of Environmental Studies: Undergraduate Student Theses

Hydroxyapatite is a mineral that is very inexpensive, easily made, and binds well to lead. In this procedure its application will be paired with Flame Atomic Absorption Spectroscopy (Flame AA) to detect lead concentrations in water to ppb levels. While ppb concentrations of lead are too dilute to produce a response from the Flame AA by using Hydroxyapatite to concentrate lead molecules from a larger volume and dissolving the Hydroxyapatite into a smaller volume it may be able to produce a response. The method could provide an inexpensive, efficient, and accurate way to detect lead concentrations to the ppb level …

Slides: Oil Shale Water Use: Upsetting The Apple-Cart Of River Habitat, Irrigation And Existing Water Rights?, Bart Miller

Western Water Law, Policy and Management: Ripples, Currents, and New Channels for Inquiry (Martz Summer Conference, June 3-5)

Presenter: Bart Miller, Western Resource Advocates, Boulder, CO

13 slides

Slides: Integrated Policy, Planning, And Management Of Water Resources, Robert Wilkinson

Western Water Law, Policy and Management: Ripples, Currents, and New Channels for Inquiry (Martz Summer Conference, June 3-5)

Presenter: Robert Wilkinson, Ph.D., Director of the Water Policy Program, Donald Bren School of Environmental Science and Management, University of California-- Santa Barbara

60 slides

Biogeochemical Behavior Of Dissolved Arsenic And Uranium Concentrations In Public Water Supply Wells, Kevin J. Mcvey

School of Natural Resources: Dissertations, Theses, and Student Research

Public water supply (PWS) wells currently contain dissolved uranium concentrations above the federally mandated maximum contaminant level (MCL) of 30 ppb (parts per billion) and dissolved arsenic concentrations above the 10 ppb MCL. Both uranium and arsenic are known to cause various forms of cancer in humans. Variations in total uranium concentrations in PWS wells in Nebraska indicate a relationship to the duration and rate of pumping in specific wells. Although total arsenic concentrations show some variability over time in specific wells, the relationship to pumping is not as clear. Previous studies show that iron and sulfur bacteria present in …

Water Quality Variability In A Bioswell And Concrete Drainage Pipe, Southwest Lincoln, Nebraska, Jessica Shortino

Department of Environmental Studies: Undergraduate Student Theses

Abstract The goal of this project is to evaluate the effectiveness of bioswells in protecting water quality from urban runoff. The hypothesis tested in this project is that water in bioswells improves water quality. Water quality in both a bioswell and an underground concrete lined ditch, both containing ground and surface water, were tested for certain water quality parameters. These parameters consisted of: Dissolved Oxygen, pH, water temperature, weather temperature, Total Dissolved Solids, Specific Conductivity, Alkalinity, Total Dissolved Carbon, Chemical Oxygen Demand, and depth and width of the sampling site. An additional contaminant that was looked at was motor oil. …

The Occurrence Of Illicit And Therapeutic Pharmaceuticals In Wastewater Effluent And Surface Waters In Nebraska, Shannon L. Bartelt-Hunt, Daniel D. Snow, Teyona Damon, Johnette Shockley, Kyle Hoagland

Nebraska Water Center: Faculty Publications

Passive samplers were used to develop semi-quantitative estimates of pharmaceutical concentrations in receiving waters influenced by wastewater effluent. The occurrence and estimated concentration of twenty illicit and therapeutic pharmaceuticals and metabolites in surface waters influenced by wastewater treatment plant (WWTP) discharge and in wastewater effluents in Nebraska were determined using Polar Organic Chemical Integrative Samplers (POCIS). Samplers were installed in rivers upstream and downstream of treated WWTP discharge at four sites and in a discharge canal at a fifth location. Based on differences in estimated concentrations determined from pharmaceuticals recovered from POCIS, WWTP effluent was found to be a significant …

Fy 2009 Umass Amherst Water & Steam Data By Building, Ezra Small

Campus Data

Each year, UMass Amherst Utilities publishes this spreadsheet which has the monthly and annual building water and steam consumption of each metered building on campus.

Just Add Water: Colonisation, Water Governance, And The Australian Inland, Leah Maree Gibbs

Faculty of Science - Papers (Archive)

Water has played a key role in the development of the Australian inland and the nation. For European colonists, the dry and variable landscape challenged ideas about nature imported from northern temperate regions. I argue first, that colonists brought with them ideas for ordering nature and tools for transforming landscapes that led to inappropriate and destructive water management and the silencing of local voices and knowledge systems. Secondly, colonial patterns of ordering and transforming landscapes are ongoing, but new ways of governing water, which challenge colonialism, are emerging. In the first section of the paper I discuss colonial relationships with …

Correction To Variations Of Ice Bed Coupling Beneath And Beyond Ice Streams: The Force Balance, Terence J. Hughes

Earth Science Faculty Scholarship

A geometrical force balance that links stresses to ice bed coupling along a flow band of an ice sheet was developed in 1988 for longitudinal tension in ice streams and published 4 years later. It remains a work in progress. Now gravitational forces balanced by forces producing tensile, compressive, basal shear, and side shear stresses are all linked to ice bed coupling by the floating fraction phi of ice that produces the concave surface of ice streams. These lead inexorably to a simple formula showing how phi varies along these flow bands where surface and bed topography are known: phi …

A Bio-Inspired Molecular Catalyst That Selectively Catalyzes Water Oxidation In Seawater, Without Significant Chlorine Formation, Robin Brimblecombe, G. Charles Dismukes, Gerhard F. Swiegers, Leone Spiccia

Faculty of Science - Papers (Archive)

Most transport fuels are derived from fossil fuels, generate greenhouse gases, and consume significant amounts of water in the extraction, purification, and/or burning processes. The generation of hydrogen using solar energy to split water, ideally from sea water or other non-potable sources, could potentially provide an unlimited, clean fuel for the future. Solar, electrochemical water splitting typically combines a photoanode at which water oxidation occurs, with a cathode for proton reduction to hydrogen. In recent work we have found that a bioinspired tetra-manganese cluster catalyzes water oxidation at relatively low overpotentials (0.38 V) when doped into a Nafion proton conduction …

Molecular Water Oxidation Catalysts For Photoelectrochemical Cells, Robin Brimblecombe, Charles Dismukes, Gerhard F. Swiegers, Leone Spiccia

Faculty of Science - Papers (Archive)

Photoelectrochemical cells that efficiently split water into oxygen and hydrogen, "the fuel of the future", need to combine robust water oxidation catalysts at the anode (2H(2)O -> O-2 + 4H(+) + 4e(-)) with hydrogen reduction catalysts at the cathode (2H(+) + 2e(-) -> H-2). Both sets of catalysts will, ideally, operate at low overpotentials and employ light-driven or light-assisted processes. In this Perspective article, we focus on significant efforts to develop solid state materials and molecular coordination complexes as catalyst for water oxidation. We briefly review the field with emphasis on the various molecular catalysts that have been developed and …

Spatial Ecology Of Hatchling Water Pythons (Liasis Fuscus) In Tropical Australia, Richard Shine, Thomas R. Madsen, Ligia Pizzatto, Gregory P. Brown

Faculty of Science - Papers (Archive)

Young snakes are rarely seen in the field and little is known about their habits. mostly because they are too small for radio-telemetry (the primary method for Studying snake spatial ecology). However, the offspring or some larger species can be fitted with transmitters and we investigated the spatial ecology and habitat use of ten hatchling water pythons (Liasis fuscus: Pythonidae) in the floodplain of the Adelaide River, tropical Australia. Patterns of habitat use in the late wet season and during the dry season were similar to those of adults tracked in the same vicinity in an earlier study. Soon after …

A Bio-Inspired Molecular Water Oxidation Catalyst For Renewable Hydrogen Generation: An Examination Of Salt Effects, Robin Brimblecombe, Miriam Rotstein, Annette Koo, G Charles Dismukes, Gerhard F. Swiegers, Leone Spiccia

Faculty of Science - Papers (Archive)

Most transport fuels are derived from fossil fuels, generate greenhouse gases, and consume significant amounts of water in the extraction, purification, and/or burning processes. The generation of hydrogen using solar energy to split water, ideally from abundant water sources such as sea water or other non-potable sources, could potentially provide an unlimited, clean fuel for the future. Solar, electrochemical water splitting typically combines a photoanode at which water oxidation occurs, with a cathode for proton reduction to hydrogen. In recent work, we have found that a bioinspired tetra-manganese cluster catalyzes water oxidation at relatively low overpotentials (0.38 V) when doped …

Development And Application Of A System For The Analysis Of Atmospheric, Water And Sediment Nitrogen And Carbon, Ann Stavert, Stephen R. Wilson, Dianne F. Jolley

Faculty of Science - Papers (Archive)

Eutrophication and climate change, key environmental concerns, are both linked to the carbon and nitrogen cycles hence the improved understanding of these cycles is essential. Currently, there is no system that simultaneously measures the fluxes of the three key gas phase products of nitrogen and carbon cycling (CO2, CH4 and N2O) in submerged ecosystems with hourly time resolution. A “Lake-in-a-box” (mesocosm) was developed in the laboratory which allowed the monitoring of key components of the carbon and nitrogen cycles within the air, water and sediments. The approach is automated, simple and time efficient and novel in its ability to examine …

Ordway Weather And Water Data 2009, Macalester College

Ordway Weather Data

Contains daily readings for the year indicated. The values include: PAR umol/s/m2, avg wind dir degree, avg windspeed mph, Avg Max Windspeed mph, Avg airtemp C, Avg RH %, Avg BP mmHg, Avg DailyRain in, Avg Rain Duration sec, Avg RainIntensity in/h, Avg Water Temp F, Avg sp cond mS/cm, avg pH, Avg Turb NTU+, Avg ODOSat %, Avg ODO mg/L, Water station PAR umol/s/m2, Avg Water Level m. File format: CSV.