Physical Sciences and Mathematics Commons^™

Unsaturated Flow And Transport Of 90Sr, Co(Ii)Edta, And U(Vi) In Undisturbed Cores From The Hanford Formation, Hanford, Wa, Mary Fairfax Nichols-Pace

Doctoral Dissertations

At the U.S. Department of Energy’s Hanford Site in Richland, WA nuclear processing wastes, such as Sr-90, organic chelating agents such as EDTA, Co-60, and U(VI) have been detected in the vadose zone beneath the underground storage tanks. There is concern that waste released to the vadose zone could reach the groundwater and eventually flow into the Columbia River. The goal of this paper is to provide an improved understanding of coupled hydrologic and geochemical mechanisms that influence contaminant transport in the Handford vadose zone. Disturbed sediment and undisturbed sediment cores were collected from the Environmental Restoration Disposal Facility (ERDF) …

Development Of A Dilatant Damage Zone Along A Thrust Relay In A Low-Porosity Quartz Arenite, Jennie E. Cook

Masters Theses

A damage zone developed along a backthrust fault system in well-cemented quartz arenite of the Tuscarora Sandstone in the Alleghanian foreland thrust system consists of a network of NW-dipping thrusts that are linked by multiple higher-order faults and bound a zone of intense extensional fractures and breccias. The damage zone is unusual in that it preserves porous brittle fabrics despite formation at >5km depth. The damage zone developed at an extensional step-over between two independent, laterally propagating backthrusts. Continued displacement resulted in breaching of the relay and formation of faultbounded horses, and favored the formation of extensional fractures. The presence …

Detection Of Enteric Viruses In East Tennessee Public Ground Water Systems, Trisha Baldwin Johnson

Masters Theses

A two-part study was conducted by University of Tennessee-Knoxville, the U.S. Geological Survey, and the U.S. Environmental Protection Agency-National Exposure Research Laboratory to (1) develop, validate, and test a real-time reverse transcription-polymerase chain reaction (real-time RT-PCR) assay for enteroviruses in ground water samples and to (2) perform the first survey of enteric viral occurrence in the karst aquifers of East Tennessee. Karst aquifers are expected to have a high susceptibility to viral contamination because of the rapid flow (100’s of m/day) and frequent occurrence of fecal indicator bacteria typically observed in these systems.

Real-time RT-PCR primers and probes specific for …

Development Of A Dilatant Damage Zone Along A Thrust Relay In A Low-Porosity Quartz Arenite, Jennie E. Cook

Masters Theses

A damage zone developed along a backthrust fault system in well-cemented quartz arenite of theTuscarora Sandstone in the Alleghanian foreland thrust system consists of a network of NW-dipping thrusts that are linked by multiple higher-order faults and bound a zone of intense extensional fractures and breccias. The damage zone is unusual in that it preserves porous brittle fabrics despite formation at >5km depth. The damage zone developed at an extensional step-over between two independent, laterally propagating backthrusts. Continued displacement resulted in breaching of the relay and formation of faultbounded horses, and favored the formation of extensional fractures. The presence of …

Deciphering Eustatic And Tectonic Influences During Parasequence Development In The Mesoprotozoic Helena/Wallace Formation, Belt Supergroup, Montana And Idaho, Stephen Alan Welch

Masters Theses

The stratigraphic architecture of sedimentary basins results from a combination of changes in relative sea-level and tectonism, and resulting changes in sediment supply. The Helena/Wallace formations, Mesoproterozoic Belt Supergroup, Montana and Idaho, consists of >500 meters of stacked meter-scale cycles (parasequences) that record in situ carbonate deposition as well as siliciclastic deposition from both the Laurentian craton and an unknown (tectonically active?) western source. In this study, statistical methods and 2-D forward modeling are combined with geochemical provenance analysis to examine parasequence stacking patterns and decipher the relative eustatic and tectonic controls on sequence development.

Helena/Wallace parasequences are typically composed …

Stratigraphic And Structural Relationships Of The Ocoee Supergroup, Southern Appalachians: Implications For Neoproterzoic Rift Basin Architecture And Paleozoic Collisional Orogenesis, James Ryan Thigpen

Masters Theses

The late Proterozoic-Early Cambrian Ocoee Supergroup (OSG)is the dominant lithostratigraphic sequence of the western Blue Ridge (WBR) province in southeast Tennessee, southwest North Carolina, and northern Georgia. The OSG is divided into the basal Snowbird Group (SG) that nonconformably overlies Grenvillian basement, the thick Great Smoky Group (GSG) that is usually in fault contact with the Snowbird Group, and the Walden Creek Group (WCG) that directly underlies the Cambrian Chilhowee Group and conformably overlies both the Snowbird and Great Smoky Groups. Traditional interpretations suggest that the OSG was deposited during late Neoproterozoic-Early Cambrian rifting along the southeast Laurentian margin, initially …

Identification Of Terrestrial Alkalic Rocks Using Thermal Emission Spectroscopy: Applications To Martian Remote Sensing, Tasha Laurrelle Dunn

Masters Theses

We present a detailed study examining the use of laboratory thermal emission spectra (5-25 μm at 2 cm^-1 spectral sampling) for identification and classification of alkalic volcanic rocks. Modal mineralogies and derived bulk rock chemistries of a suite of terrestrial alkali basalts, trachyandesites, trachytes, and rhyolites were determined using linear spectral deconvolution. Model-derived mineral modes were compared to modes measured using an electron microprobe mapping technique to access the accuracy of linear deconvolution in determining mineral abundances. Standard deviations of 1σ of absolute differences between measured and modeled mineral abundances range from 0.68 to 15.02 vol %, with …

Seasonal Forage Availability And Diet Of Reintroduced Elk In The Cumberland Mountains, Tennessee, Jason Lee Lupardus

Masters Theses

The Tennessee Wildlife Resources Agency (TWRA) reintroduced elk (Cervus elaphus manitobensis) into the Cumberland Mountains, Tennessee over a 3-year period beginning in December 2000. We radio-collared 160 elk and monitored them by aerial telemetry from February 2001 to June 2003. Locations (n = 1450) were used in a geographic information system (GIS) to develop a core herd home range (789-ha sampling area) to assess elk seasonal forage use and availability. We monitored diet and resource availability from November 2003 to October 2004 by vegetation sampling and microhistological analysis of feces. Tall fescue (Festuca arundinacea; 35.1%) dominated …

Virus Transport During Transient Unsaturated And Steady-State Saturated Flow Conditions In Memphis Aquifer Sand, Andrew Boruff Kenst

Masters Theses

The overall goal of this research was to determine the effect of transient unsaturated flow conditions on the transport of a virus in aquifer material. It was hypothesized that viruses would be transported at the same rate and over the same distance as the migration of the wetting front and that virus retention during transient unsaturated flow would be similar to that during steady-state saturated flow. Virus transport during transient unsaturated horizontal flow was experimentally compared with its behavior under steady-state saturated vertical flow. In the transient flow experiment, virus (ΦX174) suspension was introduced into an initially air-dry repacked Memphis …

Structural And Stratigraphic Investigations Of The Bays Mountain Synclinorium, Parrottsville And A Portion Of Cedar Creek 7.5-Minute Quadrangles, East Tennessee, Neil E. Whitmer

Masters Theses

The southern Valley and Ridge foreland fold-thrust belt is comprised of a wedge of Lower Cambrian through Pennsylvanian sedimentary rocks that were folded and faulted during the late stages of the Alleghanian orogeny. Within one of the eastern thrust sheets lies the Bays Mountain synclinorium. Rocks as young as Middle Ordovician are preserved in the core of the synclinorium and record the evolution of a Taconian (Blountian) Sevier tectonic basin.

The Parrottsville and Cedar Creek 7.5-minute quadrangles are located on the southeastern flank of the Bays Mountain synclinorium of East Tennessee and contain rocks belonging to the Conasauga, Knox, and …

C3/C4 Variations In High Salt Marsh Sediments: An Application Of Compound Specific Isotopic Analysis Of Lipid Biomarkers To Late Holocene Paleoclimatic Research, Benjamin Ryan Tanner

Doctoral Dissertations

Chapter 1

Bulk carbon isotopes were previously used as a tool to differentiate between C3 and C4 plant communities in ancient salt-marsh deposits (Chmura and Aharon 1995). However, the bulk carbon values reflect organic matter contributions not only from salt-marsh plants, but also from algal bacterial inputs, as well as allochtonous terrestrial organic matter. The introduction of gas chromatography-isotope ratio mass spectrometery (GC-IRMS) allows for the separation of algal vs. higher plant contributions to the sediment pool. In the present study, this technique is applied to a core and modern plant samples collected from two Maine salt-marshes. We sampled 10 …

A Tree-Ring Oxygen Isotope Record Of Tropical Cyclone Activity, Moisture Stress, And Long-Term Climate Oscillations For The Southeastern U.S., Dana Lynette Miller

Doctoral Dissertations

Geological proxies are needed to extend the record of hurricane occurrence beyond historical observations. Tree rings preserve uniquely high resolution and precisely dated records of past environmental conditions. Oxygen isotopic compositions of alpha cellulose in seasonally-resolved components (earlywood (EW) and latewood (LW)) of tree rings of southeastern coastal plain pines predominantly reflect precipitation source and/or temperature providing a snapshot of climate activity for the region.

Tropical cyclones produce large amounts of precipitation with distinctly lower oxygen isotope ratios than typical low-latitude thunderstorms. Evidence of isotopically depleted precipitation may persist in surface and soil waters for several weeks after a large …

Geochemical Investigations Of Ordinary Chondrites, Shergottites, And Hawaiian Basalts, Valerie Slater Reynolds

Doctoral Dissertations

Part I: Quantifying peak temperatures achieved during metamorphism is critical for understanding the thermal histories of ordinary chondrite parent asteroids. I performed two-pyroxene geothermometry, using QUILF95, on the same Type 6 chondrites for which peak temperatures were estimated using the plagioclase geothermometer. Pyroxenes record a narrow, overlapping range of temperatures in H6 (865-926°C), L6 (812-934°C), and LL6 (874-945°C) chondrites. Lower plagioclase temperature estimates may not reflect peak metamorphic temperatures because chondrule glass probably recrystallized to plagioclase prior to reaching the metamorphic peak. The average temperature for H, L, and LL chondrites (~900°C) is at least 50°C lower than peak temperatures …

Analysis Of Martian Parental Melts And Thermal Infrared Studies Of Putative Paleolake Basins On Mars, Karen Renée Stockstill

Doctoral Dissertations

Both martian meteorites and remote sensing data allow us to study the geologic history of Mars. Martian meteorites can reveal information regarding partial melting of the Mars mantle and the surface processes that affected the meteorite following eruption (weathering, impact ejection, etc.). Remote sensing data can be used to investigate the local-, regional- or global-scale surface of Mars in terms of composition and geomorphology. A well-rounded approach is necessary to address fundamental questions regarding the geologic history of Mars.

We studied melt inclusions in augite of the martian meteorite Nakhla to better understand the magma that produced this rock. This …

The Middle Ordovician Tellico-Sevier Syncline: A Stratigraphic, Structural And Paleoseimic Investigation., Stephen Christopher Whisner

Doctoral Dissertations

Analyses of remote-sensing satellite data, aerial photography, radar images, and digital elevation models, and detailed (1:24,000-scale) geologic mapping of bedrock and surficial deposits were conducted in a portion of the southeastern Tennessee. This area contains the southern portion of the Tellico-Sevier Alleghanian syncline and the highest concentration of modern earthquakes as well as two major rivers with unconsolidated floodplain and terrace deposits that would be most susceptible to disruption by earthquakes. Cambrian to Mississippian age rocks occurs in the syncline. The majority of detailed mapping was conducted in Middle Ordovician Chickamauga Group rocks.

Earthquakes occur in the East Tennessee seismic …

Experimental Investigation Of The Breakdown Of Dolomite And Isotope Transport In Rock Cores At 100 Mpa, 650–750 °C, Michael Thomas Deangelis

Masters Theses

The kinetics of the breakdown reaction dolomite = periclase + calcite + CO2 were investigated using cores of dolomitic marble. Two samples of Reed Dolomite from southwestern Nevada were cut into cylinders approximately 4×6 mm in size.

The cores were sealed in gold capsules with isotopically enriched water (H218O or HD 18O0.5 16 O0.5). The samples were heated in a cold-seal hydrothermal apparatus to 650–750 °C at 100 MPa for durations ranging from 2–59 days. The cores were then sectioned and examined by EMP, XRD, and SIMS techniques. All experiments show some amount of reaction regardless of duration or temperature. …

Distribution And Transportation Of Coal Tar Contaminants In The Chattanooga Creek Floodplain, Dalphania Syreeta Dickerson

Masters Theses

In Chattanooga, Tennessee, tens of thousands of tons of coal tar were disposed of in Chattanooga Creek during operations of the Chattanooga Coke Plant (1918-1987). Coal tar is composed of thousands of organic compounds, which span a wide range of molecular weight. Many of these compounds are polycyclic aromatic hydrocarbons (PAHs) and are known carcinogens. Chattanooga Creek is an urban creek, which runs through the southern part of the city of Chattanooga and is surrounded by industrial development, residential neighborhoods, parks, and schools. Due to the hazardous nature of coal tar and coal tar constituents, portions of the creek and …

Determination Of An Appropriate Geometrical Model For Soil Aggregates Based Upon Specific Surface Area Scaling, Jeremy E. Lawson

Masters Theses

The appropriate geometrical form of soil aggregates is important for modeling soil hydraulic and mechanical properties. To investigate this topic, specific surface are (SSA) measurements were conducted on soul aggregates obtained from two sites. Differing long-term agricultural practices at the two sites resulted in nine distinct soil treatments. Each of the soil treatments was fractionated into five size classes and the SSA of each class was measured using the nitrogen adsorption technique. The measured data were then compared to simulated SSA results. To accomplish this, six geometrical models were developed, using either Euclidean or fractal geometry, to predict the SSA …

Utk Geography Newsletter 5 (2005), Department Of Geography

UTK Geography Newsletter

No abstract provided.

Limnología De Las Lagunas Glaciales En El Páramo Del Chirripó, Costa Rica. (Limnology Of Glacial Lakes In The Chirripó Páramo Of Costa Rica.), Sally P Horn, Kenneth H. Orvis, Kurt A. Haberyan

Geography Publications and Other Works

More than 30 lakes of glacial origin exist within the Chirripó páramo in the Cordillera de Talamanca of Costa Rica. This chapter describes the geomorphic setting and physical and chemical limnology of 19 lakes located between 3450-3570 m elevation in the upper basins of five glaciated valleys. All lakes are clear, dilute, and apparently polymictic. Water chemistry data from 1998, 2000, and 2001 are similar from lake to lake and year to year, and are consistent with sparse prior measurements between 1966 and 1991. However, the lake water temperatures we have measured are much higher than those reported by earlier …

Registros De Sedimentos Lacustres De La Vegetación Del Holoceno Y Historia Del Fuego En El Páramo De Costa Rica. (Lake-Sediment Records Of Holocene Vegetation And Fire History In The Costa Rican Páramos), Sally P Horn, Brandon L. League

Geography Publications and Other Works

We examined pollen, pteridophyte (ferns and fern-allies) spores, and charcoal in a 5.6 m long sediment core from Lago de las Morrenas 1, and charcoal in a 1.1 m long sediment core from Lago Chirripó, to reconstruct postglacial vegetation and fire history in the Chirripó páramo. Lago de las Morrenas 1, the largest lake in the Valle de las Morrenas of Chirripó National Park, is presently surrounded by treeless páramo vegetation and has apparently been so since deglaciation approximately 10,000 radiocarbon years ago. Pollen spectra suggest no pronounced changes in vegetation since ice retreat. Pollen percentages for Gramineae and other …