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Chemistry

Nanomaterials

Theses and Dissertations

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Full-Text Articles in Physical Sciences and Mathematics

Manufacturing Of A Flexible Piezoelectric Nanogenerator By Functionalizing Polyvinylidene Fluoride With Lithium Tantalate And Multiwalled Carbon Nanotubes For Energy Harvesting And Sensing Applications, Islam Uddin Shipu Aug 2023

Manufacturing Of A Flexible Piezoelectric Nanogenerator By Functionalizing Polyvinylidene Fluoride With Lithium Tantalate And Multiwalled Carbon Nanotubes For Energy Harvesting And Sensing Applications, Islam Uddin Shipu

Theses and Dissertations

Mechanical energy is one of the readily accessible green energy sources that could be employed to meet the small-scale energy requirement. In order to capture mechanical energy, power the next generation of electronic gadgets, and health monitoring flexible piezoelectric nanogenerators made of light weight polymers and carbon nanotubes have drawn a lot of attention. Lithium tantalate (LiTaO3), a ferroelectric substance, was prepared here and utilized to create a flexible piezoelectric nanogenerator (FPNG). A compact piezoelectric nanogenerator that successfully transfers mechanical energy into electricity was then created using lightweight polyvinylidene fluoride (PVDF), multi-walled carbon nanotube (MWCNT), and LiTaO3 nanoparticles. To create …


Tailored Nanomaterials For Advancing Fast-Charge Research, Wessel Van Den Bergh Apr 2022

Tailored Nanomaterials For Advancing Fast-Charge Research, Wessel Van Den Bergh

Theses and Dissertations

The demand for fast, energy-dense storage has driven research into nanoscale intercalation materials. Nanoscale materials not only accelerate kinetics but also can modify reaction path thermodynamics, intercalant solubility, and diffusivity. Pioneering works have revealed such nanoscale changes, often without the need to separately probe each fundamental transport process. While electrodes can be designed to have one transport processes dominant, there remain opportunities to better understand energy-dense designs with multiple concomitant transport constraints. The contents herein highlight emerging an method using tailored, energy-dense nanomaterials and the process of elimination to clearly correlate architectural features to performance. For example, this method revealed …


Investigations On The Surface Chemistry Of Colloidal Quantum Dots Towards Fluorescent Biological Probes, John Hardin Dunlap Oct 2021

Investigations On The Surface Chemistry Of Colloidal Quantum Dots Towards Fluorescent Biological Probes, John Hardin Dunlap

Theses and Dissertations

Colloidal semiconductor quantum dots (QDs) have garnered significant interest as promising materials for biological applications due to their improved photostability and narrow, tunable photoluminescence properties compared to organic fluorophores. To facilitate their utility as fluorescent bioimaging probes, QDs must undergo post-synthetic modifications to exchange their native hydrophobic ligands from synthesis with hydrophilic ones that enable colloidal dispersions in aqueous environments. Many examples exist that demonstrate surface modifications for water-soluble QDs and their efficacy in biological systems, however, there is a need to develop a more thorough understanding of how hydrophilic ligands coordinate to QD surfaces in order to develop more …


Plasmonic Metallic And Semiconductor Nanomaterials, Mengqi Sun Jul 2021

Plasmonic Metallic And Semiconductor Nanomaterials, Mengqi Sun

Theses and Dissertations

The earliest account of localized surface plasmon resonance (LSPR) has to date back to the ancient age of Rome in 400 A.D. The famous glass of Lycurgus cup told the story of unique light-and-matter interaction at the nanoscale that confines the electromagnetic field resonance at its surface and therefore allows LSPR feature to noticeably arise. The conventional metallic LSPR nanomaterials, like Au and Ag nanoparticles attract constant attentions due to their synthetic simplicity, chemical robustness, and visible spectral response. Its ability to generate sensitive dielectric sensing of the surroundings, strong electromagnetic field and active charge carriers upon optical excitation triggered …


The Rational Synthesis Of Lanthanum Manganite Nanomaterials For Magnetic Refrigeration Applications, Caitlin Hunt Jan 2021

The Rational Synthesis Of Lanthanum Manganite Nanomaterials For Magnetic Refrigeration Applications, Caitlin Hunt

Theses and Dissertations

Refrigeration systems for the cooling of commercial and residential buildings are a major drain on energy resources and source of greenhouse gas emissions. Magnetic refrigeration, which employs the magnetocaloric effect, has the potential to mitigate the energy drain and greenhouse gas emissions for air conditioning. In order to commercialize magnetic refrigerators, a material with a high magnetic entropy change, ΔS, near room temperature which is simple and inexpensive to create is needed.1 Current options for this solid refrigerant are either expensive, difficult to synthesize, or have a ΔS or Tc (the Curie Temperature, where ΔS is maximized) below …