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Theses/Dissertations

Chemistry

Department of Chemistry

2019

Articles 1 - 4 of 4

Full-Text Articles in Physical Sciences and Mathematics

Determination Of Benzotriazole And Analog Compounds By Liquid Chromatography-Mass Spectrometry In Surface Runoff Water Samples From Wilmington Air Park, Jessica A. Wiese Jan 2019

Determination Of Benzotriazole And Analog Compounds By Liquid Chromatography-Mass Spectrometry In Surface Runoff Water Samples From Wilmington Air Park, Jessica A. Wiese

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Benzotriazole (BTri) and its analog compounds are widely used in aircraft de-icing and anti-icing solutions, however their high solubility in water and resistance to biodegradation results in only their partial removal in wastewater treatment, and therefore makes them potential contaminants in watershed systems. The Wilmington Air Park in Wilmington, Ohio currently has two surface-runoff lagoons to pre-treat water containing these de-icing compounds before releasing it into nearby streams. Because the Wilmington Air Park has recently made an agreement with a major online retailer to lease over two dozen planes and open a package-sorting facility beginning in late 2019, the goal …


Silver Nanoparticles: An Effective Antibacterial Agent Against Gram-Negative Bacteria, Ashley M. Wilcox Jan 2019

Silver Nanoparticles: An Effective Antibacterial Agent Against Gram-Negative Bacteria, Ashley M. Wilcox

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A fourth of the world’s population lack access to safe water, thus the need for a more effective water treatment is imperative. Interest in silver nanoparticles (AgNPs) has grown in the last decade. Unlike chlorine, AgNPs do not form disinfection by products (DBPs), making them a prime candidate for drinking water treatment. The main aim of this study was to compare the antibacterial activity of electrochemical silver nanoparticles (eAgNPs-f) of ~5 nm in diameter against well-established pathogens: Escherichia coli (E. coli), Klebsiella variicola (K. variicola), and Pseudomonas aeruginosa (P. aeruginosa) to chlorine and Ag+ for drinking water. This was achieved …


Implication Of Inorganic Nitrogen And Phosphorous Species As A Cause Of A Harmful Algal Bloom Event In Caesar Creek Lake, Ohio And Its Tributaries, Baxter Jeffrey Foskuhl Jan 2019

Implication Of Inorganic Nitrogen And Phosphorous Species As A Cause Of A Harmful Algal Bloom Event In Caesar Creek Lake, Ohio And Its Tributaries, Baxter Jeffrey Foskuhl

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Agricultural runoff poses a threat to the Wilmington, Ohio municipal water supply and its source waters. A harmful algal bloom (HAB) was documented in June 2019 in Caesar Creek Lake, Waynesville, Ohio. This study seeks to establish baseline nutrient concentrations in Caesar Creek Lake (Warren County, Ohio) and its tributaries, and to identify potential non-point sources of excess nitrogen and phosphorous that contributed to the HAB event. In collaboration with the Wilmington Water Department, dissolved inorganic nitrogen DIN-[N] (sum of NH3-[N], NH4+-[N], NO2--[N], NO3--[N] concentrations), dissolved phosphorous DP-[P], particulate phosphorous PP-[P], total phosphorous TP-[P] (total sum of DP-[P] and PP-[P] …


In Vitro Uptake And Biodistribution Of Silver Nanoparticles In Vero 76 Cells, Miriam A. Crane Jan 2019

In Vitro Uptake And Biodistribution Of Silver Nanoparticles In Vero 76 Cells, Miriam A. Crane

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The number of consumer products containing nanomaterials over the last eight years has increased over two-fold. Silver is one of the most commonly used materials in consumer goods nanoparticle fabrication.1 Thus, the uptake and biodistribution of silver nanoparticles (AgNPs) within mammalian cells can provide insight into their possible toxicological effects. In this study, starch-capped AgNPs of an average diameter of 9 ± 5 nm were synthesized via a bottom-up method, and characterized by Raman spectroscopy, transmission electron microscopy (TEM), inductively couple plasma optical emission spectroscopy (ICP-OES), and absorption spectroscopy. Vero 76 cells were incubated with 0.0, 0.1, 1.0, and 3.0 …