Physical Sciences and Mathematics Commons^™

Coating Of Aluminum Powder With Polymers In Supercritical Carbon Dioxide, Li Yuan

Theses

Eleven polymers were used to produce coatings (2-20 nm) on the surface of an aluminum powder to modify its properties. The polymers studied are polyisobutylene (PIB), poly (vinylidene fluoride) (PVF), poly (methyl methacrylate) (PMMA), polystyrene (PS), poly(ethylene terephthalate) (PETP), poly(4-vinylbiphenyl) (PVB), poly(4-vinylpyridine) (PVP), poly(4-bromo styrene) (PBS), poly (vinylidene fluorideco-hexafluoropropylene) (PVFH), poly (styrene-co-methyl methacrylate) (PSMMA), poly (vinyl chloride-co-vinyl acetate) (PVCVA). Supercritical carbon dioxide was used as a solvent and as a transport medium. Coated aluminum powders exhibit enhanced resistance to the dissolution in basic solutions. The protective properties of the polymeric films were quantified based on the dissolution rate. Polymeric films …