Physical Sciences and Mathematics Commons^™

Identification And Quantitation Of Volatile Amines In Chesapeake Bay Sediments, Neeraja Y. Krishna

Chemistry & Biochemistry Theses & Dissertations

Sediments from different parts of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A HF-HCl extraction method was used to extract both exchangeable and fixed amines from the sediments and a purge-and-trap technique was used to concentrate the amines. Following derivatization with heptafluorobutyric anhydride (HFBA), the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One primary amine, i-amylamine with a concentration ranging from 0. 78 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty seven samples collected on three different dates in 1993. Another primary amine, 2-methylbutylamine with a concentration ranging from 0.18 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty three samples collected on three different dates in 1993. A secondary amine, diethylamine was detected but could not be quantified in a total of seven samples collected in September 1993. The concentrations of these amines varied with location in the Bay, depth in the sediment, and time of year the sediments were collected. The origin of i-amylamine and 2-methylbutylamine might be from the biological decarboxylation of amino acids leucine and isoleucine, respectively. The origin of diethylamine is unknown.

Description, Distribution, And Abundance Of The Blue Crab, Callinectes Sapidus (Rathbun), Spawning Stock Of The Lower Chesapeake Bay, Patrick John Geer

OES Theses and Dissertations

The lower Chesapeake Bay spawning stock of the blue crab, Callinectes sapidus, (Rathbun), is examined for seven years (1986 - 1992) in an attempt to better understand stock behavior. Three methods of post-stratification are used to describe the distribution and movement of the population over time. The three methods, density strata, geographic zones, and depth strata, did well in explaining movements of the population, indicating a trend of increased concentration of blue crabs near the eastern Bay late in the spawning season - October. The data suggest a bimodal period of spawning and a trimodal period of abundance. The …

The Biogeochemistry Of Iodine In Seawater, Lingsu Zhang

OES Theses and Dissertations

Iodate and iodide are the two major species of iodine in seawater. In comparison to iodate, iodide is thermodynamically unstable in oxic seawater. The conversion (or reduction) of iodate to iodide may be mediated via biological activities. Since biological activities vary with the season, the conversion of iodate to iodide may also vary seasonally. The conversion (or oxidation) of iodide to iodate is thermodynamically feasible, but the mechanism is poorly known. Hydrogen peroxide, which is ubiquitous in surface seawater, may oxidize iodide to iodate.

Water samples were collected in the middle and lower Chesapeake Bay in different seasons between 1990 …

Production And Decomposition Of Hydrogen Peroxide By Marine Phytoplankton, Dong-Beom Kim

OES Theses and Dissertations

H₂0₂ in seawater has complicated sources and sinks. The relative importance of biological regulation of H₂0₂ compared to other processes is not well understood. In addition, environmental factors affecting the biological regulation of H202 are largely unknown. Marine phytoplankton was examined for the kinetics of the production and decomposition of H₂0₂ in the dark. Effects of varying environmental factors such as light, temperature, salinity, nutrients, amino acids, trace metals and growth phase, were examined. H₂0₂ was determined with the scopoletin-fluorescence decay method.

Five out of 11 species produced …

The Biogeochemistry Of Hydrogen Sulfide In The Open Ocean, Joël Radford-Knoery

OES Theses and Dissertations

Hydrogen sulfide is a poorly quantified component of the global sulfur cycle. In seawater, its dissolved species (dissolved sulfide) can react with trace metals to form dissolved complexes and insoluble compounds. Therefore, the study of dissolved° sulfide in the open ocean can yield a better understanding of the biogeochemical cycles of sulfur and trace metals.

The biogeochemical cycling of dissolved sulfide was examined using specially developed sampling and analytical methods. In the western North Atlantic and central Equatorial Pacific Oceans, total dissolved sulfide concentrations ranged from /L; they were highest, in the mixed layer and decreased with depth. The depth …

Paleobathymetric Interpretation Of Pleistocene Sediments In The South Padre Island Area, Northwestern Gulf Of Mexico, Using Benthic Foraminiferal Morphology, Karen Ianthe Kruebbe-Belwood

OES Theses and Dissertations

This study tested the validity of using intraspecific variation in benthic foraminifera as a means for determining Pleistocene paleobathymetry. Canonical variate analysis was used as a means for determining visually undetectable but statistically significant differences in the morphology of selected species. Two species, Cassidulina subglobosa and Uvigerina peregrina, were collected from Pleistocene well cuttings from the northwest Gulf of Mexico. The canonical analysis involved comparing the intraspecific variation of these Pleistocene species to their counterparts occurring in the modern Gulf of Mexico, where intraspecific variation was previously analyzed and found to be sufficient to allow detection of bathymetric differences …

Modeling Nutrient And Plankton Processes In The California Coastal Transition Zone, John Roland Moisan

OES Theses and Dissertations

Two time- and space-dependent, physical-bio-optical models have been developed for the California Coastal Transition Zone (CTZ) region with the overall objective of understanding and quantifying the processes th at contribute to the spatial and temporal development of nutrient and plankton distributions in the CTZ. The first of these models considers only time- and vertical processes at specific locations in the CTZ. The model food web components include: silicate, nitrate, ammonium, two phytoplankton size fractions, copepods, doliolids, euphausiids and a detritus pool. The wavelength dependent attenuation of the subsurface irradiance field, due to sea water, phytoplankton pigment concentrations and dissolved organic …

Instability Waves In The Gulf Stream Front And Its Thermocline Layer, Sang-Ki Lee

OES Theses and Dissertations

Linear instability calculations were carried out on a three layer Gulf Stream front model in an attempt to elucidate the interaction of the thermocline layer with surface slopewater shoreward of the front. The basic state is geostrophic balance and constant potential vorticity in the two active layers, but the perturbations are ageostrophic. The flow is found to be unstable to long wave perturbations, the wavelength of the most unstable wave to be of order 10 radii of deformation. The instability is mainly baroclinic, 75-85% of the energy supply to the growing perturbation coming from basic flow potential energy. Calculated wavelengths …

Description And Dynamics Of 50-Day Oscillations In The Western Tropical Region Of The Cme Model, Julie Lorraine Mcclean

OES Theses and Dissertations

The WOCE Community Modelling Effort (CME) general circulation model of the north Atlantic was used to investigate the behavior, nature and dynamics of 50-day oscillations seen in the meridional component of velocity between 35° and 55°W and between 5° and 11°N. Validation studies showed that the model reproduced the surface circulation in this area with a reasonable degree of accuracy, in particular, the characteristic seasonal variability. From June to December, the North Brazil Current (NBC) retroflects to form the western arm of the North Equatorial Countercurrent (NECC). Associated with the NECC is a standing meander pattern which extends from the …

Heat Storage And Transport Processes In The Tropical Atlantic Ocean, Andras Kapolnai

OES Theses and Dissertations

Heat storage and transport processes of the tropical Atlantic play an important role in the climate of three continents. The exploration of how the warm water mass maintenance in the equatorial basin depends on various external factors is therefore an important task. This study examines the annual cycle of the warm water mass formation and its transport in the equatorial Atlantic through the interaction of the atmospheric and oceanic boundary layers. Key features of the model are the sea level wind field, equatorial upwelling rate and escape transport of the formed warm water out of the equatorial basin.

The model …