Physical Sciences and Mathematics Commons^™

In The Margins: Reconsidering The Range And Contribution Of Diazotrophs In Nearshore Environments, Corday R. Selden

OES Theses and Dissertations

Dinitrogen (N₂) fixation enables primary production and, consequently, carbon dioxide drawdown in nitrogen (N) limited marine systems, exerting a powerful influence over the coupled carbon and N cycles. Our understanding of the environmental factors regulating its distribution and magnitude are largely based on the range and sensitivity of one genus, Trichodesmium. However, recent work suggests that the niche preferences of distinct diazotrophic (N₂ fixing) clades differ due to their metabolic and ecological diversity, hampering efforts to close the N budget and model N₂ fixation accurately. Here, I explore the range of N₂ fixation …

The Impact Of Stream-Groundwater Exchange On Seasonal Nitrate Loads In An Urban Stream, Julio I. Beltran

Theses - ALL

Urbanization negatively impacts water quality in streams by reducing stream-groundwater interactions, which reduces the stream’s ability to naturally attenuate nitrate. Meadowbrook Creek, a first order urban stream in Syracuse, New York, has a negative urbanization gradient that results in urbanized headwaters that are disconnected from the floodplain, and downstream reaches that have intact riparian floodplains and connection to riparian aquifers. This system allows us to assess how stream-aquifer interactions in urban streams impact the net sources and sinks of nitrate at the reach scale. We used continuous (15-minute) streamflow measurements, along with weekly grab samples at three gauging stations positioned …

Spatial And Temporal Variation Of Nutrients In The Great Lakes-St. Lawrence Basin: Implications For Primary Production In Stream Ecosystems, Nolan Pearce

Electronic Thesis and Dissertation Repository

Growing human populations and associated land use activities has increased the amount of nutrients delivered to surface waters. Eutrophication from the over-enrichment of nitrogen and phosphorus has degraded ecosystem conditions in streams, lakes, and coastal areas worldwide. Thus, the management of anthropogenic nutrient loading is a global concern. This thesis employed a combination of field and experimental research to provide watershed managers with information on the spatial and temporal patterns in stream nutrient enrichment, and the associated ecological effects of anthropogenic nutrient loading in the Great Lakes-St. Lawrence basin. Four studies were completed to address this research goal. First, I …

Effect Of Plant Derived Tannins On Nitrogen And Carbon Cycling In Pasture Soils, Kathryn A. Slebodnik

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Pasture-finished beef has become increasingly popular, but nitrogen losses from these pastures are of concern. Legumes containing condensed tannins such as birdsfoot trefoil (Lotus corniculatus) and sainfoin (Onobrychis viciifolia) may serve as environmentally and economically viable alternative forages in pasture finishing systems while reducing soil nitrogen loss. The goal of this project was to understand how tannin type and concentration affects soil nitrogen cycling both in the lab and the field. This thesis: 1) compared the physical, chemical, and biological characteristics of soil samples obtained from grazed grass and tannin and non-tannin containing legume pastures, 2) …

Nitrogen Fertilizer Needs Of First-Year Small Grains Following Alfalfa, Collin Pound

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Wheat, barley, triticale, and oats, are small grains commonly grown as hay and grain following alfalfa in Utah and the Intermountain West, especially during drought years as they require less irrigation than corn. Several studies in many parts of the world have shown that first-year corn following alfalfa rarely needs nitrogen (N) fertilizer, yet relatively few have evaluated the N needs of small grains, especially small grains grown for hay. Objectives of this research were to determine whether N fertilizer is needed to economically optimize the yield and quality of first-year small grains following alfalfa, develop N guidelines, and whether …

A Study Of The Anthropogenic Impact In Farmington Bay Through Isotopic And Elemental Analysis, Nathan Vaun Gunnell

Theses and Dissertations

The influence of human activity on surrounding environments is an important field of research. With respect to aquatic settings, lacustrine deposits provide excellent proxies of environmental change since the sediment accumulates at a relatively constant rate, recording environmental change. This study employs isotopic, mineral, and chemical records from Farmington Bay freeze cores, in particular δ13C, δ15N, and 210Pb isotopes as well as phosphorus level fluctuation and trace metal analysis. In particular, 210Pb isotopes permit estimation of the age of sediment with depth and δ15N, δ13C, and concentration of P provides a record of changing nutrient sources and level of eutrophication. …

In Situ Plant Uptake Of Excess Nutrients And Consequential Alteration Of Rhizosphere Dynamics, Srusti Maddala

Crop, Soil and Environmental Sciences Undergraduate Honors Theses

The use of phytoremediation in ecological remediation projects has numerous benefits including soil stabilization and nutrient uptake. Recently, microdialysis, a diffusion-based sampling technique commonly used in biomedical research, has been recognized as a candidate for monitoring chemical changes in the rhizosphere. The real-time, in situ data it provides about nutrient diffusion may improve the management and success of restoration projects. Therefore, the objective of this study was to employ the technique of microdialysis in the novel application of quantifying the diffusive flux of inorganic nitrogen compounds in the rhizosphere of native plants of Arkansas. The microdialysis technique was first optimized …

Field And Numerical Evaluation Of Nitrogen Transport From Septic Systems In Surfical Aquifer Systems To Charlotte Harbor, Florida, Tanten T. Buszka

Masters Theses

Shallow water tables in coastal surficial aquifers limit effective treatment of septic effluent which can result in excess nutrient loading into nearby surface water bodies. Approximately 45,000 septic systems in Charlotte County, Florida transmit effluent into an under studied surficial aquifer and contribute to harmful algal blooms and outbreaks of E. coli. An undeveloped field site was characterized using standard hydrogeologic methods, including a one-year duration natural gradient tracer test, to obtain representative lithology of the sandy surficial aquifer and estimates of groundwater velocity, flow directions, effective porosity and dispersion. These data were used to support the development of a …

The Design Of A Continuous Wave Molecular Nitrogen Stimulated Raman Laser In The Visible Spectrum, Timothy J. Bate

Theses and Dissertations

Hollow-core photonic crystal fibers (HCPCFs) shows promise as a hybrid laser with higher nonlinear process limits and small beam size over long gain lengths. This work focuses on the design of a CW molecular nitrogen (N₂) stimulated Raman laser. N₂ offers Raman gains scaling up to 900 amg, scaling higher than H₂. The cavity experiment showed the need to include Rayleigh scattering in the high pressure required for N₂ Raman lasing. Even at relatively low pressure ssuch as 1,500 psi, high conversion percentages should be found if the fiber length is chosen based on …

Evaluation Of Nitrogen And Phosphorus Removal In Alternative Management Practices For Dairy Farm Production Area Runoff: Bioretention Cells And A Woodchip Bioreactor Treatment System, Jillian Sarazen

Graduate College Dissertations and Theses

Non-point source pollution from agricultural areas can lead to the degradation of downstream water bodies, including eutrophication and harmful algal blooms, due to high concentrations of nitrogen (N) and phosphorus (P) emanating from these areas. One source of agricultural runoff that is often overlooked, originates from agricultural production areas, which have impervious surfaces, such as paved and compacted areas, barnyards, cow paths, and silage bunker storage; these areas generate stormwater runoff and contribute to pollution during storm events.

This research evaluates two built stormwater runoff treatment systems designed to treat high concentrations of nutrients in runoff from a dairy farm. …

The Environmental Microbiome In A Changing World: Microbial Processes And Biogeochemistry, Stephanie Juice

Graduate College Dissertations and Theses

Climate change can alter ecosystem processes and organismal phenology through both long-term, gradual changes and alteration of disturbance regimes. Because microbes mediate decomposition, and therefore the initial stages of nutrient cycling, soil biogeochemical responses to climate change will be driven by microbial responses to changes in temperature, precipitation, and pulsed climatic events. Improving projections of soil ecological and biogeochemical responses to climate change effects therefore requires greater knowledge of microbial contributions to decomposition. This dissertation examines soil microbial and biogeochemical responses to the long-term and punctuated effects of climate change, as well as improvement to decomposition models following addition of …

Community Structure Has Greater Effect On Water Column Ammonium Cycling Than Nutrients And Temperature In Shallow Lake Mesocosms, Shannon Marie Collins

Browse all Theses and Dissertations

Harmful algal blooms (HABs) impact lakes worldwide and are caused by excess nitrogen (N) and phosphorus (P) loading from watersheds. Climate warming and nutrient loading effects on N cycling were examined in shallow lake mesocosms in Denmark. N loading to some mesocosms ceased in June 2018 and resumed in June 2019. Ammonium (NH4+) uptake, regeneration, and nitrification and nitrate uptake rates were evaluated. High nutrient, ambient temperature mesocosms exhibited the highest NH4+ cycling rates. Before resumption of N loading in high nutrient mesocosms, NH4+ regeneration supported 46 % of potential microbial NH4+ demand, versus 24 % with N loading. Nutrient …