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Existence Of The Dielectric Constant In Dipolar Fluid Mixtures, John D. Ramshaw, Norman D. Hamer

Physics Faculty Publications and Presentations

The existence of the dielectric constant epsilon is investigated for fluid mixtures of rigid polar molecules. The investigation is performed using the functional-derivative formalism for mixtures, and is closely analogous to that previously carried out for pure dipolar fluids (J. Chem. Phys. 68, 5199 (1978)). Sufficient conditions for the existence of epsilon are obtained in terms of the direct correlation function matrix c/sub alphabeta/(12). It is found that epsilon exists if c/sub alphabeta/(12) depends only on relative positions and orientations, and becomes asymptotic to -theta/sub alphabeta/(12)/kT at long range, where theta/sub alphabeta/(12) is the dipole--dipole potential between a molecule of …