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Articles 1 - 16 of 16
Full-Text Articles in Physical Sciences and Mathematics
Pyridoxamine Traps Intermediates In Lipid Peroxidation Reactions In Vivo: Evidence On The Role Of Lipids In Chemical Modification Of Protein And Development Of Diabetic Complications, Thomas O. Metz, Nathan L. Alderson, Mark E. Chachich, Suzanne R. Thorpe, John W. Baynes
Pyridoxamine Traps Intermediates In Lipid Peroxidation Reactions In Vivo: Evidence On The Role Of Lipids In Chemical Modification Of Protein And Development Of Diabetic Complications, Thomas O. Metz, Nathan L. Alderson, Mark E. Chachich, Suzanne R. Thorpe, John W. Baynes
Faculty Publications
Maillard or browning reactions between reducing sugars and protein lead to formation of advanced glycation end products (AGEs) and are thought to contribute to the pathogenesis of diabetic complications. AGE inhibitors such as aminoguanidine and pyridoxamine (PM) inhibit both the formation of AGEs and development of complications in animal models of diabetes. PM also inhibits the chemical modification of protein by advanced lipoxidation end products (ALEs) during lipid peroxidation reactions in vitro. We show here that several PM adducts, formed in incubations of PM with linoleate and arachidonate in vitro, are also excreted in the urine of PM-treated animals. The …
Bis[Μ-1,2-Bis(2-Pyridyl)Ethyne-K2N:N']Bis[Aquadinitratocadmium(Ii)], Badruz Zaman Md., Matthew J. Davis, Mark D. Smith, Hans Conrad Zur Loye
Bis[Μ-1,2-Bis(2-Pyridyl)Ethyne-K2N:N']Bis[Aquadinitratocadmium(Ii)], Badruz Zaman Md., Matthew J. Davis, Mark D. Smith, Hans Conrad Zur Loye
Faculty Publications
Two twisted 1,2-bis(2-pyridyl)ethyne ligands bridge two Cd2+ centers in the C2-symmetric title complex, [Cd2(NO3)4(-C12H8N2)2(H2O)2]. The bridging ligands arch across one another creating a `zigzag loop' molecular geometry. Two nitrate ions and a water molecule complete the irregular seven-coordinate Cd-atom environment. The dihedral angles between the equivalent pyridyl ring planes of the two independent ligands are 67.2 (1)°. Owater-HOnitrate hydrogen bonding creates two-dimensional layers parallel to the ab plane.
Formula: [Cd2(NO3)4(C …
Sr3Mgpto6, Mark D. Smith, Hans Conrad Zur Loye
Sr3Mgpto6, Mark D. Smith, Hans Conrad Zur Loye
Faculty Publications
Single crystals of the mixed alkaline earth platinate, tristrontium magnesium platinum hexaoxide, Sr3MgPtO6, were grown from a KOH flux at 1273 K. The compound adopts the rhombohedral K4CdCl6 structure type, featuring chains of face-shared, distorted MgO6 trigonal prisms (Mg site symmetry 32) and PtO6 octahedra (Pt site symmetry ) surrounded by columns of Sr2+ ions (Sr site symmetry 2).
Semiclassical Dynamics With Quantum Trajectories: Formulation And Comparison With The Semiclassical Initial Value Representation Propagator, Sophya Garashchuk, Vitaly A. Rassolov
Semiclassical Dynamics With Quantum Trajectories: Formulation And Comparison With The Semiclassical Initial Value Representation Propagator, Sophya Garashchuk, Vitaly A. Rassolov
Faculty Publications
We present a time-dependent semiclassical method based on quantum trajectories. Quantum-mechanical effects are described via the quantum potential computed from the wave function density approximated as a linear combination of Gaussian fitting functions. The number of the fitting functions determines the accuracy of the approximate quantum potential (AQP). One Gaussian fit reproduces time-evolution of a Gaussian wave packet in a parabolic potential. The limit of the large number of fitting Gaussians and trajectories gives the full quantum-mechanical result. The method is systematically improvable from classical to fully quantum. The fitting procedure is implemented as a gradient minimization. We also compare …
Histological Effect Of Ascocotyle Tenuicollis (Digenea: Heterophyidae) Metacercarial Infection On The Heart Of Fundulus Heteroclitus (Teleostei: Cyprinodontidae), Toni Hicks, Edna Steele
Histological Effect Of Ascocotyle Tenuicollis (Digenea: Heterophyidae) Metacercarial Infection On The Heart Of Fundulus Heteroclitus (Teleostei: Cyprinodontidae), Toni Hicks, Edna Steele
Journal of the South Carolina Academy of Science
No abstract provided.
Scas Officers And Council Members 2003 - 2004
Scas Officers And Council Members 2003 - 2004
Journal of the South Carolina Academy of Science
No abstract provided.
Some Notes On Multiplicative Congruential Random Number Generators With Mersenne Prime Modulus 261-1., James Harris
Some Notes On Multiplicative Congruential Random Number Generators With Mersenne Prime Modulus 261-1., James Harris
Journal of the South Carolina Academy of Science
No abstract provided.
President's Message
Journal of the South Carolina Academy of Science
No abstract provided.
Par Mediation Of Thrombin-Induced Effects On Motoneurons, Nadim Salman, Drew Watkins, Kate Hamel, Lakisha Gadsden, Sarah Funderburk, Victoria Turgeon
Par Mediation Of Thrombin-Induced Effects On Motoneurons, Nadim Salman, Drew Watkins, Kate Hamel, Lakisha Gadsden, Sarah Funderburk, Victoria Turgeon
Journal of the South Carolina Academy of Science
No abstract provided.
2002 & 2003 Annual Meeting Extended Abstracts
2002 & 2003 Annual Meeting Extended Abstracts
Journal of the South Carolina Academy of Science
No abstract provided.
Embryogenesis In The Japanese Medaka, Oryzias Latipes, Laura Harris Harris, Lisa Sims, Roxann Stachiw
Embryogenesis In The Japanese Medaka, Oryzias Latipes, Laura Harris Harris, Lisa Sims, Roxann Stachiw
Journal of the South Carolina Academy of Science
No abstract provided.
Critical Thinking And Biology Instruction., David J. Stroup, John L. Frola
Critical Thinking And Biology Instruction., David J. Stroup, John L. Frola
Journal of the South Carolina Academy of Science
No abstract provided.
South Carolina Statewide Science Safety Project., Linda Sinclair, Jack Gerlovich, Rahul A. Parsa
South Carolina Statewide Science Safety Project., Linda Sinclair, Jack Gerlovich, Rahul A. Parsa
Journal of the South Carolina Academy of Science
No abstract provided.
Table Of Contents
Journal of the South Carolina Academy of Science
No abstract provided.
Maternal And Sibling Influences On Seed Germination Of Aegilops Triuncialis Erin, Erin Scott, Andrew R. Dyer
Maternal And Sibling Influences On Seed Germination Of Aegilops Triuncialis Erin, Erin Scott, Andrew R. Dyer
Journal of the South Carolina Academy of Science
No abstract provided.
Nitroalkane Anomaly: Computational Study With Cluster And Continuum Modeling, H. Yamataka, Salai Cheettu Ammal
Nitroalkane Anomaly: Computational Study With Cluster And Continuum Modeling, H. Yamataka, Salai Cheettu Ammal
Faculty Publications
The origin of anomalous relation between rates and equilibria for the proton-transfer reactions of nitroalkanes, known as nitroalkane anomaly, was investigated by theoretical calculations with a cluster model, in which three water molecules are explicitly considered in the system, as well as the PCM solvent continuum model. For the CH3NO2/CH3CH2NO2 system, B3LYP and MP2 computations reproduced the anomaly, and the imbalance in the charge distribution at the transition state (TS) was observed. In contrast, although the TS imbalance was detected for the substituted phenylnitromethane system, the Brønsted plots did not show any anomaly. The experimentally observed abnormally large Brønsted coefficient …