Physical Sciences and Mathematics Commons^™

Longitudinal Tidal Dispersion Coefficient Estimation And Total Suspended Solids Transport Characterization In The James River, Beatriz Eugenia Patino

Civil & Environmental Engineering Theses & Dissertations

The longitudinal dispersion coefficient is a parameter used to evaluate the effect of cross-sectional variations on substance mixing mechanisms in estuaries influenced by tide, wind and internal density variations. Considering a two dimensional approach, this study aims at evaluating a tidal area of the lower James River at approximately 19 miles upstream from the mouth at the Chesapeake Bay, in the City of Newport News, and applies an experimental procedure based on in-situ salinity concentrations to estimate the dispersion coefficient in the area where receives a discharge from the HRSD James River Wastewater Treatment Plant, and further characterizes Total Suspended …

Export Of Terrestrial Dissolved Organic Matter Along A River To Ocean Transect Of The Lower Chesapeake Bay Investigated By Advanced Analytical Techniques, Rachel Leigh Sleighter

Chemistry & Biochemistry Theses & Dissertations

Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) has proved essential for the complete separation of the thousands of peaks present in natural organic matter (NOM), a complex assemblage of organic molecules present in water, soils, and sediments. An improved understanding of its composition is crucial to understand how pollutants interact with NOM and how NOM cycles through global carbon cycles.

Optimizing the acquisition and handling of the FTICR mass spectra is the first step to obtaining high quality data. A simple method to internally calibrate the peaks in the complex spectra, using naturally present fatty …

Exchange Hydrodynamics Between A Subestuary And Its Adjacent Estuary, Diego A. Narváez

OES Theses and Dissertations

Four oceanographic surveys and two periods of moored data were analyzed to describe the subtidal exchange hydrodynamics between a subestuary (Nansemond River) and its adjacent estuary (James River) in the lower Chesapeake Bay. The surveys were carried out during two semidiurnal periods (~25 hrs), which included two spring and two neap tides. Velocity profiles and hydrographic data were recorded over an area ~4 km long and ~1 km wide allowing a spatial resolution rarely obtained with observational data. The results obtained in the surveys were extended with instruments deployed at the entrance to the subestuary during winter and summer time …

Fortnightly Variability At The Transition Between Two Sub-Estuaries, Mayra Lorena Riveron Enzastiga

OES Theses and Dissertations

Profiles of current velocity from an Acoustic Doppler Current Profiler (ADCP) and of water salinity, temperature and density from a Conductivity-Temperature-Depth (CTD) recorder, were combined with surface salinity, temperature and density from a Conductivity-Temperature (CT) recorder to elucidate the fortnightly variability at the Lafayette River entrance. The Lafayette River connects at its mouth with the Elizabeth River, which is a tributary to the James River in the Chesapeake Bay. Data were collected in four experiments during consecutive spring and neap tides in the autumn of 2000, and in the spring of 2001. Each experiment was carried out for -25 hours …

Interannual Variation Of Stratification In Lower Chesapeake Bay, Christopher S. Katzenmiller

OES Theses and Dissertations

Stratification in the water column can prove to be an important indicator to the state of the water column and ecosystem. The focus of this research is to evaluate trends in stratification in the Lower Chesapeake Bay. Detailed analysis was performed on a 14 year data set to study interannual variation in the region of study. Potential energy anomaly was used to quantify stratification. Potential energy anomaly is the amount of energy required to mix a water column. It is determined from the vertical density structure of density. Potential energy anomaly is the departure of potential energy from climate conditions. …

Wind-Induced Exchange In Semi-Enclosed Basins, Rosario Sanay

OES Theses and Dissertations

The wind-induced circulation over laterally varying bathymetry was investigated in homogeneous and in stratified systems using the three-dimensional Regional Ocean Model (ROMS). For homogeneous systems, the focus was to describe the influence of the earth's rotation on the lateral distribution of the flow with particular emphasis on the transverse circulation. Along-basin wind-stress with no rotation caused a circulation dominated by an axially symmetric transverse structure consisting of downwind flow over the shoals and upwind flow in the channel along the whole domain. Transverse circulation was important only at the head of the system where the water sank and reversed direction …

Morphostatic Long-Term Hypsometric Analysis Of Coastal Bay Environments: Hog Island Bay, Virginia, Kathleen Marie Overman

OES Theses and Dissertations

Sea level has been rising at a variable rate since the end of the last glaciation approximately 18,000 years ago. As the transgressing sea inundates the shore areas a series of landform state changes occur in coastal regions. One such change of state in a coastal paleo-river channel is from an estuary into a coastal lagoon. At large temporal intervals (thousands of years) the hypsometry of a coastal lagoon varies as a result of sea level rise due to these changes of state. Using a morphostatic technique, the time period in which an estuary transforms into a coastal lagoon can …

Processes Affecting The Behavior Of Redox-Sensitive Elements In Chesapeake Bay, Maria Lourdes San Diego-Mcglone

OES Theses and Dissertations

Several processes can affect variations in the chemical composition of an estuary, including (1) biogeochemical reactions in the water column, (2) advective transport, and (3) diffusion from underlying sediments.

The purpose of the study was to establish whether estuarine redox reactions are controlled by a complex interaction of processes 1 to 3. Short-term and long-term studies were conducted in Chesapeake Bay. Redox species involved in redox cycling include oxygen, iron, manganese, hydrogen sulfide, nitrogen species, arsenic and antimony species, while phosphate is indirectly involved in redox cycles. Silicate was used as a non-redox tracer.

For the short-term study, a Lagrangian …