Physical Sciences and Mathematics Commons^™

Characterization Of Dielectric Properties Of Earth Materials At Low Frequencies, Tarrah Dawn Henrie

Undergraduate Honors Capstone Projects

Sharma and de Lima (1992) have proposed a model based on Fixman's theoretical development of charged macromolecules in external fields (1980). There are three types of charges considered: the fixed surface charges that are covalently bonded, the layer of bound counterions, and the diffuse layer (Fixman, 1980, Lyklema, 1983 ). Figure (1) shows these different layers. Other common theories, such as Schurr's only consider the bound counterions and the diffuse layer. Schurr assumes that the diffuse layer ions can exchange with the electrolyte. A consequence of this assumption is the lack of polarization of the diffuse layer. This leads to …