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Mössbauer Spectral Study Of The Magnetic Properties Of Ce₂Fe₁₇Hₓ (X=0, 1, 2, 3, 4, And 5), Dimitri Hautot, Gary J. Long, Fernande Grandjean, Olivier Isnard
Mössbauer Spectral Study Of The Magnetic Properties Of Ce₂Fe₁₇Hₓ (X=0, 1, 2, 3, 4, And 5), Dimitri Hautot, Gary J. Long, Fernande Grandjean, Olivier Isnard
Chemistry Faculty Research & Creative Works
The Mössbauer spectra of Ce2Fe17Hx, where x=0, 1, 2, 3, 4, and 5, have been measured and analyzed between 4.2 and 295 K. Because Ce2Fe17 exhibits a helical magnetic order between 225 and 90 K and a fan magnetic order below 90 K, its Mössbauer spectra were fit with a distribution of hyperfine fields and θ angles for four of the eight magnetically inequivalent sites. Because the hydrides exhibit a magnetization within the basal plane of the hexagonal cell, their Mössbauer spectra were fit with seven sextets. The four isomer shifts …
Cerium Liii-Edge X-Ray Absorption Study Of The Ceₓfe4-YCoYSb₁₂ Skutterudites, Fernande Grandjean, Gary J. Long, Robert Cortès, Donald T. Morelli, Gregory P. Meisner
Cerium Liii-Edge X-Ray Absorption Study Of The Ceₓfe4-YCoYSb₁₂ Skutterudites, Fernande Grandjean, Gary J. Long, Robert Cortès, Donald T. Morelli, Gregory P. Meisner
Chemistry Faculty Research & Creative Works
The cerium LIII-edge x-ray absorption near-edge spectra of the CexFe4-yCoySb12 compounds have been obtained at 295 K and unambiguously indicate that cerium is in the 4f1 electronic ground state for all values of 0.22≤x≤0.98 and 0.0≤y≤3.5. This stable trivalent state of cerium is in agreement with the proposed (CeFe4Sb12) 1-α(Co4Sb12)α, solid solution structure, in which the cerium atoms are always surrounded by twelve antimony first neighbors and six iron second neighbors, the observed magnetic properties of CeFe4Sb12 and …