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X-Ray Diffraction Studies On Liquids At Very High Pressures Along The Melting Curve. I. Methods And Techniques, Keith H. Brown, J. Dean Barnett

Faculty Publications

A technique using the tetrahedral anvil high-pressure x-ray system has been developed to extract coherent x-ray intensity patterns of liquids near melting from measured scattering curves in the presence of high-background counts. Radial distribution functions for liquids along the melting curve to pressures of at least 50 kbar can be obtained. At each pressure scattering curves are recorded for the liquid and solid on opposite sides of the melting curve and a subtraction is made to eliminate background and incoherent scattering. Theoretical estimates of the thermal diffuse scattering from the solid are added to the appropriately corrected difference patterns to …