Physical Sciences and Mathematics Commons^™

Measuring Surface Chemical Properties Of Soil Using Flow Calorimetry, R. D. Rhue, Chip Appel, Nadine Kabengi

Earth and Soil Sciences

Flow calorimetry, which is ideally suited for measuring reactions occurring at the liquid/solid interface, has been used to study the surface chemistry of many types of solids, but little use of it has been made in the study of surface reactions of soils. The purpose of this study was to demonstrate the application of flow calorimetry to the study of two fundamental soil chemical processes, namely cation exchange and phosphate sorption. Surface horizon samples of a Typic Acrorthox and a Typic Tropohumult from Puerto Rico, a strong acid cation exchange resin (Dowex 50W-8), and an amorphous Al(OH)₃ were used. …

Heats Of K/Ca And K/Pb Exchange In Two Tropical Soils As Measured By Flow Calorimetry, Chip Appel, Dean Rhue, Lena Ma, Bill Reve

Earth and Soil Sciences

Flow calorimetry can provide useful information about surface chemical reactions in soils that cannot be obtained readily by other methods. When flow calorimetry is conducted over a range of surface coverages, different sorption heats can be calculated to yield information about how binding energies vary with coverage, i.e., surface heterogeneity. The purpose of this study was to determine heats of exchange for K/Ca and K/Pb systems using flow calorimetry and to evaluate the degree of surface heterogeneity with respect to cation exchange. Surface horizon samples from a Typic Acrorthox and Typic Tropohumult from Puerto Rico were used. Lead was adsorbed …

Selectivities Of K/Ca And K/Pb Exchange In Two Tropical Soils, C. S. Appel, L. Q. Ma, R. D. Rhue, W. Reve

Earth and Soil Sciences

Measurement of cation selectivity in soils provides important information about the affinity and binding strength of a particular cation on soil surfaces. Gaines-Thomas (KGT) selectivity coefficients were determined for a variety of K/Ca and K/Pb ratios on an Oxisol and Ultisol soil from Puerto Rico. The calculated KGT values indicated a preference for K+ over Ca2+ or Pb2+. The selectivity for Pb2+ was significantly greater than that for Ca2+ due to the larger hydrated charge density of Pb2+ relative to that of Ca2+. The patterns of selectivity were independent of metal type. The selectivity of the Oxisol for Ca2+ or …

Concentration, Ph, And Surface Charge Effects On Cadmium And Lead Sorption In Three Tropical Soils, Chip Appel, Lena Ma

Earth and Soil Sciences

Reactions of heavy metals with soil are important in determining metal fates in the environment. Sorption characteristics of two heavy metals, Cd and Pb, in three tropical soils (Mollisol, Oxisol, and Ultisol) from Puerto Rico were assessed at varying metal concentrations (0 to 1.2 mM) and pH values (approximately 2 to 7). All soils sorbed more Pb than Cd. Sorption maxima were obtained for each metal for the Oxisol and Ultisol soils, but not the Mollisol. Sorption appeared to depend more on soil mineralogy than organic matter content. Sorption isotherms were linear within the sorption envelope with similar slopes for …

Importance Of Soil Texture To Vineyard Management, Thomas J. Rice

Earth and Soil Sciences

No abstract provided.

Plant Establishment With Rainfall Simulators For Erosion Control, Brent Hallock, Steve Rein, Misty Scharff, Michael Curto

Earth and Soil Sciences

Hydroseeding failures on disturbed sites are usually attributable to combinations of improper species selection, seeding at inappropriate times, and/or improper seed mixes, fiber, and tackifier. To investigate these factors, California Polytechnic State University, San Luis Obispo, in conjunction with the California Department of Transportation (Caltrans) and California State University, Sacramento, conducted a study of these factors’ affect on vegetation establishment.

The goal was to identify initially fast growing vegetation that demonstrates long-term erosion control effectiveness. Native plant species common to District 5, along the California Central Coast, were used. Treatments were conducted in 0.6 by 2 m by 30 cm …

A Gis To Select Plant Species For Erosion Control Along California Highways, Michael Curto, Brent Hallock, Misty Scharff

Earth and Soil Sciences

Through road construction and maintenance activities, the California Department of Transportation (Caltrans) actively manages roadside rights-of-way that transect California's 41 million hectares (101 million acres), spanning over 3,000 meters of elevational change from seashore to subalpine. State and federal highways are grouped into 12 districts, each encompassing from one to 11 of the state's 58 counties. District personnel are typically responsible for implementing site-specific adaptations of general statewide guidelines for shortto long-term erosion control following construction or storm damage. Many erosion control projects involve reestablishing vegetation through seeding where the precarious life stages of germination and establishment are controlled by …