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Graduate Theses and Dissertations

Earth Sciences

Chert

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Comparative Geochemical Analysis Of Ordovician And Mississippian Cherts In Relation To The Northern Arkansas And The Tri-State Mississippi Valley-Type Ore Districts, Jonathan T. Chick May 2020

Comparative Geochemical Analysis Of Ordovician And Mississippian Cherts In Relation To The Northern Arkansas And The Tri-State Mississippi Valley-Type Ore Districts, Jonathan T. Chick

Graduate Theses and Dissertations

It has been hypothesized that Ordovician, Mississippian, and younger carbonate and clastic formations found within the Ouachita Basin of west-central Arkansas and northward onto the Ozark Dome have experienced interaction with hydrothermal fluids due to tectonic forces produced by the Ouachita Orogeny. Lead (Pb) isotope analyses and resulting values produced through previous and concurrent geochemical studies of several formations indicate that the Mississippi Valley-type (MVT) ores were produced from a mixing and cooling of these sedimentary basinal brines by meteoric or connate waters. Reduction of sulfate to sulfide is one of the possible mechanisms by which MVT ore precipitation may …


Geochemical Analysis Of Mississippian Cherts And Devonian-Mississippian Novaculites, Southern Midcontinent Region, Julie Mary Cains May 2019

Geochemical Analysis Of Mississippian Cherts And Devonian-Mississippian Novaculites, Southern Midcontinent Region, Julie Mary Cains

Graduate Theses and Dissertations

This study uses trace elements and radiogenic isotopes (Pb, Sr, and Nd) to investigate the origin and mode of formation for the siliceous deposits in the Lower Mississippian Boone Formation and the Devonian-Mississippian Arkansas Novaculite in the southern midcontinent. Mississippi Valley-type Pb-Zn ore deposits in the Tri-State District and the Northern Arkansas District were deposited by hydrothermal fluids, and highly radiogenic Pb isotope ratios suggest a genetic relationship between the Boone Formation chert (206Pb/204Pb ~ 21.59, 207Pb/204Pb ~ 15.87, 208Pb/204Pb ~ 40.10) and the MVT ores. Due to the very low concentration of Pb in the Boone chert (~2 ppm) …


A Geochemical Analysis Of The Arkansas Novaculite And Comparison To The Siliceous Deposits Of The Boone Formation, John Byron Scott Philbrick May 2016

A Geochemical Analysis Of The Arkansas Novaculite And Comparison To The Siliceous Deposits Of The Boone Formation, John Byron Scott Philbrick

Graduate Theses and Dissertations

Geochemical analyses of the Arkansas Novaculite, located within core structures of the Ouachita Mountains in west-central Arkansas, and penecontemporaneous chert of the lower Boone Formation, located atop the Springfield Plateau of southwest Missouri, northwest Arkansas, and northeast Oklahoma, have identified a significant concentration of both aluminum and potassium. This would seem to eliminate a biogenic origin and favor a volcanic source of the silica that comprises these units. Trace and rare earth element (REE) analysis also suggests that the Arkansas Novaculite and the chert in the lower Boone Formation may have both been formed from the same volcanic source.

The …


Toolstone Use In Ozark Prehistory: Assessing Adaptations To A Lithic Dichotomy In The Boston Mountains And Springfield Plateau, Luke Allen Morris May 2015

Toolstone Use In Ozark Prehistory: Assessing Adaptations To A Lithic Dichotomy In The Boston Mountains And Springfield Plateau, Luke Allen Morris

Graduate Theses and Dissertations

Toolstone use in the Ozark Mountains is a reactionary process reliant on how the landscape provides or constrains chipped stone for prehistoric populations. These technological adaptations are recognized at sites throughout the area, but no regional assessment of lithic assemblages provides answers as to why certain stones are used at a particular location. This thesis employs a five step mass analysis of lithic assemblages, and GIS visualizations to observe how the organization of stone technologies vary based on location within contrasting geologic contexts. The chert-bearing Springfield Plateau, and the Boston Mountains with siltstone, are two neighboring dichotomous landscapes that illustrate …


Analysis Of Tripolitic Chert In The Boone Formation (Lower Mississippian, Osagean), Northwest Arkansas And Southwestern Missouri, Paul Marchand Minor Aug 2013

Analysis Of Tripolitic Chert In The Boone Formation (Lower Mississippian, Osagean), Northwest Arkansas And Southwestern Missouri, Paul Marchand Minor

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas and southwestern Missouri exposes a nearly complete sequence of Lower Mississippian chert-bearing carbonates deposited by a single 3rd order transgression and regression. An abundant amount of chert that has replaced limestone highlights the Boone, but little is understood about the timing and development of chert in Lower Mississippian carbonates. Interpretation of the diagenetic history of the chert, in particular tripolite, has significant implications beyond the outcrop. Determining the origin, timing, and extent of tripolitic chert in the Lower Mississippian System improves reservoir characterization in subsurface petroleum reservoirs in the mid-continent that are laterally equivalent …