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Full-Text Articles in Physical Sciences and Mathematics
Modeling Flocculation And Deflocculation Processes Of Cohesive Sediments, Xiaoteng Shen
Modeling Flocculation And Deflocculation Processes Of Cohesive Sediments, Xiaoteng Shen
Dissertations, Theses, and Masters Projects
The transport and fate of cohesive sediments are responsible for many engineering, environmental, economic and policy issues that relate to, for example, siltation and dredging in navigation channels, water quality, water turbidity, pollutant transports, and biological ecosystem responses. Our current understanding, however, is insufficient to conduct accurate quantitative predictions of these processes. This is because the cohesive particles in natural waters will flocculate, which determines the settling, and thus the deposition behaviors. The simulation of flocculation processes is a primary challenge since the time variation of Floc Size Distribution (FSD) is controlled by a partial differential equation that also contains …
Assessing The Impact Of Climate Change On Proposed Restoration Of The Lynnhaven River Ecosystem, Emily E. Skeehan
Assessing The Impact Of Climate Change On Proposed Restoration Of The Lynnhaven River Ecosystem, Emily E. Skeehan
Dissertations, Theses, and Masters Projects
Environmental degradation of the Chesapeake Bay (CB) and its sub-estuaries has been linked to population growth in the surrounding coastal zone, rapid development in the watershed and resultant nutrient loading into the Bay. Consequently, the federal government and its partners have developed restoration plans to mitigate the effects of eutrophication and improve essential ecosystem functions, though few restoration plans have considered the interactive effects of climate change. Climate change and other anthropogenic drivers are causing changes in ecosystem structure and function, thereby impacting the beneficial services ecosystems provide. While some studies have attempted to quantitatively predict the benefits of ecosystem …
Development Of Boron-Containing Polyimide Materials And Poly(Arylene Ether)S For Radiation Shielding, Brittani May Collins
Development Of Boron-Containing Polyimide Materials And Poly(Arylene Ether)S For Radiation Shielding, Brittani May Collins
Dissertations, Theses, and Masters Projects
No abstract provided.
Magneto-Optics And Magneto-Transport Studies On Thin Films For Sensor Applications, Kaida Yang
Magneto-Optics And Magneto-Transport Studies On Thin Films For Sensor Applications, Kaida Yang
Dissertations, Theses, and Masters Projects
Recent progress and interest have bought considerable effort to bear on the synthesis and opportunities of magnetic thin films in different fields. There are applications in many fields, including remote sensing, waveguide applications, hard drive applications, etc. at the College of William and Mary, we have focused on utilizing magnetic thin films in some of these applications and are deeply involved in the optimization process of the thin films.
Superconducting Thin Films For Srf Cavity Applications: A Route To Higher Field Gradient Linacs, Wiliam Michael Roach
Superconducting Thin Films For Srf Cavity Applications: A Route To Higher Field Gradient Linacs, Wiliam Michael Roach
Dissertations, Theses, and Masters Projects
Many linear accelerator (linac) applications rely on the use of superconducting radio frequency (SRF) cavities. In order to overcome the current field gradient limits imposed by the use of bulk niobium, a model involving the deposition of alternating superconducting-insulating-superconducting (SIS) thin films onto the interior surface of SRF cavities has been proposed. Since SRF performance is a surface phenomenon, the critical surface of these cavities is less than 1 micron thick, thus enabling the use of thin films. Before such approach can successfully be implemented fundamental studies correlating the microstructure and superconducting properties of thin films are needed. to this …
Effective Resource And Workload Management In Data Centers, Lei Lu
Effective Resource And Workload Management In Data Centers, Lei Lu
Dissertations, Theses, and Masters Projects
The increasing demand for storage, computation, and business continuity has driven the growth of data centers. Managing data centers efficiently is a difficult task because of the wide variety of datacenter applications, their ever-changing intensities, and the fact that application performance targets may differ widely. Server virtualization has been a game-changing technology for IT, providing the possibility to support multiple virtual machines (VMs) simultaneously. This dissertation focuses on how virtualization technologies can be utilized to develop new tools for maintaining high resource utilization, for achieving high application performance, and for reducing the cost of data center management.;For multi-tiered applications, bursty …
An Evaluation Of A Reduced Bar Spacing Turtle Excluder Device In The U.S Gulf Of Mexico Offshore Shrimp Trawl Fishery, Michel Anthony Nalovic
An Evaluation Of A Reduced Bar Spacing Turtle Excluder Device In The U.S Gulf Of Mexico Offshore Shrimp Trawl Fishery, Michel Anthony Nalovic
Dissertations, Theses, and Masters Projects
Shrimp are the most economically valuable internationally-traded seafood commodity, and wild-caught, trawled shrimp make up almost half of the ~6.6 million metric tons of annual global production. Shrimp trawling is responsible for one-third of the world’s total fisheries bycatch, leading many to consider shrimp trawling to be the single most destructive fishing practice in the world. Though the bycatch of large marine animals can be significantly reduced by use of turtle excluder devices (TEDs) on shrimp trawls, current TED designs are ineffective at reducing the capture of smaller organisms which represent a large portion of the total bycatch. To further …
Nonlinear Optical Studies Of Photoelastic Effect And Magneto-Plasmonics, Wei Zheng
Nonlinear Optical Studies Of Photoelastic Effect And Magneto-Plasmonics, Wei Zheng
Dissertations, Theses, and Masters Projects
Nonlinear optical (NLO) processes are optical phenomena involving a nonlinear response to an applied light field. Two kinds of nonlinearities are studied in this dissertation: magnetic-induced second-harmonic generation (MSHG) interacting with surface plasmon, called "nonlinear magnetoplasmonics" (NMP), and the nonlinear index induced by a strong pump beam in Titanium doped sapphire crystal, referred to as population-induced nonlinear index effect.;The fundamentals of the major effects involved are discussed, which include: surface plasmon and its field enhancement effect, MSHG technique and phenomenological calculations, the contrast ratio of magnetic switching, the calculation of lensing effects, population induced strain, and photoelastic effect. Furthermore, the …
Optical Characterization Of Magnetism In Magnetic/Nonmagnetic Heterostructures, Yichun Fan
Optical Characterization Of Magnetism In Magnetic/Nonmagnetic Heterostructures, Yichun Fan
Dissertations, Theses, and Masters Projects
This thesis focuses on the study of the static and dynamic magnetic interactions in ferromagnetic/nonmagnetic heterostructures using interface-specific and time-resolved optical techniques. The goal of this thesis is to elucidate the interface exchange coupling, magnetic anisotropy, and coherent spin dynamics in these advanced material systems, crucial to the realization of high performance spintronic devices.;First, a pronounced exchange bias (EB) phenomenon is observed in Fe/MgO (001) by magnetic second harmonic generation. The bulk magnetization does not, in marked contrast to typical systems where EB is manifested only in the net magnetization. The magnitude of the exchange bias varies with interface oxygen …
Polymeric Radiation Shielding For Applications In Space: Polyimide Synthesis And Modeling Of Multi-Layered Polymeric Shields, Clinton Cleveland Schiavone
Polymeric Radiation Shielding For Applications In Space: Polyimide Synthesis And Modeling Of Multi-Layered Polymeric Shields, Clinton Cleveland Schiavone
Dissertations, Theses, and Masters Projects
No abstract provided.
Surface Impedance Of Superconducting Radio Frequency (Srf) Materials, Binping Xiao
Surface Impedance Of Superconducting Radio Frequency (Srf) Materials, Binping Xiao
Dissertations, Theses, and Masters Projects
Superconducting radio frequency (SRF) technology is widely adopted in particle accelerators. There remain many open questions, however, in developing a systematic understanding of the fundamental behavior of SRF materials, including niobium treated in different ways and various other bulk/thin film materials that are fabricated with different methods under assorted conditions. A facility that can measure the SRF properties of small samples in a range of 2∼40 K temperature is needed in order to fully answer these questions. The Jefferson Lab surface impedance characterization (SIC) system has been designed to attempt to meet this requirement. It consists of a sapphire-loaded cylindrical …
An Input Centric Paradigm For Program Dynamic Optimizations And Lifetime Evolvement, Kai Tian
An Input Centric Paradigm For Program Dynamic Optimizations And Lifetime Evolvement, Kai Tian
Dissertations, Theses, and Masters Projects
Accurately predicting program behaviors (e.g., memory locality, method calling frequency) is fundamental for program optimizations and runtime adaptations. Despite decades of remarkable progress, prior studies have not systematically exploited the use of program inputs, a deciding factor of program behaviors, to help in program dynamic optimizations. Triggered by the strong and predictive correlations between program inputs and program behaviors that recent studies have uncovered, the dissertation work aims to bring program inputs into the focus of program behavior analysis and program dynamic optimization, cultivating a new paradigm named input-centric program behavior analysis and dynamic optimization.;The new optimization paradigm consists of …
Microscopic Dynamics And Transport Of Hydrogen In Proton Conducting Oxides, Erik J. Spahr
Microscopic Dynamics And Transport Of Hydrogen In Proton Conducting Oxides, Erik J. Spahr
Dissertations, Theses, and Masters Projects
The microscopic motion of hydrogen in solid oxides plays an important role in defect migration and reaction processes. Understanding the vibrational dynamics associated with both hydrogen-oxygen (O-H) bonds and the surrounding ionic environment allows one to better characterize these fundamental interactions. This thesis presents a comprehensive investigation into the vibrational decay dynamics of O-H and O-D stretch modes in crystalline oxides using time-resolved infrared pump-probe spectroscopy.;Measurements of the vibrational lifetimes of hydrogen related local modes in potassium tantalate (KTaO3) and titanium dioxide (TiO2 ) show that the localized O-H vibration is very closely tied to proton transport. In KTaO3 we …
Thin Film And Chemical Ordering Effects On The Magnetic Anisotropy In Binary Alloys, Jonathan Ronald Skuza
Thin Film And Chemical Ordering Effects On The Magnetic Anisotropy In Binary Alloys, Jonathan Ronald Skuza
Dissertations, Theses, and Masters Projects
This dissertation presents various investigations into the structure-property correlations in highly anisotropic FePt and FePd thin films and nanostructures. These binary alloy thin films may exhibit long-range chemical ordering (e.g. L10), which induces a strong uniaxial magnetic anisotropy whose orientation is dependent on the ordering direction in the thin film. The chemical ordering, and hence the magnetic anisotropy, in these thin films can be controlled and tailored through sputter deposition and ion implantation conditions followed by subsequent processing. Two novel fabrication methods, x-ray rapid thermal annealing (XRTA) and heavy ion implantation, successfully demonstrate the ability to obtain highly anisotropic nanometer-sized …
Enhanced Field Emission From Vertically Oriented Graphene By Thin Solid Film Coatings, Michael Bagge-Hansen
Enhanced Field Emission From Vertically Oriented Graphene By Thin Solid Film Coatings, Michael Bagge-Hansen
Dissertations, Theses, and Masters Projects
Recent progress and a coordinated national research program have brought considerable effort to bear on the synthesis and application of carbon nanostructures for field emission. at the College of William and Mary, we have developed field emission arrays of vertically oriented graphene (carbon nanosheets, CNS) that have demonstrated promising cathode performance, delivering emission current densities up to 2 mA/mm2 and cathode lifetime > 800 hours. The work function ( & phis;) of CNS and other carbonaceous cathode materials has been reported to be &phis;∼4.5-5.1 eV. The application of low work function thin films can achieve several orders of magnitude enhancement of …
Production Of Cyclohexylene-Containing Diamines In Pursuit Of Novel Radiation Shielding Materials, Norah G. Bate
Production Of Cyclohexylene-Containing Diamines In Pursuit Of Novel Radiation Shielding Materials, Norah G. Bate
Dissertations, Theses, and Masters Projects
No abstract provided.
First-Principles Calculations Of Nuclear Magnetic Resonance Chemical Shielding Tensors In Complex Ferroelectric Perovskites, Daniel Lawrence Pechkis
First-Principles Calculations Of Nuclear Magnetic Resonance Chemical Shielding Tensors In Complex Ferroelectric Perovskites, Daniel Lawrence Pechkis
Dissertations, Theses, and Masters Projects
Nuclear magnetic resonance (NMR) spectroscopy is one of the most important experimental probes of local atomistic structure, chemical ordering, and dynamics. Recently, NMR has increasingly been used to study complex ferroelectric perovskite alloys, where spectra can be difficult to interpret. First-principles calculations of NMR spectra can greatly assist in this task. In this work, oxygen, titanium, and niobium NMR chemical shielding tensors, s&d4; , were calculated with first-principles methods for ferroelectric transition metal prototypical ABO3 perovskites [SrTiO3, BaTiO 3, PbTiO3 and PbZrO3] and A(B,B')O3 perovskite alloys Pb(Zr1/2Ti1/2)O3 (PZT) and Pb(Mg1/3Nb2/3)O3 (PMN). The principal findings are 1) a large anisotropy between …
On The Real-Time Performance, Robustness And Accuracy Of Medical Image Non-Rigid Registration, Yixun Liu
On The Real-Time Performance, Robustness And Accuracy Of Medical Image Non-Rigid Registration, Yixun Liu
Dissertations, Theses, and Masters Projects
Three critical issues about medical image non-rigid registration are performance, robustness and accuracy. A registration method, which is capable of responding timely with an accurate alignment, robust against the variation of the image intensity and the missing data, is desirable for its clinical use. This work addresses all three of these issues. Unacceptable execution time of Non-rigid registration (NRR) often presents a major obstacle to its routine clinical use. We present a hybrid data partitioning method to parallelize a NRR method on a cooperative architecture, which enables us to get closer to the goal: accelerating using architecture rather than designing …
Characterization Of Pa-11 Flexible Liner Aging In The Laboratory And In Field Environments Throughout The World, Arthur Jaeton Mitman Glover
Characterization Of Pa-11 Flexible Liner Aging In The Laboratory And In Field Environments Throughout The World, Arthur Jaeton Mitman Glover
Dissertations, Theses, and Masters Projects
Polyamide-11 (PA11) is a polymer of the Nylon family whose monomer is obtained from the castor bean, a renewable resource. It is widely used in offshore oil and gas production as a non-rigid flexible pipe liner, allowing for oil and gas transport from the wellhead to floating platforms for processing. The degradation of PA11 over time may lead to the pipe's failure, with possibly catastrophic results which include loss of life. Until now, the characterization of the degredative process has been limited to laboratory studies of the effects of water and temperature on the rate and degree of hydrolysis. In …
Applications Of Pattern Classification To Time-Domain Signals, Crystal Ann Bertoncini
Applications Of Pattern Classification To Time-Domain Signals, Crystal Ann Bertoncini
Dissertations, Theses, and Masters Projects
Many different kinds of physics are used in sensors that produce time-domain signals, such as ultrasonics, acoustics, seismology, and electromagnetics. The waveforms generated by these sensors are used to measure events or detect flaws in applications ranging from industrial to medical and defense-related domains. Interpreting the signals is challenging because of the complicated physics of the interaction of the fields with the materials and structures under study. often the method of interpreting the signal varies by the application, but automatic detection of events in signals is always useful in order to attain results quickly with less human error. One method …
Advancements In Dual-Pump Broadband Cars For Supersonic Combustion Measurements, Sarah Augusta. Tedder
Advancements In Dual-Pump Broadband Cars For Supersonic Combustion Measurements, Sarah Augusta. Tedder
Dissertations, Theses, and Masters Projects
Space- and time-resolved measurements of temperature and species mole fractions of nitrogen, oxygen, and hydrogen were obtained with a dual-pump coherent anti-Stokes Raman spectroscopy (CARS) system in hydrogen-fueled supersonic combustion free jet flows. These measurements were taken to provide time-resolved fluid properties of turbulent supersonic combustion for use in the creation and verification of computational fluid dynamic (CFD) models. CFD models of turbulent supersonic combustion flow currently facilitate the design of air- breathing supersonic combustion ramjet (scramjet) engines. Measurements were made in supersonic axi-symmetric free jets of two scales. First, the measurement system was tested in a laboratory environment using …
Processing And Conversion Of Algae To Bioethanol, Sara Katherine Kampfe
Processing And Conversion Of Algae To Bioethanol, Sara Katherine Kampfe
Dissertations, Theses, and Masters Projects
No abstract provided.
Optical Control Of Ultrafast Spin -Wave Relaxation By Magnetic Anisotropy In A Ferromagnet, Kevin James Smith
Optical Control Of Ultrafast Spin -Wave Relaxation By Magnetic Anisotropy In A Ferromagnet, Kevin James Smith
Dissertations, Theses, and Masters Projects
This thesis presents an investigation of the damping of spin waves in ferromagnetic Au(3 nm)/Ni(10 nm)/MgO(001) thin films using the time-resolved Magneto-optical Kerr Effect (TR-MOKE) and ferromagnetic resonance (FMR) techniques. In the optical measurements, a 150 fs, 800 nm laser beam pulse is split into pump and probe components. The pump pulse, containing most of the beam energy, thermally excites coherent spin precession. The weaker probe pulse, time-delayed by a variable beam path, captures the magnetization dynamics via the polar MOKE effect, and oscillations are observed as a function of external field amplitude and direction. The extracted precession frequency is …
Multifunctional Polymer Synthesis And Incorporation Of Gadolinium Compounds And Modified Tungsten Nanoparticles For Improvement Of Radiation Shielding For Use In Outer Space, Emily Grace Harbert
Multifunctional Polymer Synthesis And Incorporation Of Gadolinium Compounds And Modified Tungsten Nanoparticles For Improvement Of Radiation Shielding For Use In Outer Space, Emily Grace Harbert
Dissertations, Theses, and Masters Projects
No abstract provided.
Silver-Polyimide Nanocomposite Films: Single-Stage Synthesis And Analysis Of Metalized Partially-Fluorinated Polyimide Btda/4-Bdaf Prepared From Silver(I) Complexes, Joshua Erold Robert Abelard
Silver-Polyimide Nanocomposite Films: Single-Stage Synthesis And Analysis Of Metalized Partially-Fluorinated Polyimide Btda/4-Bdaf Prepared From Silver(I) Complexes, Joshua Erold Robert Abelard
Dissertations, Theses, and Masters Projects
No abstract provided.
The Functionalization Of Carbon Nanosheets, Ronald A. Quinlan
The Functionalization Of Carbon Nanosheets, Ronald A. Quinlan
Dissertations, Theses, and Masters Projects
Carbon nanosheets are a novel two-dimensional nanostructure made up of 2-20 graphene atomic planes oriented with their in-plane axis perpendicular to the growth substrate. Previous efforts in developing nanosheet technology have focused on the characterization of the system and their development as an electron source due to the high atomic enhancement factor (beta) and low turn on field. Further investigation of nanosheets as high surface area electrodes revealed poor wetting by polymeric material and extreme hydrophobic behavior.;Because nanosheet technology has promise as a high surface area electrode material, this thesis research has focused on three areas of interest: the enhancement …
Twine-Top Modifications Of Sea-Scallop Dredges: Reducing Yellowtail-Flounder Bycatch, Kelli A. Milleville
Twine-Top Modifications Of Sea-Scallop Dredges: Reducing Yellowtail-Flounder Bycatch, Kelli A. Milleville
Dissertations, Theses, and Masters Projects
No abstract provided.
Time-Resolved Magnetic Flux And Ac-Current Distributions In Superconducting Yttrium Barium Copper Oxide Thin Films And Multifilaments, Ran Yang
Dissertations, Theses, and Masters Projects
Time-resolved magneto-optical imaging (TRMOI) technique allows dynamic ac transport measurements on superconductors. The high time and spatial resolutions of the measurements also offer good quantitative data analysis of the MO images. YBa2Cu 3O7-delta (YBCO) was discovered as a high-temperature superconductor (HTSC) which has wide applications due to its high critical temperature of Tc = 91 K, and high critical current density Jc in the order of 106-7 Acm-2. Many of the applications require high ac current load and a high magnetic field. We study the interaction behavior of YBCO thin films in an ac transport current and a dc magnetic …
Effects Of Metal-Based Montmorillonite Clay And Zeolite Additives On The Fire Retardance And Smoke Suppression Of Poly(Vinyl Chloride), Alexander George Zestos
Effects Of Metal-Based Montmorillonite Clay And Zeolite Additives On The Fire Retardance And Smoke Suppression Of Poly(Vinyl Chloride), Alexander George Zestos
Dissertations, Theses, and Masters Projects
No abstract provided.
Synthesis And Field Emission Properties Of Carbon Nanostructures, Kun Hou
Synthesis And Field Emission Properties Of Carbon Nanostructures, Kun Hou
Dissertations, Theses, and Masters Projects
This dissertation focuses on developing carbon nanostructures for application as the electron emissive material in novel back-gated triode field emission devices. The synthesis, characterization, and field emission properties of carbon nanostructures, including 1-D carbon nanofibers (CNF), 2-D carbon nanosheets (CNS), and chromium oxide coated carbon nanosheets (CrOx-CNS), are presented in this work.;First, we have fabricated aligned carbon nanofiber based back-gated triode field emission devices and confirmed the operation of these devices. 1-D carbon nanofibers were directly synthesized on blank TiW substrates using direct current plasma enhanced chemical vapor deposition. It was found that the morphology of carbon nanofibers could be …