Physical Sciences and Mathematics Commons^™

A Geologic Record Of Methane Consumption Associated With Methane Gas Hydrates At Blake Ridge Region (Continental Rise, Offshore Southeastern United States), Walter S. Borowski, Kathryn G. Takacs, Matthew K. Thompson

EKU Faculty and Staff Scholarship

Geochemical signals locked within sedimentary rocks are a record of earth processes. Sulfide minerals (elemental sulfur, iron monosulfides, and pyrite) are formed within marine sediments by several different geochemical processes mediated by microbes. Investigating the concentration and sulfur isotopic composition (d³⁴S) of sulfide minerals gives clues about the relative importance of these competing geochemical processes.

Marine sediments of the Blake Ridge(offshore South Carolina and Georgia) contain sulfide minerals that point to anaerobic methane oxidation (AMO) as an important diagenetic process both today and in the recent geological past (Miocene). At the present-day methane-sulfate interface, upward-diffusing methane is consumed …

Sulfide Mineralization In Deep-Water Marine Sediments Related To Methane Transport, Methane Consumption, And Methane Gas Hydrates, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Patterns of sulfide sulfur concentration and sulfur isotopic composition (d³⁴ S) are perhaps related to upward methane transport, especially in sediments underlain by methane gas hydrate deposits. Increased methane delivery augments the effect of anaerobic methane oxidation (AMO) occurring at the sulfate-methane interface (SMI). Sulfate and methane co-consumption results in production of dissolved sulfide at the interface that is eventually sequestered within sulfide minerals (elemental sulfur, iron monosulfide, pyrite).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits (offshore southeastern United States) by extracting total sedimentary sulfide using chromium reduction. We use …

Relative Concentration Of Solid-Phase Sulfide Species In Marine Sediments Overlying Gas Hydrate Deposits: Recognition Of The Role Of Anaerobic Methane Oxidation In Authigenic Sulfide Formation, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Sulfide mineralization in marine sediments occurs when dissolved sulfide, produced by sulfate reduction processes, combines with dissolved iron to form iron sulfide minerals. Sulfide can be produced by oxidation of organic matter or by anaerobic methane oxidation (AMO), which involves the co-consumption of sulfate and methane. The latter process seems especially important within gas hydrate terrains like that of theBlakeRidge(offshore southeasternUnited States), where appreciable amounts of methane diffuse upward to the base of the sulfate reduction zone, or sulfate-methane interface (SMI).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits by sequentially extracting …

Sulfide Mineralization Within Modern, Deep-Sea Marine Sediments And Oxygenation Of The Early Earth, Matthew K. Thompson, Walter S. Borowski

EKU Faculty and Staff Scholarship

The Earth’s atmosphere and oceans have not always been oxygenated. The exact pathway and timing of the oxygenation of the Earth’s early oceans is poorly constrained, although it appears that oxygenation was essentially complete by the beginning of the Cambrian (545 million years ago). Indeed, the appearance and diversification of the first animals may have been dependent on threshold levels of oxygen. Eventually we intend to use the sulfur isotopic composition of sulfide minerals (iron monosulfides and pyrite) present in sedimentary rocks to reconstruct the oxygenation of Proterozoic oceans, but first must strive to understand sulfide mineral formation in the …

Variations In Mineralogy, Temperature, And Oxygen Fugacity In A Suite Of Strongly Peralkaline Lavas And Tuffs, Pantelleria, Italy., John C. White, Minghua Ren, Don Parker

EKU Faculty and Staff Scholarship

Eight samples of pantelleritic lava and tuff and a lithic inclusion of trachyte from Pantelleria, Italy, have been thoroughly analyzed with an electron microprobe. These samples reveal five different mineral assemblages if classified by the presence of fayalite, aenigmatite, ilmenite, and magnetite: (1) augite + fayalite + ilmenite + magnetite, (2) augite + fayalite + ilmenite, (3) hedenbergite or sodian hedenbergite + fayalite + ilmenite + aenigmatite + quartz, (4) sodian hedenbergite or aegirine-augite + ilmenite + aenigmatite + quartz ± ferrorichterite, and (5) aegirine-augite + aenigmatite + quartz. Alkali feldspar (Or35–37) is present as the dominant phyric phase in …