Physical Sciences and Mathematics Commons^™

Investigations Of Iron Cycling In Aquatic Systems, Heather A. Lounsbury

Honors Theses

A fully automated luminal-based chemiluminescence flow injection analysis system has been developed for rapid detection of Fe(IT) at natural levels in natural water systems. Similar detection limits are achieved for H202 by fluorometry using an enzyme mediated oxidation of the reagent p-hydroxyphenylacetic acid. Using these analytical systems, the rates of Fe(IT) oxidation by dissolved oxygen in 0.7 M NaO have been measured for nanomolar concentrations of Fe(II) over the pH range 7.0 to 8.3. When the production and decomposition of H202 in the system were considered, measured rates were in excellent agreement with a model based on previously reported rate …