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Physical Sciences and Mathematics Commons

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2002

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Physical Chemistry

Electrochemistry

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Full-Text Articles in Physical Sciences and Mathematics

Electrochemical Preparation And Reaction Mechanism Of Nanocrystalline Nio, Jia-Shan Gu, Ai-Jie Han, Xing-Fu Zhou, Dao-Bao Chu, Chang-Jian Lin Nov 2002

Electrochemical Preparation And Reaction Mechanism Of Nanocrystalline Nio, Jia-Shan Gu, Ai-Jie Han, Xing-Fu Zhou, Dao-Bao Chu, Chang-Jian Lin

Journal of Electrochemistry

Metallic nickel was electrochemically dissolved in absolute ethanol and acetylacetone mixed solutions and in the presence of Bu 4NBr (as an electron-conductive additive). The electrolyte solution containing the precursor was then directly hydrolyzed to obtain nanocrystalline NiO. The precursor was characterized by FTIR?HNMR?Raman spectra and the nano-powder was characterized by XRD and TEM. The results showed that the NiO powder after calcined at 450 ℃ had formed the cubic NaCl structure and the nanocrystalline NiO prepared by this method had narrow size distribution of 10~15 nm. Moreover, the product yield could be improved by controlling temperature below 30~40 ℃. The …


Application Of Electrochemical Techniques To The Researches In Life Science, Jian-Tao Pang, Chun-Hai Fan, Gen-Xi Li May 2002

Application Of Electrochemical Techniques To The Researches In Life Science, Jian-Tao Pang, Chun-Hai Fan, Gen-Xi Li

Journal of Electrochemistry

The research work of our group in the last two years is briefly reviewed in this paper. By using electrochemical method, and combining some other chemical and biological techniques, lots of achievements have been obtained. And these researches are towards some hot topics in life science, such as function conversion, interaction between signal molecules and proteins, electron_transfer of biomolecules, gene detection, structural biology, biochemical analysis and the third generation biosensors.


Some Trends Of Electrochemistry In 21 St Century, Zhong-Hua Lin Feb 2002

Some Trends Of Electrochemistry In 21 St Century, Zhong-Hua Lin

Journal of Electrochemistry

The important advances in electrochemistry in the late twentieth century are reviewed and some trends of electrochemistry in earlier stage of the twenty_first century are discussed. Future researches in electrochemistry are indicated with an emphasis being made on the electrochemistry in new systems.