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Chemical Weathering Of Pyrite In Soils, Aaron D. Brown
Chemical Weathering Of Pyrite In Soils, Aaron D. Brown
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
The products of pyrite oxidation, including solution phase Fe2+, Fe3+, S2O32-, S4O62-, SO32- and SO42- and solid phase Fe(OH)3, were measured under controlled conditions in order to investigate the behavior of pyrite in calcareous and alkaline soils.
The distribution of sulfur oxidation products is pH dependent and can be interpreted in terms of metastable equilibrium among thiosulfate, disulfane disulfonate and sulfite. Thiosulfate and sulfite predominate in the pH range greater than about pH 7 or 8. Sulfane disulfonates are more …