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Full-Text Articles in Physical Sciences and Mathematics

First-Row Transition Element Distribution Across The Blueschist-Eclogite Transition: A Case Study From New Caledonia, Natalie M. Harmon Dec 2022

First-Row Transition Element Distribution Across The Blueschist-Eclogite Transition: A Case Study From New Caledonia, Natalie M. Harmon

Electronic Theses and Dissertations

The first-row transition elements (FRTE), namely Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, are potential redox tracers in the solid Earth due to their general compatibility during crustal processes, and the redox-sensitive nature of certain elements. Despite widespread interest in the FRTEs, their distribution and behavior in subduction zones, particularly across the blueschist-eclogite transition, are still poorly constrained. New Caledonia preserves a prograde subduction zone with largely coherent continuous progression in metamorphic grade. Although the metamorphic sequence has been disrupted to some extent, this is the closest natural example of blueschist and eclogite that was sourced …


Air Quality Impacts From Mineral Dust, Fireworks, And Urban Pollution Revealed By Trace Element Chemistry And Strontium Isotopes Ratios In The Wasatch Front, Utah, Usa, Micah J. Marcy Aug 2022

Air Quality Impacts From Mineral Dust, Fireworks, And Urban Pollution Revealed By Trace Element Chemistry And Strontium Isotopes Ratios In The Wasatch Front, Utah, Usa, Micah J. Marcy

Theses and Dissertations

Airborne particulate matter (PM) in urban areas is derived from a combination of natural and anthropogenic sources. To identify PM sources and their effects on air quality, we collected PM using active filter samplers over a two-year period in the urban Wasatch Front, northern Utah, an area affected by multiple pollution sources. Filters from active samplers and other PM samples were analyzed for major and trace element concentrations and 87Sr/86Sr ratios. We identified wind-blown mineral dust from dry lake beds, winter inversions, and fireworks as primary PM sources affecting air quality in the Wasatch Front. Dust contributes Al, Be, Ca, …


Understanding Biogeochemical And Physical Controls On Methane Air-Sea Exchange Fluxes In The Pacific Ocean, Sarah Raney May 2022

Understanding Biogeochemical And Physical Controls On Methane Air-Sea Exchange Fluxes In The Pacific Ocean, Sarah Raney

Master's Theses

Methane and trace element samples were collected on GEOTRACES GP15 Pacific Meridional Transect (PMT) cruise conducted between the Aleutian Islands (57 °N) and Tahiti (20 °S) from September to November 2018. Uncertainty in methane air-sea exchange fluxes was determined using a propagation of errors approach. Fluxes ranged from -0.88 to 4.9 µmol CH4 m-2 d-1. Average CH4 flux along the Alaskan margin was 2.2 ± 2.9 µmol CH4 m-2 d-1. Methane fluxes decreased moving southward and increased to their open ocean maximum around 20 °N before declining in equatorial waters. Near …