Physical Sciences and Mathematics Commons^™

Method Of Solubilizing Shortened Single-Walled Carbon Nanotubes In Organic Solutions, Robert C. Haddon, Jian Chen

Chemistry Faculty Patents

Naked single-walled nanotube carbon metals and semiconductors were dissolved in organic solutions by derivatization with SOCl₂ and octadecylamine charge. Both ionic (charge transfer) and covalent solution phase chemistry with concomitant modulation of the single-walled carbon nanotubes (SWNT) band structure were demonstrated. Solution phase near-IR spectroscopy was used to study the effects of chemical modifications on the band gaps of the SWNTs. Reaction of solubilized SWNTs with dichlorocarbene led to functionalization of the nanotube walls.

Monitoring Subsurface Drainage Flow At Remote Locations, Stephen R. Workman, Stephen F. Higgins, Scott A. Shearer

Biosystems and Agricultural Engineering Faculty Publications

Laboratory evaluations and field results are presented for a slotted weir used to measure discharge from subsurface drains. The head–discharge curve for the vertical slot is a simple power function with an exponent of 1.5. There was excellent agreement (r² > 0.99 and 1:1 slope) between predicted and observed discharge in laboratory testing of 12 test weirs representing five slot widths. The primary advantages of the vertical slot weir are its simplicity, ease of maintenance, and ability to measure small flow rates. Disadvantages include a tendency for the slot to close a small amount over time as a result of …

The Planetary Nebula A39: An Observational Benchmark For Numerical Modeling Of Photoionized Plasmas, George H. Jacoby, Gary J. Ferland, Kirk T. Korista

Physics and Astronomy Faculty Publications

Galactic nebulae are the main probes for the chemical evolution of the interstellar medium. Yet, recent observations have shown that chemical abundances determined from recombination and collisionally excited emission lines can differ by as much as an order of magnitude in some planetary nebulae (PNs). Many PNs have complex geometries and morphological evidence for interactions from stellar winds, and it is not clear to what extent winds, inhomogeneities, or shocked gas affect the observed spectrum. There currently is no full explanation for this discrepancy, which brings into question whether we understand the physical state of these low-density plasmas at all. …

Determining Matric Stress With The Modified Cam Clay Energy Relationship, Richard A. Rohlf, Larry G. Wells

Biosystems and Agricultural Engineering Faculty Publications

The stress generated by matric suction, or matric stress, was determined at points along the stress path with an analytical and experimental procedure based on the modified Cam clay energy relationship. Matric stress was found to be approximately constant at large strain for constant water content triaxial compression tests. Matric stress was included in both shear and volume relationships in a critical–state soil model that employed the modified Cam clay yield function. Shear was modeled with a constant matric stress. Slope of the normal compression and recompression lines was adjusted for matric stress using a state function that expressed matric …

Measurement And Interpretation Of Deuterium-Line Emission In The Orion Nebula, C. R. O'Dell, Gary J. Ferland, W. J. Henney

Physics and Astronomy Faculty Publications

We present new observations of the deuterium and hydrogen Balmer lines in the Orion Nebula. There is a real variation in the deuterium-to-hydrogen line ratios across the nebula, being greatest in the emission from the largest proplyd (Orion 244-440). We also present the results of a detailed model for the emission of these lines, the hydrogen lines being the result of photoionization and recombination while the deuterium lines are produced by fluorescent excitation of the upper energy states by the far-UV radiation from θ¹ Ori C. Comparison of the observations and predictions of the line intensities shows good agreement, …

Pride Water Quality Assessment Report: Iv. Nutrient Assessment, Kentucky Water Resources Research Institute, University Of Kentucky

KWRRI Research Reports

The efficient utilization of federal funds in improving the water quality and aquatic habitat of the region requires a mechanism for assessing and evaluating the impacts of the proposed and ongoing projects as well as some mechanism for prioritizing the allocation of additional funds. In order to evaluate the effectiveness of these projects it is important to provide a formal monitoring and assessment program based on sound scientific principles. This report provides an initial 10 year baseline assessment of the existing water quality conditions in the 40 county PRIDE region for the purpose of evaluating the impacts of the PRIDE …

Fractal Quasar Clouds, Mark Bottorff, Gary J. Ferland

Physics and Astronomy Faculty Publications

This paper examines whether a fractal cloud geometry can reproduce the emission-line spectra of active galactic nuclei (AGNs). The nature of the emitting clouds is unknown, but many current models invoke various types of magnetohydrodynamic confinement. Recent studies have argued that a fractal distribution of clouds, in which subsets of clouds occur in self-similar hierarchies, is a consequence of such confinement. Whatever the confinement mechanism, fractal cloud geometries are found in nature and may be present in AGNs too. We first outline how a fractal geometry can apply at the center of a luminous quasar. Scaling laws are derived that …

Solubilizing Single Walled Carbon Nanotubes By Direct Reaction With Amines And Alkylaryl Amines, Robert C. Haddon, Jian Chen

Chemistry Faculty Patents

Naked single-walled nanotube carbon metals and semiconductors are dissolved in organic solutions by direct functionalization with amines or alkylaryl amines having an uninterrupted carbon chain of at least 5 and more preferably 9 carbon atoms in length.

Letcher County Water Quality Assessment, L. Ormsbee, E. Zechman

Kentucky River Watershed Watch

No abstract provided.

Generalized Block Diagram Of The Western Pennyroyal Karst, James C. Currens

Map and Chart--KGS

Karst occurs where limestone or other soluble bedrock is near the earth's surface, and fractures in the rock become enlarged when the rock dissolves. Sinkholes and sinking streams are two surface features that indicate karst development. In karst areas most rainfall sinks underground, resulting in fewer streams flowing on the surface than in non-karst settings. Instead of flowing on the surface, the water flows underground through caves, sometimes reemerging at karst windows, then sinks again to eventually discharge at a base-level spring along a major stream or at the top of an impermeable strata. The development of karst features is …

Generalized Block Diagram Of The Pine Mountain Karst, James C. Currens

Map and Chart--KGS

Karst occurs where limestone or other soluble bedrock is near the earth's surface, and fractures in the rock become enlarged when the rock dissolves. Sinkholes and sinking streams are two surface features that indicate karst development. In karst areas most rainfall sinks underground, resulting in fewer streams flowing on the surface than in non-karst settings. Instead of flowing on the surface, the water flows underground through caves to eventually discharge at a base-level spring along a major stream or at the top of an impermeable strata. The development of karst features is influenced by the type of soluble rock and …

Illustrated Physiographic Diagram Of Kentucky, Kentucky Geological Survey

Map and Chart--KGS

No abstract provided.

Coal Availability In Western Kentucky, Gerald A. Weisenfluh, William M. Andrews Jr., Robert E. Andrews, John K. Hiett

Report of Investigations--KGS

Fourteen quadrangles in five separate areas of the Western Kentucky Coal Field were studied to determine what factors affect the availability of coal for mining. Each study area consisted of at least two adjacent 7.5-minute quadrangles in order to account for the geologic variability across broad distances in western Kentucky, and determine how this variability affects availability. Areas both north and south of the Rough Creek Fault System were selected to measure the effect of different geologic, structural, and overburden settings on coal availability. The study emphasized the coals occurring stratigraphically between the Springfield and the Baker.

About 90 percent …

Hydrogeologic Conditions Around Deep Aeration Lagoons At The Bardstown Wastewater Treatment Plant, David R. Wunsch, Gregory L. Secrist, Lyle V.A. Sendlein

Report of Investigations--KGS

The hydrogeologic conditions around the Bardstown Sewage Treatment Plant were studied from August 1996 through December 1997. Hydraulic and geochemical data were collected from eight monitoring wells and four surface-water monitoring sites on the plant property.

There is a large hydraulic gradient between the lagoons at the plant and the surrounding stream, Town Creek. Initial water-level measurements in wells surrounding the site suggest no major leakage from the lagoons, however. Neither flowing artesian conditions nor unusually high water levels were observed in any of the wells. Water-level measurements collected by data loggers showed that shallow wells responded quickly to recharge, …

Physiographic Diagram Of Kentucky, Kentucky Geological Survey

Map and Chart--KGS

No abstract provided.

Mineral And Fuel Resources Map Of Kentucky, Warren H. Anderson, Garland R. Dever Jr.

Map and Chart--KGS

The production of minerals and fuels in Kentucky is a multibillion dollar industry. Historically, coal, oil, natural gas, limestone, sand and gravel, clay, fluorite, barite, lead, iron, phosphate, zinc, and brines have been produced in the state. These resources have greatly influenced the development of Kentucky by providing raw materials for the early settlers who settled the state and for current industrial and economic development. Electrical power for homes, businesses, and factories; materials for constructing houses, buildings, automobiles, and roads; and products we consume in everyday life come from the earth's mineral and fuel resources.

The ability to locate and …

Impact Of Gravel Dredging Operations On Surface Water Quality In Streams In The Upper Cumberland Basin, Jeffrey D. Jack, Arthur C. Parola, Anna L. Curini, Randall Kelley, Mark N. French, D. J. Hagerty, William M. Sampson

KWRRI Research Reports

This is a report to the USEPA, Kentucky Division of Water and the Kentucky Water Resources Research Institute, focused on the biologic and morphological impacts of gravel mining in the upper Cumberland basin.

Exploring A Small Thrust Fault And Related Features On U.S. Highway 62/68, Near Maysville, Mason County, Kentucky, Paul Edwin Potter, John Grover, Gregory A. Schumacher

Map and Chart--KGS

One of the most unusual highway cuts in all of Kentucky is located approximately 395 ft (120 m) south of the high bridge that crosses Lawrence Creek on U.S. Highway 62/68, near Maysville, Mason County (see Figs. 1-2). The Carter coordinate location of the outcrop is 400 FSL x 900 FEL, 24-AA-69, which corresponds to 38°40'3" N latitude, 83°48'10" W longitude. The roadcut is approximately 1,315 ft (400 m) long, and rises in benches to a height of almost 110 ft (33 m). About 30 to 36 ft (9 to 11 m) of the Grant Lake Limestone is exposed at …

Kentucky Water Resources Research Institute Annual Technical Report Fy 2000, Kentucky Water Resources Research Institute, University Of Kentucky

KWRRI Annual Technical Reports (USGS’s 104b Grant Program)

The FY 2000 Annual Technical Report for Kentucky consolidates the reporting requirements of the Section 104(b) base grant and previous regional competitive grant awards in a single technical report that includes: 1) a synopsis of each ongoing research project and each project completed during the period, 2) a list of related reports published, 3) a description of information transfer activities, 4) a summary of student support during the reporting period, and 5) notable achievements and awards during the year.

Generalized Block Diagram Of The Inner Bluegrass Karst, James C. Currens

Map and Chart--KGS

Karst occurs where limestone or other soluble bedrock is near the earth's surface, and fractures in the rock become enlarged when the rock dissolves. Sinkholes and sinking streams are two surface features that indicate karst development. In karst areas most rainfall sinks underground, resulting in fewer streams flowing on the surface than in non-karst settings. Instead of flowing on the surface, the water flows underground through caves, sometimes reemerging at karst windows, then sinks again to eventually discharge at a base-level spring along a major stream or at the top of an impermeable strata. The development of karst features is …

Generalized Block Diagram Of The Eastern Pennyroyal Karst, James C. Currens

Map and Chart--KGS

Karst occurs where limestone or other soluble bedrock is near the earth's surface, and fractures in the rock become enlarged when the rock dissolves. Sinkholes and sinking streams are two surface features that indicate karst development. In karst areas most rainfall sinks underground, resulting in fewer streams flowing on the surface than in non-caves, sometimes reemerging at karst windows, then sinks again to eventually discharge at a base-level spring along a major stream or at the top of an impermeable strata. The development of karst features is influenced by the type of soluble rock and how it has been broken …

Geologic Map Of Kentucky, M. C. Noger

Map and Chart--KGS

No abstract provided.

Protect Kentucky's Karst Aquifers From Nonpoint-Source Pollution, James C. Currens

Map and Chart--KGS

No abstract provided.

Karst Occurrence In Kentucky, Randall L. Paylor, James C. Currens

Map and Chart--KGS

This map was compiled from a digital version of the 1:500,000-scale geologic map of Kentucky (Noger, M.C., comp., 1988, Geologic map of Kentucky: U.S. Geological Survey). The areas of potential karst development were delineated using stratigraphic units mapped on the geological map. The classification of the potential for karst development was based on the field experience of the authors and other data. A number of isolate carbonated unites that would not have otherwise been differentiated on the geologic map were newly digitized for this map.

2000 Kentucky River Watershed Watch Data Collection Effort, L. Ormsbee, E. Zechman

Kentucky River Watershed Watch

No abstract provided.