Physical Sciences and Mathematics Commons^™

Fluorescence Spectroscopy And Microscopy Studies Of Chromophore Coupling In Isolated Small Molecule Nanostructures, Sarah R. Marques

Doctoral Dissertations

My thesis focused on understanding the structural changes producing different spectral signatures seen in aggregates of 7,8,15,16- tetrazaterrylene (TAT). Recent work from our group showed crystallographically selective directional charge-separation within isolated extended TAT crystals without the need of an interface. Aggregates of different size not only exhibited different exciton recombination kinetics, but different spectral signatures. The motivation for understanding the change in the structural properties producing the unique spectral signatures is elucidating the mechanism of this directional charge-separation, intrinsic or extrinsic. In this case, an intrinsic mechanism means it is caused by molecular design and packing, and extrinsic mechanism means …