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Physical Sciences and Mathematics Commons

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1995

Chemistry

Faculty Publications, Chemistry

Cuprate

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Dynamic Phenomena In Layer Superconducting Cuprate And Organic Metals, Juana Acrivos, Lei Chen, C. Burch Jan 1995

Dynamic Phenomena In Layer Superconducting Cuprate And Organic Metals, Juana Acrivos, Lei Chen, C. Burch

Faculty Publications, Chemistry

Dynamic electron spin resonance (ESR) and extended x-ray absorption edge fine structure (XAFS) measurements suggest that layered organic metals and cuprate superconductors behave similarly. The response to microwave radiation in a modulated external magnetic field indicates that: (i) triplet state, T * ESR is observed below Tc for both; (ii) the condensation of free spin doublet D to T* occurs above the transition temperature to superconductivity Tc (10 ± 1 K for the organic metal (BEDT-TTF)3Ta2F11 and 92 to 12 K for YBa2Cu3O7-δ and its rare earth derivatives); (iii) antiferomagnetic (AF) resonance is detected above Tc for the organic metal. …