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Chemistry

Electrochemistry

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Full-Text Articles in Physical Sciences and Mathematics

Cetyltrimethylammonium Halide-Coated Electrodes For The Detection Of Dopamine In The Presence Of Interferents, Amber J. Yeary Jan 2011

Cetyltrimethylammonium Halide-Coated Electrodes For The Detection Of Dopamine In The Presence Of Interferents, Amber J. Yeary

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Specially constructed carbon paste electrodes were coated with 10 mM cetyltrimethylammonium halide (CTAX) solutions, bromide and chloride being the counter anions. These surfactant modified electrodes were used to detect the catecholamine neurotransmitter dopamine using cyclic voltammetry. The coated electrodes gave reproducible quasi-reversible behavior for the analyte dopamine over a range of concentrations from 1 mM to 200 mM. When combined in solution with common interferents ascorbic acid (1 mM) and uric acid (300 μM), all cathodic and anodic current peaks maintained resolution at the biological pH of 7.4. When the coating solutions were below the critical micelle concentration (0.5 mM), …


A Lab To Stemulate Undergraduate Students Into Science, Technology, Engineering And Mathematics Majors, Nicole Lynn Speelman Jan 2009

A Lab To Stemulate Undergraduate Students Into Science, Technology, Engineering And Mathematics Majors, Nicole Lynn Speelman

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The central focus is the development and implementation of a research/lab module for first year chemistry courses. Electrochemical techniques are utilized to study oxidation and reduction reactions of neurotransmitters with a poly(2,2'-Bithiophene) modified electrode. The goal is to excite students about chemistry and encourage them to continue studies in Science, Technology, Engineering, and Mathematics (STEM) during their undergraduate education. The lab module was created for Project REEL (Research Experiences to Enhance Learning) and will be illustrated with results typically obtained by students. The experiment is inquiry-based, which includes challenging questions students have to do collaboration and research to answer, as …