Physical Sciences and Mathematics Commons^™

A New View Of Chlorophyll Dynamics In The Southern Mid-Atlantic Bight From A Two-Year High-Resolution Spray Glider Survey, Francesco Lane

OES Theses and Dissertations

The southern Mid-Atlantic Bight (MAB) near Cape Hatteras, NC, USA, is likely a hotspot for the episodic export of carbon-rich shelf waters to the open ocean. Over a 2 year period, from March 2017 to May 2019, Spray gliders repeatedly occupied transects, along the slope and across the shelf, generating high-resolution chlorophyll fluorescence (fChl) data in the southern MAB. This study implements an fChl calibration method utilizing remotely sensing ocean color as a standard. We validate the method’s utility by demonstrating a reduction in post-calibration cross-mission fChl variability and demonstrating close correspondence between the calibrated fChl data and an in …

History Of Ice-Rafting In The Arctic Ocean During Glacial Maxima Through Marine Isotope Stage 6, Shannon M. Cofield

OES Theses and Dissertations

Numerous studies attempted to reconstruct Arctic paleoclimate, specifically ice mass timing and locations, during glacial maxima. While some regions, like the Barents-Svalbard Ice Sheet (BSIS) are well-studied, they may benefit from a high-resolution paleo proxy. Other regions are highly contested, such as the East Siberian Sea or the presence of a central Arctic Ocean ice mass.

This research uses an Fe-grain provenance method to (1) define how the BSIS behaved during Marine Isotope Stage (MIS) 2, 4, and 6, and when it retreated; (2) determine the presence and ages of Shelf Ice Masses (SIMs) in the Beaufort Sea and East …

Nitrogen Cycling In The Lower Chesapeake Bay And Mid- And South Atlantic Bight, Yifan Zhu

OES Theses and Dissertations

Nitrogen (N) is central to marine primary production; its availability often limits the capacity and rates of primary productivity in most of the world’s oceans. Contrastingly, estuaries frequently receive anthropogenic N loading, oftentimes resulting in eutrophication, harmful algal blooms (HABs), and substantially degraded water quality. Nutrient variability in both estuaries and oceanic regimes results from meteorological forcing and physical processes, including wind-induced, tidal, and mesoscale mixing and upwelling. In this dissertation, a comprehensive investigation of N variability and cycling and its links to physical-biogeochemical processes was conducted using time-series monitoring approaches, flux estimations, satellite imaging, biogeochemical measurements, and molecular analyses. …

Modeling The Impacts Of Sea Level Rise In Coastal Virginia At Multiple Scales, George Murray Mcleod Iv

OES Theses and Dissertations

Relative sea level is increasing along the Mid-Atlantic coast of the United States and the rate of relative sea level rise (ΔRSL) for Coastal Virginia is approximately double the rate of global sea level rise (ΔSLRG)(1). The potential impacts posed to communities by ΔRSL are best understood by examining the spatial relationship between the upper limits of ocean-connected waters and the geographic positioning of critical natural and societal assets. This research examines this problem at three spatial scales to quantify the impacts of ΔRSL and storm flooding events on (i) structural and transportation infrastructure for the tide-influenced coastal zone of …

Molecular Evidence For The Export Of Terrigenous Organic Matter To The North Gulf Of Mexico By Solid-State 13C Nmr And Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Of Humic Acids, Sarah Ann Ware

Chemistry & Biochemistry Theses & Dissertations

Marine organic matter is mainly believed to originate from autochthonous organic matter, while terrigenous organic matter is assumed to be largely degraded prior to reaching the open ocean or more recently replaced by marine organic matter via a stripping process. Sediment samples along a transect extending from the Mississippi River Birdsfoot Delta to the Mississippi Canyon on the Louisiana continental shelf were examined by advanced analytical techniques, electrospray ionization coupled to a 12T Fourier transform ion cyclotron resonance mass spectrometer (ESI-FTICR-MS) and quantitative solid-state multiple cross polarization magic angle spinning (multi-CPMAS) ¹³C NMR in an effort to understand the …